Skip to main content
Log in

Effect of z-pin surface treatment on delamination and debonding properties of z-pinned composite laminates

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The effect of z-pin surface treatment on the delamination fracture properties of z-pinned unidirectional carbon fibre/epoxy prepreg laminate is presented in this paper. Cryogenic and plasma treatments were used to increase the pin/composite interface properties. Z-pin pullout tests were carried out to study the relations between the bridging force and the displacement. Mode-I double-cantilever beam tests were used to characterize the improvements in delamination toughness. It was pointed out that appropriate treatments could effectively increase the delamination fracture properties. Oxygen-containing functional groups could be induced on the pin surface through cold plasma treatment. An increasing surface energy is improving the wettability so that more chemical reactions can be generated between the epoxy group and z-pin surface. Furthermore, the surface roughness of z-pins can be extended with a plasma or cryogenic treatment. The pins obtained a larger surface area, which could wet by the epoxy matrix during the z-pin-insertion and curing process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Mouritz AP, Cox BN (2010) A mechanistic interpretation of the comparative in-plane mechanical properties of 3D woven, stitched and pinned composites. Compos Part A 41(6):709–728

    Article  Google Scholar 

  2. Mouritz AP, Bannister MK, Falzon PJ, Leong KH (1999) Review of applications for advanced three-dimensional fibre textile composites. Compos Part A 30(12):1445–1461

    Article  Google Scholar 

  3. Tong Liyong, Mouritz Adrian P, Bannister Michael K (2002) 3D fibre reinforced polymer composites. 1. Elsevier, Boston

    Google Scholar 

  4. Mouritz AP (2007) Review of z-pinned composite laminates. Compos Part A 38(12):2383–2397

    Article  Google Scholar 

  5. Partridge Ivana K, Cartié DDR, Bonnington T (2003) Manufacture and performance of z-pinned composites. Shonaike Gabriel O (Hrsg.), Advani Suresh G (Hrsg.): Advanced polymeric materials: Structure property relationships. Boca Raton and FL : CRC Press, 2003. -ISBN 978-1-58716-047-9

  6. O’Brien TK, Krueger Ronald (2006) Influence of compression and shear on the strength of composite laminates with z-pinned reinforcement. Appl Compos Mater 13(3):173–189

    Article  ADS  Google Scholar 

  7. Mouritz AP (2007) Compression properties of z-pinned composite laminates. Compos Sci Technol 67(15-16):3110–3120

    Article  CAS  Google Scholar 

  8. Chang P, Mouritz AP, Cox BN (2006) Properties and failure mechanisms of z-pinned laminates in monotonic and cyclic tension. Compos Part A 37(10):1501–1513

    Article  Google Scholar 

  9. Sweeting RD, Thomson RS (2004) The effect of thermal mismatch on Z-pinned laminated composite structures. In: Composite Structures 66(1–4):189–195. -ISSN 0263-8223. -Twelfth International Conference on Composite Structures

  10. Chang P, Mouritz AP, Cox BN (2007) Flexural properties of z-pinned laminates. Compos Part A 38(2):244–251

    Article  Google Scholar 

  11. Zhang X, Hounslow L, Grassi M (2006) Improvement of low-velocity impact and compression-after-impact performance by z-fibre pinning. Compos Sci Technol 66(15):2785–2794

    Article  CAS  Google Scholar 

  12. Cartié DDR, Cox BN, Fleck NA (2004) Mechanisms of crack bridging by composite and metallic rods. Compos Part A 35(11):1325–1336

    Article  Google Scholar 

  13. Dai SC, Yan W, Liu HY, Mai YW (2004) Experimental study on z-pin bridging law by pullout test. Compos Sci Technol 64(16):2451–2457

    Article  Google Scholar 

  14. Vazquez JT, Castanié B, Barrau JJ, Swiergiel N (2011) Multi-level analysis of low-cost z-pinned composite joints: part 1: single z-pin behaviour. Compos Part A 42(12):2070–2081

    Article  Google Scholar 

  15. Zhang H, Zhang Z, Breidt C (2004) Comparison of short carbon fibre surface treatments on epoxy composites: I. Enhancement of the mechanical properties. Compos Sci Technol 64(13-14):2021–2029

    Article  CAS  Google Scholar 

  16. Rashkovan IA, Korabelnikov Yu G (1997) The effect of fiber surface treatment on its strength and adhesion to the matrix. Compos Sci Technol 57(8):1017–1022

    Article  CAS  Google Scholar 

  17. Brandl W, Marginean G, Chirila V, Warschewski W (2004) Production and characterisation of vapour grown carbon fiber/polypropylene composites. Carbon 42(1):5–9

    Article  CAS  Google Scholar 

  18. Li Hao, Liang Hui, He Fang, Huang Yuan, Wan Yizao (2009) Air dielectric barrier discharges plasma surface treatment of three-dimensional braided carbon fiber reinforced epoxy composites. Surf Coat Technol 203(10-11):1317–1321

    Article  CAS  Google Scholar 

  19. Li Rongzhi, Ye Lin, Mai Yiu-Wing (1997) Application of plasma technologies in fibre-reinforced polymer composites: a review of recent developments. Compos Part A 28(1):73–86

    Article  Google Scholar 

  20. Wilhelmy L (1863) Über die Abhängigkeit der Capillaritäts-Constanten des Alkohols von Substanz und Gestalt des benetzten festen Körpers. In: Poggendorf JC (Hrsg.) Annalen der Physik und Chemie Bd. 119. Verlag von Johann Ambrosius, 1863, S. 177–217

  21. Chang P (2006) The mechanical properties and failure mechanisms of z-pinned composites, Royal Melbourne Institute of Technology, Ph.D. Thesis

  22. Cartié DDR (2000) Effects of z-fibres™ on the delamination behaviour of carbon fibre/epoxy laminates, Cranfield University, Ph.D. Thesis

  23. Partridge Ivana K, Cartié DDR (2005) Delamination resistant laminates by Z-Fiber\(\circledR\) pinning: Part I manufacture and fracture performance. Compos Part A 36(1):55–64

    Google Scholar 

  24. Kaelble DH (1670) Dispersion-polar surface tension properties of organic solids. J Adhesion 2(2):66–81

    Article  Google Scholar 

  25. Owens DK, Wendt RC (1969) Estimation of the surface free energy of polymers. J Appl Polym Sci 13(8):1741–1747

    Article  CAS  Google Scholar 

  26. Liu HY, Yan W, Mai YW (2003) Z-pin bridging force in composite delamination. In: Blackman BRK (Hrsg.), Pavan A (Hrsg.), Williams JG (Hrsg.): Fracture of Polymers, Composites and Adhesives II Bd. 32. Elsevier, 2003. - ISSN 1566-1369, S. 491–502

  27. Robinson P, Das S (2004) Mode I DCB testing of composite laminates reinforced with z-direction pins: a simple model for the investigation of data reduction strategies. Eng Fract Mech 71(3):345–364

    Article  Google Scholar 

  28. ISO Standard [15024:2001]: Fibre-reinforced plastic composites–determination of mode I interlaminar fracture toughness, GIC, for unidirectionally reinforced materials.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to André Knopp.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Knopp, A., Scharr, G. Effect of z-pin surface treatment on delamination and debonding properties of z-pinned composite laminates. J Mater Sci 49, 1674–1683 (2014). https://doi.org/10.1007/s10853-013-7851-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-013-7851-2

Keywords

Navigation