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Preparation and blue–white luminescence properties of Bi3+-doped Ba5SiO4Cl6

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Abstract

The Ba5SiO4Cl6:Bi3+ phosphor was synthesized by high-temperature solid-state reaction and its luminescence property was investigated. The results showed that the Bi3+-doped Ba5SiO4Cl6 phosphors exhibited an intense blue–white light emission located at 480 nm and a broad excitation band from 230 to 340 nm. The Bi3+-doped Ba5SiO4Cl6 phosphors can be efficiently excited by the incident light of 220–340 nm, and the emission properties of the Bi3+-doped Ba5SiO4Cl6 samples are strongly dependent on the excitation wavelength. The emission color tunability can be obtained by changing the excitation wavelength. The visible region emission characteristics of Ba5SiO4Cl6:Bi3+ indicates that it can potentially be used as a new efficient blue–white luminescent material.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (51002068) and Natural Science Foundation of Yunnan Province (2010ZC038).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, People’s Republic of China

    Shenfeng Lai, Zhengwen Yang, Rongfei Wang, Hangjun Wu, Jiayan Liao, Jianbei Qiu, Zhiguo Song, Yong Yang & Dacheng Zhou

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  1. Shenfeng Lai
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  2. Zhengwen Yang
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Correspondence to Zhengwen Yang.

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Lai, S., Yang, Z., Wang, R. et al. Preparation and blue–white luminescence properties of Bi3+-doped Ba5SiO4Cl6 . J Mater Sci 48, 8566–8570 (2013). https://doi.org/10.1007/s10853-013-7676-z

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  • DOI: https://doi.org/10.1007/s10853-013-7676-z

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