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Crosslinking poly(allylamine) fibers electrospun from basic and acidic solutions

  • Polymer Fibers
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Abstract

Mechanically robust, non-toxic polymer fiber mats are promising materials for a range of biomedical applications; however, further research into enhancing polymer selection is needed. In this study, poly(allylamine) (PAH), an amine-containing polyelectrolyte, was successfully electrospun from aqueous solutions into continuous, cylindrical fibers with a mean diameter of 150 ± 41 nm. A one-step crosslinking method using glutaraldehyde provides insight into the chemical and morphological changes that result from altering the molar ratio of amine to aldehyde groups, whereas a two-step crosslinking method yielded chemically and mechanically robust mats. These results indicate PAH fibrous mats synthesized from aqueous solutions could potentially be applied in biomedical applications.

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Acknowledgements

The authors thank Dr. Christopher Pastore of Philadelphia University for use of their Instron and Dr. Christopher Li of Drexel University for the use of the Kawabata. J.D.S. would like to thank the Koerner Family Fellowship and Graduate Assistance in Areas of National Need-Drexel Research and Education in Advanced Materials (GAANN-DREAM) (P200A060117), which is funded by the Department of Education’s Office of Postsecondary Education for funding. M.A.K. thanks the Institute of Food Technologists—Philadelphia Chapter and the Drexel University Freshmen Design Engineering Fellowship. A.E.D. thanks the Philadelphia SWE for the Dow Chemical Company Award and acknowledges her GAANN Fellowship P200A070496 and NSF-IGERT 0654313. U.G.K.W. thanks Anne Stevens for the generous support of her research and group at Drexel University. The authors wish to acknowledge funding by the NSF DMR Grant No. 0907572, NSF CMMI Grant No. 0804543 and Ben Franklin Nanotechnology Institute, Philadelphia, PA.

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, University of Massachusetts Amherst, Amherst, MA, 01003-9303, USA

    Jessica D. Schiffman

  2. Department of Materials Science and Engineering, Drexel University, Philadelphia, PA, 19104, USA

    Marjorie A. Kiechel, Amalie E. Donius & Caroline L. Schauer

  3. Thayer School of Engineering, Dartmouth College, Hanover, NH, 03755, USA

    Ulrike G. K. Wegst

Authors
  1. Jessica D. Schiffman
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  2. Marjorie A. Kiechel
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  3. Amalie E. Donius
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  4. Ulrike G. K. Wegst
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  5. Caroline L. Schauer
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Corresponding author

Correspondence to Caroline L. Schauer.

Additional information

Jessica D. Schiffman and Marjorie A. Kiechel contributed equally to this work.

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Schiffman, J.D., Kiechel, M.A., Donius, A.E. et al. Crosslinking poly(allylamine) fibers electrospun from basic and acidic solutions. J Mater Sci 48, 7856–7862 (2013). https://doi.org/10.1007/s10853-013-7426-2

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  • DOI: https://doi.org/10.1007/s10853-013-7426-2

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