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ZnAl2O4 co-doped with Yb3+/Er3+ prepared by combustion reaction: evaluation of photophysical properties

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Abstract

Zinc aluminate co-doped with Yb3+/Er3+ for potential application in upconversion lasers was prepared in proportions of 2:1, 5:1, and 10:1 by combustion reaction. The samples were characterized by X-ray diffraction, transmission electron microscopy, and optical spectroscopy. The results reveal the formation of crystalline ZnAl2O4 primary phase and trace amounts of ZnO and Yb3Al5O12 secondary phases. They also indicate that increasing the Yb3+/Er3+ ratio favored the increase of secondary phases. The optical spectroscopy analysis revealed that red emission predominated over green, and that emission intensity was directly influenced by the infrared intensity of the diode laser. These results indicate that ZnAl2O4 doped with rare earth ions may also be an interesting material for luminescence obtained by energy upconversion.

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References

  1. Feldmann C, Justel T, Ronda CR, Schmidt PJ (2003) Adv Funct Mater 13:511

    Article  CAS  Google Scholar 

  2. Saines PJ, Elcombe MM, Kennedy BJ (2006) J Solid State Chem 179:613

    Article  CAS  Google Scholar 

  3. Shanfeng L, Min Z, Yang P, Qingyu Z, Mingshan Z (2010) J Rare Earths 28(2):237

    Article  Google Scholar 

  4. Zhou J, Zhang W, Huang T, Wang L, Li J, Liu W, Jiang B, Pan Y, Guo J (2011) Ceram Int 37:513

    Article  CAS  Google Scholar 

  5. Yang Z, Zhu K, Song Z, Zhou D, Yin Z, Qiu J (2011) J Solid State Commun 151:364

    Article  CAS  Google Scholar 

  6. Weng F, Chen D, Wang Y, Yu Y, Huang P, Lin H (2009) Ceram Int 35:2619

    Article  CAS  Google Scholar 

  7. Qu Y, Kong X, Sun Y, Zeng Q, Zhang H (2009) J Alloy Compd 485:493

    Article  CAS  Google Scholar 

  8. Ping H, Chen D, Yu Y, Wang Y (2010) J Alloy Compd 490:74

    Article  CAS  Google Scholar 

  9. Chen L, Yu C, Hu L, Chen W (2012) Solid State Sci 14:e287

    Article  Google Scholar 

  10. You W, Lai F, Jiang H, Liao J (2012) Physica B 407:1094

    Article  CAS  Google Scholar 

  11. Chen XY, Ma C, Zhang ZJ, Wang BN (2008) Mater Sci Eng B 151:224

    Article  CAS  Google Scholar 

  12. Menon S, Dhabekar B, Alagu Rajaa E, More SP, Gundu Raob TK, Kher RK (2008) J Lumin 128:1673

    Article  CAS  Google Scholar 

  13. Chen XY, Ma C (2010) Opt Mater 32:415

    Article  CAS  Google Scholar 

  14. Barros BS, Melo PS, Kiminami RHGA, Costa ACFM, Sá GF, Alves S Jr (2006) J Mater Sci 41:4744. doi:10.1007/s10853-006-0035-6

    Article  CAS  Google Scholar 

  15. Shen SC, Hidajat K, Yu LE, Kawi S (2004) Adv Mater 16:541

    Article  CAS  Google Scholar 

  16. Farhadi S, Panahandehjoo S (2010) Appl Catal A 382:293

    Article  CAS  Google Scholar 

  17. Zawadzki M, Wrzyszcz J, Strek W, Hreniak D (2001) J Alloy Compd 323–324:279

    Article  Google Scholar 

  18. Singh V, Chakradhar RPS, Rao JL, Kim D-K (2008) J Lumin 128(3):394

    Article  CAS  Google Scholar 

  19. Jain SR, Adiga KC, Pai Verneker V (1981) Combust Flame 40:71

    Article  CAS  Google Scholar 

  20. Costa ACFM, Kiminam RHGA, Morelli MR (2009) Handbook of nanoceramics and their based nanodevices, vol 5. American Science Publishers, Valencia, p 80

    Google Scholar 

  21. Klung H, Alexander L (1962) X-ray diffraction procedures. Wiley, New York

    Google Scholar 

  22. Sun H, Dai S, Xu S, Wen L, Hu L, Jiang ZJ (2004) Mater Lett 58:3948

    Article  CAS  Google Scholar 

  23. Wang X, Kong X, Shan G, Yu Y, Sun Y, Feng L, Chao K, Lu S, Li Y (2004) J Phys Chem B 108(48):18408

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the Brazilian Research Funding Agencies CNPq, RENAMI, FAPESP, and Inct-INAMI for their financial support of this work. We are also indebted to Prof. Luiz Antonio de Oliveira Nunes from the Department of Physics of the University of São Paulo-USP for performing the upconversion tests.

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Correspondence to R. H. G. A. Kiminami.

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Costa, A.C.F.M., Kiminami, R.H.G.A., Santos, P.T.A. et al. ZnAl2O4 co-doped with Yb3+/Er3+ prepared by combustion reaction: evaluation of photophysical properties. J Mater Sci 48, 172–177 (2013). https://doi.org/10.1007/s10853-012-6725-3

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  • DOI: https://doi.org/10.1007/s10853-012-6725-3

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