Abstract
The temperature-dependent fracture toughness of brittle ceramics can be conveniently assessed from bending tests of specimens with defined cracks introduced by indentation. However, the validity of this indentation strength in bending method (ISM) depends critically on the correct consideration of the residual stress induced by the indentation process. The ISM has been applied to La0.58Sr0.4Co0.2Fe0.8O3-δ (LSCF) and, for comparison, on Ba0.5Sr0.5Co0.2Fe0.8O3-δ (BSCF) perovskite. LSCF with rhombohedral phase exhibits ferro-elastic behavior at ambient temperature, whereas BSCF deforms linear-elastically. Pre-indented specimens of both perovskites were fractured at room temperature in biaxial bending, some of them after an additional annealing step. The fracture toughness values of BSCF match reasonably well when determined with equations which consider the presence or absence of residual indentation stress. Interestingly, annealing has little influence on the apparent toughness results obtained for rhombohedral LSCF, which appears to be related with stress relaxation by ferro-elastic deformation.
Similar content being viewed by others
References
Huang BX, Malzbender J, Steinbrech RW, Grychtol P, Schneider CM, Singheiser L (2009) Appl Phys Lett 95:051901
Huang AS, Lin YS, Yang WS (2004) J Membr Sci 245:41
Barsoum MW (2003) Fundamentals of ceramics, 2nd edn. Institute Of Physics Publishing (Gb), London
Anstis GR, Chantikul P, Lawn BR, Marshall DB (1981) J Am Ceram Soc 64:533
Chantikul P, Anstis GR, Lawn BR, Marshall DB (1981) J Am Ceram Soc 64:539
Oliver WC, Pharr GM (1992) J Mater Res 7:1564
Malzbender J, Toonder JMJD, Balkenende AR, de With G (2002) Mater Sci Eng R 36:47
Marshall DB, Lawn BR (1977) J Am Ceram Soc 60:86
Quinn GD, Bradt RC (2007) J Am Ceram Soc 90:673
Fessler H, Fricker DC (1984) J Am Ceram Soc 67:582
Fett T, Rizzi G, Guin JP, Wiederhorn SM (2007) J Mater Sci 42:393. doi:10.1007/s10853-006-1102-8
Ingelstrom N, Nordberg H (1974) Eng Fract Mech 6:597
Petrovic JJ, Dirks RA, Jacobson LA, Mendiratta MG (1976) J Am Ceram Soc 59:177
Marshall DB, Lawn BR (1979) J Mater Sci 14:2001. doi:10.1007/BF00551043
Fett T, Kounga Njiwa AB, Rödel J (2005) Eng Fract Mech 72:647
Kountouros P, Förthmann R, Naoumidis A, Stochniol G, Syskakis E (1995) Ionics 1:40
Huang BX, Malzbender J, Steinbrech RW, Wessel E, Penkalla HJ, Singheiser L (2010) J. Membr Sci 349:183
Freiman S, Mecholsky J (2010) J Mater Sci 45:4063. doi:10.1007/s10853-010-4491-7
Albayrak IC, Basu S, Sakulich A, Yeheskel O, Barsoum MW (2010) J Am Ceram Soc 93:2028
Asmani M, Kermel C, Leriche A, Ourak M (2001) J Eur Ceram Soc 21:1081
Feng W, Yan D, He J, Zhang G, Chen G, Gu W, Yang S (2005) Appl Surf Sci 243:204
Acknowledgements
Financial support from the Federal Ministry of Economics and Technology via the MEM-OXYCOAL project (grant no. 0327803) is gratefully acknowledged. The authors would like to thank Dr. Wessel for his valuable support with SEM characterization.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Huang, B.X., Chanda, A., Steinbrech, R.W. et al. Indentation strength method to determine the fracture toughness of La0.58Sr0.4Co0.2Fe0.8O3-δ and Ba0.5Sr0.5Co0.8Fe0.2O3-δ . J Mater Sci 47, 2695–2699 (2012). https://doi.org/10.1007/s10853-011-6095-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-011-6095-2