Journal of Materials Science

, Volume 47, Issue 4, pp 1621–1630 | Cite as

The influence of Zr layer thickness on contact deformation and fracture in a ZrN–Zr multilayer coating



In order to understand the influence of ductile metal interlayer on the overall deformation behavior of metal/nitride multilayer, different configurations of metal and nitride layers were deposited and tested under indentation loading. To provide insight into the trends in deformation with multilayer spacings, an FEM model with elastic-perfect plastic metal layers alternate with an elastic nitride on top of an elastic–plastic substrate. The strong strain mismatch between the metal and nitride layers significantly alters the stress field under contact loading leading to micro-cracking in the nitride, large tensile stresses immediately below the contact, and a transition from columnar sliding in thin metal films to a more uniform bending and microcracking in thicker coatings.


  1. 1.
    Shih KK, Dove DB (1992) Appl Phys Lett 61:654CrossRefGoogle Scholar
  2. 2.
    Wang X, Kolitsch A, Moller W (1997) Appl Phys Lett 71:1951CrossRefGoogle Scholar
  3. 3.
    Chen BF, Pan WL, Yu GP, Hwang J, Huang JH (1999) Surf Coat Technol 111:16CrossRefGoogle Scholar
  4. 4.
    Pan WL, Yu GP, Huang JH (1998) Surf Coat Technol 110:111CrossRefGoogle Scholar
  5. 5.
    Huang JH, Ma CH, Chen H (2006) Surf Coat Technol 200:5937CrossRefGoogle Scholar
  6. 6.
    Bemporad E, Sebastiani M, Pecchio C, SDe Rossi (2006) Surf Coat Technol 201:2155CrossRefGoogle Scholar
  7. 7.
    Bromark M, Larsson M, Hedenqvist P, Hogmark S (1997) Surf Coat Technol 90:217CrossRefGoogle Scholar
  8. 8.
    Köstenbauer H, Fontalvo GA, Keckes J, Mitterer C (2008) Thin Solid Films 516:1920CrossRefGoogle Scholar
  9. 9.
    Singh DRP, Deng X, Chawla N, Bai J, Hubbard C, Tang G, Shen YL (2010) Thin Solid Films 519:759CrossRefGoogle Scholar
  10. 10.
    Kim YJ, Byun TJ, Lee HL, Han JG (2008) Surf Coat Technol 202:5508CrossRefGoogle Scholar
  11. 11.
    Kot M, Rakowski WA, Major L, Major R, Morgiel J (2008) Surf Coat Technol 202:3501CrossRefGoogle Scholar
  12. 12.
    Kang Y, Lee C, Lee J (2000) Mater Sci Eng B75:17CrossRefGoogle Scholar
  13. 13.
    Wang X, Kolitsch A, Prokert F, Moller W (1998) Surf Coat Technol 103–104:334CrossRefGoogle Scholar
  14. 14.
    Abadias G, Pailloux F, Dub SN (2008) Surf Coat Technol 202:3683CrossRefGoogle Scholar
  15. 15.
    Caicedo JC, Amaya C, Yate L, Nos O, Gomez ME, Prieto P (2010) Mater Sci Eng B 171:56CrossRefGoogle Scholar
  16. 16.
    Cheng YH, Browne T, Heckerman B, Bowman C, Gorokhovsky V, Meletis EI (2010) Surf Coat Technol 205:146CrossRefGoogle Scholar
  17. 17.
    Wu ZG, Zhang GA, Wang MX, Fan XY, Yan PX, Xu T (2006) Appl Surf Sci 253:2733CrossRefGoogle Scholar
  18. 18.
    Alpas AT, Embury JD, Hardwick DA, Springer RW (1990) J Mater Sci 25:1603. doi:10.1007/BF01045357 CrossRefGoogle Scholar
  19. 19.
    Li DJ, Zhang JJ, Cao M (2007) Mater Lett 61:4344CrossRefGoogle Scholar
  20. 20.
    Mearini GT, Hoffman RW (1993) Thin Films J Elect Mater 22(6):625Google Scholar
  21. 21.
    Tang G, Shen YL, Singh DRP, Chawla N (2010) Acta Mater 58:2033CrossRefGoogle Scholar
  22. 22.
    Xie ZH, Hoffman M, Munroe P, Bendavid A, Martin PJ (2008) Acta Mater 56:852CrossRefGoogle Scholar
  23. 23.
    Bhattacharyya D, Mara NA, Dickerson P, Hoagland RG, Misra A (2010) Philos Mag 90:1711CrossRefGoogle Scholar
  24. 24.
    Fischer-Cripps AC (2002) Nanoindentation. Springer, New YorkGoogle Scholar
  25. 25.
    Oliver WC, Pharr GM (1992) J Mater Res 7:1564CrossRefGoogle Scholar
  26. 26.
    Abdelouahdi K, Buscema CL, Aubert P (2009) J Mater Sci 44:3408. doi:10.1007/s10853-009-3452-5 CrossRefGoogle Scholar
  27. 27.
    Wang J, Zhili W, Deli H (2000) J Mater Sci 35:2689. doi:10.1023/A:1004797724460 CrossRefGoogle Scholar
  28. 28.
    Sakharova NA, Fernandes JV, Oliveira MC, Antunes JM (2010) J Mater Sci 45:3812. doi:10.1007/s10853-010-4436-1 CrossRefGoogle Scholar
  29. 29.
    Castanho JM, Vieira MT (2003) J Mater Process Technol 143–144:352CrossRefGoogle Scholar
  30. 30.
    Tang G, Shen YL, Singh DRP, Chawla N (2008) Int J Mech Mater Des 4:391CrossRefGoogle Scholar
  31. 31.
    Matthews A, Jones R, Dowey S (2001) Tribol Lett 11:103CrossRefGoogle Scholar
  32. 32.
    Zhao X, Xie Z, Munroe P (2011) Mater Sci Eng A 528:1111CrossRefGoogle Scholar
  33. 33.
    Chawla N, Singh DRP, Shen YL, Tang G, Chawla KK (2008) J Mater Sci 43:4383. doi:10.1007/s10853-008-2450-3 CrossRefGoogle Scholar
  34. 34.
    Wang BT, Zhang P, Liu HY, Li WD, Zhang P (2011) J Appl Phys 109:063514CrossRefGoogle Scholar
  35. 35.
    Saldana L, Vilas AM, Jiang L, Multigner M, Carrasco JLG, Prado MTP, Martın MLG, Munuera L, Vilaboa N (2007) Biomaterials 28:4343CrossRefGoogle Scholar
  36. 36.
    Bolotina IO, Danilov VI, Zagumennyi AA (2008) J Appl Mech Tech Phys 4:484CrossRefGoogle Scholar
  37. 37.
    Product Data Bulletin, Nitronic30, UNS S20400Google Scholar
  38. 38.
    Math S, Jayaram V, Biswas SK (2006) J Mater Res 21:783CrossRefGoogle Scholar
  39. 39.
    Bhowmick S, Xie ZH, Hoffman M, Jayaram V, Biswas SK (2004) J Mater Res 19:2616CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  1. 1.Department of Materials EngineeringIndian Institute of ScienceBangaloreIndia

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