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Anatase formation on titanium by two-step thermal oxidation

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Abstract

Two-step thermal oxidation of commercially pure Ti was investigated with a focus on the formation of anatase. A first-step treatment was conducted in Ar–(0.1–20)%CO atmosphere at a temperature of 773–1173 K for a holding time of 0 or 86.4 ks, and a subsequent second-step treatment was conducted in air at 473–873 K for 0–86.4 ks. Titanium oxides and titanium oxycarbide were obtained in the first step, with relative amounts depending on heating temperature, holding time, and CO partial pressure. An anatase-rich layer on Ti was obtained after second-step treatment in air at 573–773 K in cases where single-phase titanium oxycarbide formed in the first step. Thus, the formation of single-phase titanium oxycarbide in the first step and temperature control in the second step were required for the formation of an anatase-rich layer. The bonding strength of an anatase-rich layer with a thickness of 0.5 μm was calculated to be around 90 MPa. This study reveals the conditions under which an anatase-rich layer with excellent adherence to Ti can be prepared by thermal oxidation.

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Acknowledgement

The authors would like to thank Dr. K. Kobayashi of Tohoku University for his study on TEM analyses. This study was financially supported by the Special Education and Research Program “Highly-functional Interface Science: Innovation of Biomaterials with Highly Functional Interface to Host and Parasite” of the Japan Society for the Promotion of Science (JSPS) and a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan, under Contract nos. 19360324 and 22360299.

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Authors and Affiliations

  1. Department of Materials Processing, Graduate School of Engineering, Tohoku University, 6-6-02 Aza Aoba, Aramaki, Aoba-ku, Sendai, 980-8579, Japan

    Takuro Okazumi, Kyosuke Ueda, Nobuyuki Umetsu & Takayuki Narushima

  2. Materials Research Institute for Sustainable Development, National Institute of Advanced Industrial Science and Technology (AIST), Nagoya, 463-8560, Japan

    Kazuki Tajima

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  1. Takuro Okazumi
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  2. Kyosuke Ueda
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  3. Kazuki Tajima
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  4. Nobuyuki Umetsu
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  5. Takayuki Narushima
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Correspondence to Takayuki Narushima.

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Okazumi, T., Ueda, K., Tajima, K. et al. Anatase formation on titanium by two-step thermal oxidation. J Mater Sci 46, 2998–3005 (2011). https://doi.org/10.1007/s10853-010-5177-x

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  • DOI: https://doi.org/10.1007/s10853-010-5177-x

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