Skip to main content
SpringerLink
Log in

Volume and thermal studies for tellurite glasses

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Binary tellurite glass systems of the forms TeO2(100 − x) − xAnOm where AnOm = La2O3 or V2O5 and x = 5, 7.5, 10, 12.5, 15, 17.5, and 20 mol% for La2O3 and 10, 20, 25, 30, 35, 40, 45, and 50 mol% for V2O5 were prepared. Density and molar volume of each glass were measured and calculated. The compressibility model has been used to find the difference volume Vd due to the exchange of one formula unit between Te and both of La and V in the binary glass system and the mean volume VA per formula unit in the present binary glass in order to check whether or not it is independent of the percentage of the modifier for a glass series and also different from series to another. Differential scanning calorimetric at different heating rates was used to gain some insight into the thermal stability and calorimetric behavior of the present binary transition metal and rare-earth tellurite glasses. The glass transformation temperature Tg and glass crystallization temperature Tc were recorded at different heating rates to calculate both of the glass transition activation and the glass crystallization activation energies by using different methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. El-Mallawany R (2002) Tellurite glass handbook: physical properties and data. CRC Press, FL, USA (International Materials Institute for New Functionality in Glass (IMI-NFG), Lehigh University, USA (2005) https://doi.org/www.lehigh.edu/imi/resources.htm)

  2. El-Mallawany R, Aboushely A, Rahamni A, Yousef E (1997) Phys Status Solidi A 163:377

    Article  CAS  Google Scholar 

  3. El-Mallawany R (1992) J Mater Res 7:224

    Article  CAS  Google Scholar 

  4. El-Mallawany R (1995) J Mater Sci Electron 6:1

    Article  CAS  Google Scholar 

  5. El-Mallawany R, Hagar I, Poulain M (2002) J Mater Sci 37:3291. doi:https://doi.org/10.1023/A:1016195303433

    Article  CAS  Google Scholar 

  6. El-Mallawany R (2000) Phys Status Solidi A 177:439

    Article  CAS  Google Scholar 

  7. El-Mallawany R (2000) Mater Chem Phys 63:109

    Article  CAS  Google Scholar 

  8. El-Mallawany R (2003) J Mater Res 18(2):402

    Article  CAS  Google Scholar 

  9. El Mallawany R, Abbas Ahmed I (2008) J Mater Sci 43:5131. doi:https://doi.org/10.1007/s10853-008-2737-4s

    Article  CAS  Google Scholar 

  10. Moawad H, Jain H, El-Mallawany R, Ramadan T, ElSherbine M (2002) J Am Ceram Soc 85:11

    Google Scholar 

  11. Moawad H, Jain H, El-Mallawany R (2009) J Phys Chem Solids 70:224

    Article  CAS  Google Scholar 

  12. Kim S, Yako T, Sakka S (1993) J Am Ceram Soc 76:2486

    Article  CAS  Google Scholar 

  13. Lambson EF, Saunders GA, Bridge B, El-Mallawany RA (1984) J Non-Cryst Solids 69:117

    Article  CAS  Google Scholar 

  14. Havinga E (1961) J Phys Chem Solids 18:253

    Article  CAS  Google Scholar 

  15. Mukherjee S, Ghosh U, Basu C (1992) J Mater Sci Lett 11:985

    Article  CAS  Google Scholar 

  16. Bridge B, Higazy AA (1986) J Phys Chem Glasses 27:1

    CAS  Google Scholar 

  17. Kozhukharov VS, Nikolov S, Marinov M (1979) J Mater Res Bull 14:735

    Article  CAS  Google Scholar 

  18. Beyer H (1967) Z Kristallogr 124:228

    Article  CAS  Google Scholar 

  19. Johnson PAV, Wright AC, Yarker CA, Sincair RN (1986) J Non-Cryst Solids 81:163

    Article  CAS  Google Scholar 

  20. Lasocka M (1979) Mater Sci Eng 23:173

    Article  Google Scholar 

  21. Kissinger HE (1956) J Res NBS 57:217

    CAS  Google Scholar 

  22. Chen H (1978) J Non-Cryst Solids 27:257

    Article  CAS  Google Scholar 

  23. Shelby J (1979) J Non-Cryst Solids 34:111

    Article  CAS  Google Scholar 

  24. Moynihan CT, Easteal AJ, Wider J, Tucker J (1974) J Phys Chem 78:2673

    Article  CAS  Google Scholar 

  25. Ozawa T (1965) Bull Chem Soc Jap 38:351

    Article  Google Scholar 

  26. Coats W, Redfern JP (1964) Nature 201:86

    Article  Google Scholar 

  27. Kissinger HE (1957) Anal Chem 29:1702

    Article  CAS  Google Scholar 

  28. Goodman CHN (1987) J Glass Technol 28:19 (1987)

    CAS  Google Scholar 

  29. El-Mallawany R, El-Khokany N, Afifi H (2006) Mater Chem Phys 95:321

    Article  CAS  Google Scholar 

  30. Sidky M, El-Mallawany R, Abousehly A, Saddeek Y (2002) Mater Chem Phys 74:222

    Article  Google Scholar 

  31. Sidky M, El-Mallawany R, Abousehly A, Saddeek Y (2002) Glass Sci Technol 75:87

    Google Scholar 

  32. Abdel Kader A, El-Mallawany R, ElKholy M (1993) J Appl Phys 73:75

    Article  CAS  Google Scholar 

  33. Hampton R, Hong W, Saunders G, El-Mallawany R (1987) J Non-Cryst Solids 94:307

    Article  CAS  Google Scholar 

  34. Hampton R, Hong W, Saunders G, El-Mallawany R (1988) Phys Chem Glasses 29:100

    CAS  Google Scholar 

  35. ElKholy M, El-Mallawany R (1995) Mater Chem Phys 40:163

    Article  CAS  Google Scholar 

  36. El-Mallawany R, El-Deen LS, Elkholy M (1996) J Mater Sci 31:6339. doi:https://doi.org/10.1007/BF00354458

    Article  CAS  Google Scholar 

  37. El-Mallawany R, El-Said Adly, El-Gawad M (1995) Mater Chem Phys 41:87

    Article  CAS  Google Scholar 

  38. Abdel Kader A, El-Mallawany R, ElKholy M (1994) Mater Chem Phys 36:365

    Article  CAS  Google Scholar 

  39. Sooraj Hussain N, Hungerford G, El-Mallawany R, Gomes MJM, Lopes MA, Ali N, Santos JD, Buddhudu S (2008) J Nanosci Nanotechnol 8:1

    Article  Google Scholar 

  40. El-Mallawany R, Dirar Abdalla M, Abbas Ahmed I (2008) Mater Chem Phys 109:291

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Physics Department, Faculty of Science, Menoufia University, Shebin El-Koom, Egypt

    R. El-Mallawany, A. Abdel-Kader, M. El-Hawary & N. El-Khoshkhany

Authors
  1. R. El-Mallawany
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Abdel-Kader
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. El-Hawary
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. El-Khoshkhany
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R. El-Mallawany.

Additional information

A. Abdel-Kader—deceased.

Rights and permissions

Reprints and permissions

About this article

Cite this article

El-Mallawany, R., Abdel-Kader, A., El-Hawary, M. et al. Volume and thermal studies for tellurite glasses. J Mater Sci 45, 871–887 (2010). https://doi.org/10.1007/s10853-009-4015-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-009-4015-5

Keywords

Search

Navigation