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Preparation and catalytic activity of nanostructured Pd catalysts supported on hydrogenotitanate nanotubes

  • Mesostructured Materials
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Abstract

Nanostructured palladium particles (nanorods, icosahedra, cubes) were synthesized in aqueous solution using a seeding-mediated approach with a structure-directing agent. These nanostructured Pd particles were then impregnated onto hydrogenotitanate nanotubes using two different impregnation procedures. The as-prepared catalysts were then tested in the selective hydrogenation of cinnamaldehyde at 323 K under 10 bars of H2. The selectivity is influenced by the morphology of the Pd nanostructured particles with a higher selectivity into saturated alcohols when the proportion of (111) Pd sites increases.

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Acknowledgement

This work has been supported by the “Action Intégrée Franco-Tunisienne du Ministère des Affaires Étrangères et Européennes Français et du Ministère de l’Enseignement Supérieur de la Recherche Scientifique et de la Technologie Tunisien”.

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Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux et Catalyse, Faculté des Sciences de Tunis, 2092, ElManar, Tunis, Tunisie

    Khaled Jabou & Abdelhamid Ghorbel

  2. Institut National de Recherche et d’Analyse Physico-Chimique, Pôle Technologique, 2020, Sidi Thabet, Ariana, Tunisie

    Hafedh Kochkar

  3. Institut de Recherches sur la Catalyse et l’Environnement de Lyon, UMR 5256 CNRS Université de Lyon, Villeurbanne, 69100, France

    Gilles Berhault

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  1. Khaled Jabou
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  2. Hafedh Kochkar
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  3. Gilles Berhault
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  4. Abdelhamid Ghorbel
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Correspondence to Hafedh Kochkar.

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Jabou, K., Kochkar, H., Berhault, G. et al. Preparation and catalytic activity of nanostructured Pd catalysts supported on hydrogenotitanate nanotubes. J Mater Sci 44, 6677–6682 (2009). https://doi.org/10.1007/s10853-009-3632-3

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  • DOI: https://doi.org/10.1007/s10853-009-3632-3

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