Abstract
Multiferroic BaTiO3/CoFe2O4 superlattice films are deposited by laser molecular beam epitaxy. The film growth modes are studied by in situ reflection high energy electron diffraction and the film structures are revealed by high resolution transmission electron microscopy study. Ferroelectric switching behavior was studied by piezoresponse force microscopy, and it shows that good ferroelectricity was retained in the superlattice. Such a multiferroic superlattice also shows a magnetic exchange coupling under room temperature. Detailed analysis reveals that different growth modes and the substrate strain effect may be responsible for the magnetic exchange coupling.
Similar content being viewed by others
References
Spaldin NA, Fiebig M (2005) Science 309:391
Wang J, Neaton JB, Zheng H, Nagarajan V, Ogale SB, Liu B, Viehland D, Vaithyanathan V, Schlom DG, Waghmare UV, Spaldin NA, Rabe KM, Wuttig M, Ramesh R (2003) Science 299:1719
Zavaliche F, Zheng H, Mohaddes-Ardabili L, Yang SY, Zhan Q, Shafer P, Reilly E, Chopdekar R, Jia Y, Wright P, Schlom DG, Suzuki Y, Ramesh R (2005) Nano Lett 5:1793
Chaudhuri AR, Ranjith R, Krupanidhi SB, Mangalam RVK, Sundaresan A (2007) Appl Phys Lett 90:122902
Zhang JX, Dai JY, Lu W, Chan HLW, Wu B, Li DX (2008) J Phys D Appl Phys 41:235405
Ren SQ, Weng LQ, Song S-H, Li F, Wan JG, Zeng M (2005) J Mater Sci 40:4375. doi:https://doi.org/10.1007/s10853-006-7897-5
Lee HN, Christen HM, Chisholm MF, Rouleau CM, Lowndes DH (2005) Nature 433:395
Stengel M, Spaldin NA (2006) Nature 443:679
Yang H, Chi ZH, Jiang JL, Feng WJ, Dai JF, Jin CQ, Yu RC (2008) J Mater Sci 43:3604. doi:https://doi.org/10.1007/s10853-008-2571-8
Fong DD, Stephenson GB, Streiffer SK, Eastman JA, Auciello O, Fuoss PH, Thompson C (2004) Science 304:1650
Voogt FC, Palstra TTM, Niesen L, Rogojanu OC, James MA, Hibma T (1998) Phys Rev B 57:R8107
Ramesh R, Spaldin N (2007) Nature Mater 6:21
van der Heijden PAA, Bloemen PJH, Metselaar JM, Wolf RM, Gaines JM, van Eemeren JTWM, van der Zaag PJ, de Jonge WJM (1997) Phys Rev B 55:11569
Huang W, Zhu J, Zeng HZ, Wei XH, Zhang Y, Li YR, Hao JH (2008) Scr Mater 58:1118
Shimuta T, Nakagawara O, Makino T, Arai S (2002) J Appl Phys 91:2290
Nakagawara O, Shimuta T, Makino T, Arai S (2000) Appl Phys Lett 77:3257
Ortega N, Kumar A, Katiyar RS, Scott JF (2007) Appl Phys Lett 91:102902
Zhang JX, Dai JY, Chow CK, Sun CL, Lo VC, Chan HLW (2008) Appl Phys Lett 92:022901
Kumar V, Rana A, Yadav MS, Pant RP (2008) J Magn Magn Mater 320:1729
Zhang JX, Dai JY, Chan HLW, Phys Rev B (revised)
Cullity BD (1972) Introduction to magnetic materials. Addison-Wesley Publishing Company, Reading, MA, p 266
Vavassori P, Bonanni V, Busato A, Bisero D, Gubbiotti G, Adeyeye AO, Goolaup S, Singh N, Spezzani C, Sacchi M (2008) J Phys D Appl Phys 41:134014
Wu H-C, Arora SK, Mryasov ON, Shvets IV (2008) Appl Phys Lett 92:182502
Acknowledgement
The authors would like to thank the financial support from the collaboration project grant between the Hong Kong Polytechnic University and Beijing Institute of Technology (No. 1-BB84). J. Y. Dai is grateful to the financial support from the Hong Kong GRF grant: PolyU 5005/08P.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Zhang, J.X., Dai, J.Y., Lu, W. et al. Room temperature magnetic exchange coupling in multiferroic BaTiO3/CoFe2O4 magnetoelectric superlattice. J Mater Sci 44, 5143–5148 (2009). https://doi.org/10.1007/s10853-009-3512-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-009-3512-x