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Effect of Ag on the electrical properties of a-Ge20Se80 glasses

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Abstract

This article reports the effect of Ag impurity (low ~4 and ~6 at.% and high ~10 at.%) on the ac conductivity (σac) of a-Ge20Se80 glass. Frequency (ω)-dependent ac conductance and capacitance of the samples over a frequency range ~100 Hz to 50 kHz was taken in the temperature range ~268–358 K. At frequency 2 kHz and temperature 298 K, the value of σac increases at low as well as at higher concentration of Ag. The σac is proportional to ωs for undoped and doped samples. The value of frequency exponent (s) decreases as the temperature increases.

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References

  1. Calvez L, Ma HL, Lucas J, Zhang XH (2007) Adv Mater 19:129

    Article  CAS  Google Scholar 

  2. Calvez L, Lucas P, Roze M, Ma HL, Lucas J, Zhang XH (2007) J Appl Phys A 89:183

    Article  CAS  Google Scholar 

  3. Nemcsics A, Kovacs S, Labadi Z, Hesse KF, Czank M, Turmezei P, Motrya S (2005) Solar Energy Mater Solar Cells 89:175

    Article  CAS  Google Scholar 

  4. Street RA, Mott NF (1975) Phys Rev Lett 35:1293

    Article  CAS  Google Scholar 

  5. Kastner M, Adler D, Fritzsche H (1976) Phys Rev Lett 37:1504

    Article  CAS  Google Scholar 

  6. Frumar M, Wagner T (2003) Curr Opin Solid State Mater Sci 7:117

    Article  CAS  Google Scholar 

  7. Boolchand P, Bresser WJ (2001) Nature 410:1070

    Article  CAS  Google Scholar 

  8. Bunde A, Funke K, Ingram MD (1998) Solid State Ionics 1:105

    Google Scholar 

  9. Urena MA, Fontana M, Arcondo B, Clavaguera-Mora MT (2003) J Non-Cryst Solids 151:320

    Google Scholar 

  10. Wang Y et al (2003) J Phys Condens Matter 15:S1573

    Article  CAS  Google Scholar 

  11. Dejus RJ et al (1992) J Non-Cryst Solids 143:162

    Article  CAS  Google Scholar 

  12. Westwood JD, Gergopoulos P, Whitmore DH (1988) J Non-Cryst Solids 107:88

    Article  CAS  Google Scholar 

  13. Dejus RJ, Susman S, Volin K, Montague D, Price D (1992) J Non-Cryst Solids 143:162

    Article  CAS  Google Scholar 

  14. Piarristeguy A, Mirandou M, Fontana M, Arcondo B (2000) J Non-Cryst Solids 273:30

    Article  CAS  Google Scholar 

  15. Mitkova M, Wang Y, Boolchand P (1999) Phys Rev Lett 83:3848

    Article  CAS  Google Scholar 

  16. Shimakawa K (1982) Philos Mag B 46:123

    Article  CAS  Google Scholar 

  17. Shimakawa K (1983) Philos Mag B 48:778

    Article  Google Scholar 

  18. Bourne LC, Rowland SC, Bienenstock A (1981) J Phys Colloque C4:951

    Google Scholar 

  19. Dejus RJ, Lepoire DJ, Susman S, Volin K, Price DL (1991) Phys Rev B Condens Matter 44:11705

    Article  CAS  Google Scholar 

  20. Dejus RJ, Lepoire DJ, Price DL, Susman S, Volin K (1989) J Non-Cryst Solids 114:37

    Article  CAS  Google Scholar 

  21. Ibanez A, Armand P, Philippot E, Dexpert H (1993) Solid State Ionics 59:157

    Article  CAS  Google Scholar 

  22. Peyroutou C, Peytavin S, Ribes M, Dexpert H (1989) J Solid State Chem 82:70

    Article  CAS  Google Scholar 

  23. Walter U, Price DL, Susman S, Volin KJ (1988) Phys Rev B 37:4232

    Article  CAS  Google Scholar 

  24. Kumagai N, Shirafuji J, Inuishi Y (1977) J Phys Soc Jpn 42:1261

    Article  Google Scholar 

  25. Kawasaki M, Kawamura J, Nakamura Y, Aniya M (1999) Solid State Ionics 123:259

    Article  CAS  Google Scholar 

  26. Armand P, Ibanez A, Dexpert H, Bittencourt D, Raoux D, Philippot E (1992) J Phys IV Colloque C22:2

    Google Scholar 

  27. Mirandou M, Fontana M, Arcondo B (2003) J Mater Process Technol 143–144:420

    Article  Google Scholar 

  28. Pattanayak P, Asokan S (2005) J Appl Phys 97:013515

    Article  Google Scholar 

  29. Borisova ZU, Rykova TS, Turkina EYu, Tabolin AR (1984) Izv Akad Nauk SSR Neorg Mater 20:1796

    CAS  Google Scholar 

  30. Bychkov E, Tsegelink V, Vlasov Y, Pradel A, Ribes M (1996) J Non-Cryst Solids 208:1

    Article  CAS  Google Scholar 

  31. Piarristeguy A, Ramonda M, Kuwata N, Pradel A, Ribes M (2006) Solid State Ionics 177:3157

    Article  CAS  Google Scholar 

  32. Pradel A, Kuwata N, Ribes M (2003) J Phys Condens Matter 15:S1561

    Article  CAS  Google Scholar 

  33. Wagner T, Jilkova R, Frumer M, Vlcek M (1994) Int J Electron 77:185

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This work was financially supported by the C.S.I.R. (major project), New Delhi.

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Correspondence to S. K. Tripathi.

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Singh, G., Goyal, N., Saini, G.S.S. et al. Effect of Ag on the electrical properties of a-Ge20Se80 glasses. J Mater Sci 44, 3376–3381 (2009). https://doi.org/10.1007/s10853-009-3441-8

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  • DOI: https://doi.org/10.1007/s10853-009-3441-8

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