Abstract
We report on spectroscopic study of pyrolytic hBN (pBN) by means of time- and energy-resolved photoluminescence methods. A high purity pBN samples (though low crystallinity) allow complementary information about excited states involved into the luminescence process. We affirm our recent conclusions about the impurity-related nature of most of fluorescence bands in microcrystalline hBN. In addition, a broad band centred at 3.7 eV previously not considered because of its superposition with an intense structured impurity emission is attributed to the radiative recombination of deep DAPs.
Similar content being viewed by others
References
Watanabe K, Taniguchi T, Kanda H (2004) Nat Mater 3:404
Jaffrennou P, Barjon J, Lauret JS, Attal-Tretout B, Ducastelle F, Loiseau A (2007) J Appl Phys 102:116102
Silly MG, Jaffrennou P, Barjon J, Lauret JS, Ducastelle F, Loiseau A, Obraztsova E, Attal-Tretout B, Rosencher E (2007) Phys Rev B Condens Matter Mater Phys 75:085205
Lukomskii AI, Shipilo VB, Gameza LM (1993) J Appl Spectrosc 57:607
Larach S, Shrader RE (1956) Phys Rev 102:582
Museur L, Kanaev AV (2008) J Appl Phys 103:103520
Museur L, Anglos D, Petitet JP, Michel JP, Kanaev AV (2007) J Luminescence 127:595
Kanaev AV, Petitet JP, Museur L, Marine V, Solozhenko VL, Zafiropulos V (2004) J Appl Phys 96:4483
Wu J, Han W, Walukiewicz W, Ager JW, Shan W, Haller EE, Zettl A (2004) Nano Lett 4:647
Yao B, Shen ZX, Liu L, Su WH (2004) J Phys Condens Matter 16:2181
Solozhenko VL, Lazarenko AG, Petitet JP, Kanaev AV (2001) J Phys Chem Solids 62:1331
Larach S, Shrader RE (1956) Phys Rev 104:68
Museur L, Feldbach E, Kanaev A (2008) Phys Rev B 78:155204
Museur L, Petitet J-P, Michel J-P, Marine W, Anglos D, Fotakis C, Kanaev AV (2008) J Appl Phys 104:093504
Moore AW (1990) J Cryst Growth 106:6
Le Gallet S, Chollon G, Rebillat F, Guette A, Bourrat X, Naslain R, Couzi M, Bruneel JL (2004) J Eur Ceram Soc 24:33
Zimmerer G (1991) Nucl Instrum Methods Phys Res A 308:178
Zimmerer G (2007) Radiat Meas 42:859
Nemanich RJ, Solin SA, Martin RM (1981) Phys Rev B 23:6348
Stepanov VA, Stepanov PA (1998) Opt Spectrosc 85:893
Kobayashi H, Shibata H, Tagawa S (1994) Nucl Instrum Methods Phys Res B 90:556
Watanabe K, Taniguchi T, Kanda H (2004) Phys Status Solidi A 201:2561
Kubota Y, Watanabe K, Tsuda O, Taniguchi T (2007) Science 317:932
Arnaud B, Lebègue S, Rabiller P, Alouani M (2006) Phys Rev Lett 96:026402
Pankove JI (1971) Optical processes in semiconductors. Dover Publications, New York
Taylor CA, Brown SW, Subramaniam V, Kidner S, Rand SC, Clarke R (1994) Appl Phys Lett 65:1251
Zunger A, Katzir A, Halperin A (1976) Phys Rev B 13:5560
Reshchikov MA, Yi GC, Wessels BW (1999) Phys Rev B 59:13176
Remes Z, Nesladek M, Haenen K, Watanabe K, Taniguchi T (2005) Phys Status Solidi A Appl Mater Sci 202:2229
Lopatin VV, Konusov FV (1992) J Phys Chem Solids 53:847
Zhi CY, Bando Y, Tang CC, Golberg D, Xie RG, Sekigushi T (2005) Appl Phys Lett 86:213110
Berzina B, Trinkler L, Korsak V, Krutohvostov R, Carroll DL, Ucer KB, Williams RT (2006) Phys Status Solidi B Basic Solid State Phys 243:3840
Watanabe K, Taniguchi T, Kuroda T, Kanda H (2006) Appl Phys Lett 89:141902
Taniguchi T, Watanabe K (2007) J Cryst Growth 303:525
Zunger A, Katzir A (1975) Phys Rev B 11:2378
Acknowledgements
This work has been supported by the IHP-Contract HPRI-CT-1999-00040 of the European Commission. The authors are grateful to G. Stryganyuk for assistance in conducting experiments at SUPERLUMI station and to V. Solozhenko for helpful discussions and the kindly providing pyrolytic boron nitride samples.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Museur, L., Kanaev, A. Photoluminescence properties of pyrolytic boron nitride. J Mater Sci 44, 2560–2565 (2009). https://doi.org/10.1007/s10853-009-3334-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-009-3334-x