Abstract
It is of interest to determine whether the prediction of long-term creep failure from short-term fatigue experiments, as established for polyethylene in air, can be extended to environmental liquids. This article was undertaken to characterize the mechanism of creep crack growth in an environmental liquid at 50 °C and to determine whether the mechanism was conserved in fatigue as required for the fatigue-to-creep correlation. For this purpose, creep and fatigue tests at R-ratio (the ratio of minimum to maximum load in the fatigue cycle) of 1.0 (creep) and 0.1 were performed in air, water, and aqueous Igepal CO-630 (Igepal-630) solutions at various concentrations. It was found that fatigue and creep followed the same stepwise crack growth mechanism as in air in all the Igepal-630 concentrations studied. In air and water, fatigue substantially accelerated the crack growth kinetics compared to creep. A fatigue acceleration effect was also seen with the lower Igepal-630 concentrations. However, the acceleration effect lessened as the concentration increased to 0.05 vol.% due to the combined effects of the gradually decreasing creep lifetime and the gradually increasing fatigue lifetime. Above 0.05%, the lifetimes in creep and fatigue decreased in parallel with the fatigue lifetime only slightly lower than the creep lifetime. It appeared that Igepal-630 reduced the frictional resistance to chain slippage to the extent that any significant strain rate sensitivity was lost. Increasing the molecular weight had the equivalent effect of decreasing the Igepal-630 concentration. This was probably a kinetic effect related to the diffusion of the stress cracking liquid.
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References
Lustiger A (1986) In: Brostow W, Corneliussen RD (eds) Failure of plastics. Hanser Publications, NY
Williams JG, Marshall GP (1975) Pro R Soc Lond A 55:1975
Shanahan MER, Schultz J (1979) J Polym Sci Polym Phys 17:705
Qian R, Lu X, Brown N (1993) Polymer 34:4727
Hittmair P, Ullman R (1962) J Appl Polym Sci 6:1
Ward AL, Lu X, Huang Y, Brown N (1991) Polymer 32:2172
Ward AL, Lu X, Huang Y, Brown N (1990) Polym Eng Sci 30:1175
Chan MKV, Williams JG (1983) Polymer 24:234
Tonyali K, Rogers CE, Brown HR (1989) J Macromol Sci Phys B 28:235
Lustiger A, Corneliussen RD (1987) J Mater Sci 22:2470. doi:https://doi.org/10.1007/BF01082132
Brown H (1978) Polymer 19:1186
Tonyali K, Rogers CE, Brown HR (1987) Polymer 28:1472
Mai YW, Williams JG (1979) J Mater Sci 14:1933. doi:https://doi.org/10.1007/BF00551034
Altstaedt V, Keiter S, Renner M, Schlarb A (2004) Macromol Symp 214:31
Parsons M, Stepanov EV, Hiltner A, Baer E (1999) J Mater Sci 34:3315. doi:https://doi.org/10.1023/A:1004616728535
Parsons M, Stepanov EV, Hiltner A, Baer E (2000) J Mater Sci 35:1857. doi:https://doi.org/10.1023/A:1004741713514
Parsons M, Stepanov EV, Hiltner A, Baer E (2000) J Mater Sci 35:2659. doi: https://doi.org/10.1023/A:1004789522642
Ayyer R, Hiltner A, Baer E (2007) J Mater Sci 42:7004. doi: https://doi.org/10.1007/s10853-006-1108-2
Shah A, Stepanov EV, Hiltner A, Baer E, Klein M (1997) Int J Fract 84:159
Parsons M, Stepanov EV, Hiltner A, Baer E (2001) J Mater Sci 36:5747. doi: https://doi.org/10.1023/A:1012935517866
Shah A, Stepanov EV, Capaccio G, Hiltner A, Baer E (1998) J Polym Sci B Polym Phys 36:2355
Brown N, Ward IM (1983) J Mater Sci 18:1405. doi:https://doi.org/10.1007/BF01111960
Berger LL, Kramer EJ (1987) Macromolecules 20:1980
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Ayyer, R., Hiltner, A. & Baer, E. Effect of an environmental stress cracking agent on the mechanism of fatigue and creep in polyethylene. J Mater Sci 43, 6238–6253 (2008). https://doi.org/10.1007/s10853-008-2926-1
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DOI: https://doi.org/10.1007/s10853-008-2926-1