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Synthesis of lamellar mesostructured calcium phosphates using n-alkylamines as structure-directing agents in alcohol/water mixed solvent systems

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Abstract

Lamellar mesostructured calcium phosphates constructed by ionic bonds were prepared by using n-alkylamines (n-CnH2n+1NH2, n = 8–18) at room temperature in the mixed solvent systems of aliphatic alcohol (CnH2n+1OH, n = 1–4) and water, and the synthetic conditions were investigated in detail. The mixed solvent systems suppressed the formation of crystalline calcium phosphates like brushite (CaHPO4·2H2O) and monetite (CaHPO4) at low temperatures, successfully affording pure lamellar mesostructured calcium phosphates. Other crystalline phases such as hydroxyapatite (Ca10(PO4)6(OH)2) were not formed under the conditions with the Ca/P molar ratios in the range of 0.7–1.0 in the starting mixtures. The Ca/P molar ratio of the lamellar mesostructured calcium phosphates was ca. 1.0, calculated by ICP and 31P MAS NMR data. Interestingly, the kind of alcohols strongly influenced the solubilities of calcium phosphate species and n-alkylamines, and then lamellar mesostructured phases were obtained with some morphological variation.

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Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, 739-8527, Japan

    Nobuaki Ikawa, Yasunori Oumi & Tsuneji Sano

  2. National Institute of Advanced Industrial Science and Technology (AIST), Shimoshidami, Moriyama-ku, Nagoya, 463-8560, Japan

    Tatsuo Kimura

  3. AIST, Tohoku, Nigatake, Miyagino-ku, Sendai, 983-8551, Japan

    Takuji Ikeda

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  1. Nobuaki Ikawa
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  2. Yasunori Oumi
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  4. Takuji Ikeda
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Correspondence to Tsuneji Sano.

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Ikawa, N., Oumi, Y., Kimura, T. et al. Synthesis of lamellar mesostructured calcium phosphates using n-alkylamines as structure-directing agents in alcohol/water mixed solvent systems. J Mater Sci 43, 4198–4207 (2008). https://doi.org/10.1007/s10853-008-2602-5

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