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Phase developments in Pb(Mg1/2W1/2)O3 and Pb(Zn1/2W1/2)O3 via B-site precursor route

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Abstract

Phase formation stages of MgWO4 and ZnWO4 (precursor compositions for following steps) were investigated by monitoring the reactions of oxide chemicals at various temperatures. Developed phases were examined by using X-ray diffraction (XRD). Successive attempts were also conducted for Pb(Mg1/2W1/2)O3 (PMW) and Pb(Zn1/2W1/2)O3 (PZW) by reacting PbO with the precursor compounds. Stages of phase development in the two compositions were also analyzed. The results are compared with those of another tungsten-containing perovskite Pb(Fe2/3W1/3)O3 (PFW) and its B-site precursor Fe2WO6. After PbO addition to the precursor powders, a perovskite phase formed directly (i.e., without any intermediate phases) in the case of PMW. For PbO + ½ZnWO4, in contrast, the decomposition of ZnWO4 and preferential reaction with PbO resulted in Pb2WO5 and ZnO, instead of the perovskite PZW.

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References

  1. Shuvalov LA, Minaeva KA (1963) Sov Phys-Dokl 7(10):906

    Google Scholar 

  2. Agranovskaya AI (1960) Bull Acad Sci USSR, Phys Ser 24:1271

    Google Scholar 

  3. Isupov VA (1963) Sov Phys-Solid State 5:136

    Google Scholar 

  4. Inada M (1977) Jpn Natl Tech Rept 27:95

    Google Scholar 

  5. Lejeune M, Boilot JP (1982) Ceram Int 8:99

    Article  CAS  Google Scholar 

  6. Swartz SL, Shrout TR (1982) Mater Res Bull 17:1245

    Article  CAS  Google Scholar 

  7. Lejeune M, Boilot JP (1983) Ceram Int 9:119

    Article  CAS  Google Scholar 

  8. Lejeune M, Boilot JP (1984) Ferroelectrics 54:191

    Article  Google Scholar 

  9. Kim N-K (1997) Mater Lett 32:127

    Article  CAS  Google Scholar 

  10. Ananta S, Brydson R, Thomas NW (1999) J Eur Ceram Soc 19:355

    Article  CAS  Google Scholar 

  11. Yu Y, Feng C, Li C, Yang Y, Yao W, Yan H (2001) Mater Lett 51:490

    Article  CAS  Google Scholar 

  12. Babushkin O, Lindbaeck T, Luc J-C, Leblais J-Y M (1998) J Eur Ceram Soc 18:737

    Article  CAS  Google Scholar 

  13. Yonezawa M, Ohno T (1982) Japan-US Study Seminar on Dielectric and Piezoelectric Ceramics, T-8, 1–4

  14. Kassarjian MP, Newnham RE, Biggers JV (1985) Am Ceram Soc Bull 64:1108

    CAS  Google Scholar 

  15. Fu S-L, Chen G-F (1988) Ferroelectrics 82:119

    Article  CAS  Google Scholar 

  16. Lee B-H, Kim N-K, Kim J-J, Cho S-H (1998) Ferroelectrics 211:233

    Article  CAS  Google Scholar 

  17. Lu C-H, Shinozaki K, Kato M, Mizutani N (1991) J Mater Sci 26:1009. doi:https://doi.org/10.1007/BF00576779

    Article  CAS  Google Scholar 

  18. Lu C-H, Shinozaki K, Mizutani N (1992) J Am Ceram Soc 75:1303

    Article  CAS  Google Scholar 

  19. Park B-O, Kim N-K (1999) Mater Lett 40:246

    Article  CAS  Google Scholar 

  20. Park T-K, Kim N-K, Lee C-H, Lee J-Y (2005) Mater Lett 59:588

    Article  CAS  Google Scholar 

  21. Ananta S, Thomas NW (1999) J Eur Ceram Soc 19:155

    Article  CAS  Google Scholar 

  22. Halliyal A, Kumar U, Newnham RE, Cross LE (1987) Am Ceram Soc Bull 66:671

    CAS  Google Scholar 

  23. Shrout TR, Halliyal A (1987) Am Ceram Soc Bull 66:704

    CAS  Google Scholar 

  24. Smith WF (1990) Principles of materials science and engineering, 2nd edn. McGraw-Hill, Singapore, p 37

    Google Scholar 

  25. Shannon RD (1976) Acta Crystallogr A 32:751

    Article  Google Scholar 

  26. Kim N-K, Payne DA (1990) J Mater Res 5:2045

    Article  CAS  Google Scholar 

Download references

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  1. School of Materials Science and Engineering, Kyungpook National University, Daegu, 702-701, Korea

    Woo-Joon Lee & Nam-Kyoung Kim

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  1. Woo-Joon Lee
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  2. Nam-Kyoung Kim
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Correspondence to Nam-Kyoung Kim.

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Lee, WJ., Kim, NK. Phase developments in Pb(Mg1/2W1/2)O3 and Pb(Zn1/2W1/2)O3 via B-site precursor route. J Mater Sci 43, 3608–3611 (2008). https://doi.org/10.1007/s10853-008-2574-5

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  • DOI: https://doi.org/10.1007/s10853-008-2574-5

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