Abstract
A versatile approach to the synthesis of YBCO (high temperature superconductor ceramics) nanofibers via electrospinning a polymer precursor solution is reported. The aqueous polymer precursor solution consists of poly(acrylic acid) (PAAc) and a mixture of yttrium nitrate, barium nitrate, and copper nitrate, henceforth termed (Y,Ba,Cu)–N. The conductivity of the polymer precursor solution at 27.1 °C was 14.70 mS/cm, its zero shear viscosity was 52.00 cP, and its pH was 1.88. Typical YBCO nanofibers were 50–100 nm in diameter and around of 10 μm length. The nanofibers also contain relatively small amounts of yttrium oxide and copper yttrium oxide.
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Xu TT, Zheng JG, Wu NQ, Nicholls AW, Roth JR, Dikin DA, Ruoff RS (2004) Nano Lett 4:963
Martin CR (1994) Science 266:1961
Bezryadin A, Lau CN, Tinkham M (2000) Nature 404:971
Larsson P, Nilsson B, Ivanov ZG (2000) J Vac Sci Technol B 18:25
Von Lampe I, Wasche M, Lorkowski HJ (1993) Acta Polym 44:148
Chaudhari P, Koch RH, Laibowitz RB, McGuire TR, Gambino RJ (1987) Phys Rev Lett 58:2684
Xia YN, Yang PD, Sun YG, Wu YY, Mayers B, Gates B, Yin YD, Kim F, Yan YQ (2003) Adv Mater 15:353
Von Lampe I, Schultze D, Zygalsky F, Silverstein MS (2003) Polym Degrad Stab 81:57
Von Lampe I, Gotze S, Zygalsky F (1996) J Low Temp Phys 105:1289
Silverstein MS, Najary Y, Grader GS, Shter GE (2004) J Polym Sci Part B-Polym Phys 42:1023
Silverstein MS, Najary Y, Lumelsky Y, von Lampe I, Grader GS, Shter GE (2004) Polymer 45:937
Lumelsky Y, Silverstein MS (2006) J Mater Sci 41:8202
Dubinsky S, Lumelsky Y, Grader GS, Shter GE, Silverstein MS (2005) J Polym Sci Part B-Polym Phys 43:1168
Dubinsky S, Grader GS, Shter GE, Silverstein MS (2004) Polym Degrad Stab 86:171
Goto T, Kada M (1987) Jpn J Appl Phys Part 2-Lett 26:L1527
Sakar A, Peterson T (1992) Polym Eng Sci 32:305
Catania P, Hovnanian N, Cot L (1990) Eur J Solid State Inorg Chem 27:659
Chien JCW, Gong BM, Mu XG, Yang YS (1990) J Polym Sci Part A-Polym Chem 28:1999
Chien JCW, Gong BM, Yang YS, Cabrera I, Effing J, Ringsdorf H (1990) Adv Mater 2:305
Li D, Xia YN (2004) Adv Mater 16:1151
Reneker DH, Yarin AL, Zussman E, Xu H (2007) Adv Appl Mech 41:43
Ramakrishna S, Fujihara K, Teo W-e, Lim TC, Ma Z (2005) An introduction to electrospinning and nanofibers. World Scientific Publishing Company, Singapore
Li D, McCann JT, Xia YN (2006) J Am Ceram Soc 89:1861
Zussman E, Chen X, Ding W, Calabri L, Dikin DA, Quintana JP, Ruoff RS (2005) Carbon 43:2175
Zussman E, Yarin AL, Bazilevsky AV, Avrahami R, Feldman M (2006) Adv Mater 18:348
Dzenis Y (2004) Science 304:1917
Theron A, Zussman E, Yarin AL (2001) Nanotechnology 12:384
Zussman E, Theron A, Yarin AL (2003) Appl Phys Lett 82:973
Reneker DH, Yarin AL, Fong H, Koombhongse S (2000) J Appl Phys 87:4531
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We gratefully acknowledge the financial support by Russell Berrie Nanotechnology Institute.
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Greenberg, Y., Lumelsky, Y., Silverstein, M.S. et al. YBCO nanofibers synthesized by electrospinning a solution of poly(acrylic acid) and metal nitrates. J Mater Sci 43, 1664–1668 (2008). https://doi.org/10.1007/s10853-007-2389-9
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DOI: https://doi.org/10.1007/s10853-007-2389-9