Abstract
Rare earth elements (REEs) and their composites could promote the growth of agricultural products, which, hence, have been widely used in farms as an important trace fertilizer, especially in China. In this work, two kinds of rare earth organic complex europium-salicylic acid-[1,10-phenanthroline] (Eu(Sal)3Phen) and praseodymium-salicylic acid-[1,10-phenanthroline] (Pr(Sal)3Phen) were synthesized first. Then we prepared the Eu,Pr(Sal)3Phen/LLDPE composites by adding Eu(Sal)3Phen and Pr(Sal)3Phen (with a weight ratio of Eu(Sal)3Phen: Pr(Sal)3Phen = 1:1) into the linear low-density polyethylene (LLDPE) matrix by mechanical mixing. The experiments of fluorescent properties showed that the composites can absorb ultraviolet light (UV) (wavelength range of 200–400 nm) and can emit red-orange light (wavelength range of 600–680 nm), which is necessary light source for growth crop. The fluorescent properties of Eu,Pr(Sal)3Phen treated for different time at 160 °C and treated for 10 min at different temperatures have been tested. It has been found that the fluorescent intensity of the Eu,Pr(Sal)3Phen reduced with the increase of treated time and treated temperature. Furthermore, the fluorescent properties of Eu,Pr(Sal)3Phen/LLDPE composites placed at room temperature for different time have been analyzed. It has been proved that the decrease in the fluorescent intensity of the Eu,Pr(Sal)3Phen/LLDPE composites is not evident within 3 months. Therefore, these composites meet the requirements of growth crop in one quarter, sufficiently.
Similar content being viewed by others
References
Wang DF et al (2003) J Agric Food Chem 51:6731
Cao X, Zhao G et al (1998) Analyst 123:1115
Chen WJ, Gu YH et al (2000) Plant Sci 152:145
Xu XK, Zhu WZ et al (2002) Sci Total Environ 293:97
Barry MJ, Meehan BJ (2000) Chemosphere 41:1669
Chen CY, Zhang PQ, Chai ZF (2001) Analytica Chimica Acta 439:19
Ding SM, Liang T et al (2006) Environ Sci Technol 40:2686
Shen YG, Wang TD (1984) Photosynthesis. Science and Technology Publishers, Shanghai, p 61
Lian SX, Li CZ et al (2000) China Plast 14(9):1
Zhang SP, Li JY et al (2003) China Plast 17(11):19
Qin L, Tian Y (2002) China Plast 16(3):53
Sabbarin N, Grardigle M, Leln JM (1993) Coor Chem Rev 13:208
Ding ZM, Liu LX, Zhou SJ (2005) Fine Specialty Chem 13:5
Zhang XY, Zhang YJ, Lei XF (2004) Chin Rare Earths 25:63
Li X, Chu Y (2006) Chin J Inorg Chem 22:145
Panigrahi BS, Peter S et al (1997) Spectrochimica Acta Part A 53:2579
Vink AP, Dorenbos P, Evan Eijk CW (2003) J Solid State Chem 171:308
Lavin V, Rodriguez VD, Martin IR (1997) J Lumin 72:437
Vergeer P, Babin V, Meijerink A (2005) J Lumin 114:267
Makhova VN, Khaidukov NM et al (2003) J Lumin 102:638
Yang C, Liu L, Gao Yi, Zhang W, Zhang L (2006) Luminescence 21:98
Li YH, Zhang HJ et al (2001) Thin Solid Films 385:205
Xua C-J, Xie F et al (2005) Spectrochimica Acta Part A 61:2005
He XD, Feng JC (1997) Lanzhou Petrochem Technol 9:202
Wu XG (1982) translate D. Shi H write. Botanic Physiology. Science Publishers, Beijing, p 4
Liu L, He L, Yang C, Zhang L-Q (2004) Macromol Rapid Commun 25:1197
Yang C, Liu L, Zhang L (2005) J Appl Polym Sci 96:20
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yang, C., Sun, ZF., Liu, L. et al. Preparation and luminescence performance of rare earth agriculture-used light transformation composites. J Mater Sci 43, 1681–1687 (2008). https://doi.org/10.1007/s10853-007-2345-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-007-2345-8