Skip to main content
Log in

Mechanical properties of photo-degraded recycled photo-degraded polyolefins

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Test bars made from a selection of polyolefins were injection moulded from virgin polymer and from blends containing recycled photodegraded polymer of the same kind. Bars were also moulded from similar blends prepared using recycled polymer that had not been photodegraded previously. The moulded bars were subjected to ultraviolet (UV) exposure and tensile tests were conducted after various exposure times. The extensibility decreased rapidly after a period of exposure that varied with the material and with fraction of recyclate contained. The results showed that previously photodegraded material acts as a pro-degradant in all of the materials studied. The recyclability of the materials is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. F. P. LAMANTIA, Polym. Degrad. Stab. 14 (1986) 241

    Article  CAS  Google Scholar 

  2. F. P. LAMANTIA and D. CURTO, ibid. 36 (1992) 131

    Article  CAS  Google Scholar 

  3. F. P. LAMANTIA, ibid. 37 (1992) 145

    Article  CAS  Google Scholar 

  4. H. HERBST, K. HOFFMANN, R. PFAENDNER and F. SITEK, Kunststoffe 82 (1992) 783.

    CAS  Google Scholar 

  5. J. POSPíšIL, F. A. SITEK and R. PFAENDNER, Polym. Degrad. Stab. 48 (1995) 351.

    Article  Google Scholar 

  6. R. PFAENDNER, H. HERBST, K. HOFFMANN and F. SITEK, Angew. Makromol. Chem. 232 (1995) 193.

    Article  CAS  Google Scholar 

  7. R. PFAENDNER, H. HERBST and K. HOFFMANN, Engineering Plastics 9 (1996) 249.

    Google Scholar 

  8. J. POSPíšIL, S. NEšPůREK, R. PFAENDNER and H. ZWEIFEL, Trends in Polymer Science 5 (1997) 294.

    Google Scholar 

  9. N. TZANKOVA DINTCHEVA, N. JILOV and F. P. LA MANTIA, Polym. Degrad. Stab. 57 (1997) 191.

    Article  Google Scholar 

  10. R. PFAENDNER, H. HERBST and K. HOFFMANN, Macromol. Symp. 135 (1998) 97.

    CAS  Google Scholar 

  11. H. HERBST and R. PFAENDNER, Polymer Recycling 4 (1999) 75.

    CAS  Google Scholar 

  12. C. N. KARTALIS, C. D. PAPASPYRIDES and R. PFAENDNER, Polym. Degrad. Stab. 70 (2000) 189.

    Article  CAS  Google Scholar 

  13. C. N. KARTALIS, C. D. PAPASPYRIDES, R. PFAENDNER, K. HOFFMANN and H. HERBST, J. Appl. Polym. Sci. 77 (2000) 1118.

    Article  CAS  Google Scholar 

  14. C. N. KARTALIS, C. D. PAPASPYRIDES, R. PFAENDNER, K. HOFFMANN and H. HERBST, Polym. Eng. Sci. 41 (2001) 771.

    Article  CAS  Google Scholar 

  15. C. D. PAPASPYRIDES, C. N. KARTALIS and R. PFAENDNER, Polymer Recycling 6 (2001) 1.

    Google Scholar 

  16. R. PFAENDER, Chap.19 in Plastics Additives Handbook, 5th ed. edited by H. Zweifel (Hanser, Munich, 2001) 973.

  17. S. AL-MALAIKA, S. CHOHAN, M. COKER, G. SCOTT, R. ARNAUD, P. DABIN, A. FAUVE and J. LEMAIRE, J.M.S. Pure Appl.Chem. A32 (1995) 709.

    Article  CAS  Google Scholar 

  18. W. STEVENSON and J. R. WHITE, J. Mater. Sci. 37 (2002) 1091.

    Article  CAS  Google Scholar 

  19. E. LOYD and J. R. WHITE, J. Mater. Sci. Lett. 21 (2002) 627.

    Article  CAS  Google Scholar 

  20. I. H. CRAIG, J. R. WHITE, A. V. SHYICHUK and I. D. SYROTYNSKA, Polym. Eng. Sci. 45 (2005) 579.

    Article  CAS  Google Scholar 

  21. J. R. WHITE, I. H. CRAIG and PHUA CHAI KIN, Polymer 46 (2005) 505.

    Article  CAS  Google Scholar 

  22. A. V. SHYICHUK, J. R. WHITE, I. H. CRAIG and I. D. SYROTYNSKA, Polym. Degrad. Stab. 88 (2005) 415.

    Article  CAS  Google Scholar 

  23. I. H. CRAIG and J. R. WHITE, Polym. Eng. Sci. 45 (2005) 588.

    Article  CAS  Google Scholar 

  24. R. STEWART, G. SMITH, I. H. CRAIG and J. R. WHITE, unpublished studies.

  25. B. G. WILLOUGHBY, A. GOLBY, J. DAVIES and R. CAIN, Polymer Test. 22 (2003) 553.

    Article  CAS  Google Scholar 

  26. B. O'DONNELL and J. R. WHITE, J. Mater.Sci. 29 (1994) 3955.

    Article  Google Scholar 

  27. M. M. QAYYUM and A. DAVIS, Polym.Degrad.Stab. 6 (1984) 201.

    Article  CAS  Google Scholar 

  28. M. S. RABELLO and J. R. WHITE, Polymer 38 (1997) 6389.

    Article  CAS  Google Scholar 

  29. Idem., ibid. 38 (1997) 6379.

    Article  CAS  Google Scholar 

  30. LI TONG and J. R. WHITE, Plast. Rubb. Compos. Procs. Applics. 25 (1996) 226.

    CAS  Google Scholar 

  31. LI TONG and J. R. WHITE, Polym. Eng. Sci. 37 (1997) 321.

    Article  CAS  Google Scholar 

  32. J. R. WHITE, Polymer Test. 4 (1984) 165 [Also appeared as Chapter 8 in Measurement Techniques for Polymeric Solids, edited by R. P. Brown and B. E. Read (Elsevier, Barking, 1984)]

    Article  CAS  Google Scholar 

  33. L. AUDOUIN, V. LANGLOIS, J. VERDU and J. C.M. DE BRUIJN, J. Mater. Sci. 29 (1994) 569.

    Article  CAS  Google Scholar 

  34. K. T. GILLEN, J. WISE and R. L. CLOUGH, Polym. Degrad. Stab. 47 (1995) 149.

    Article  CAS  Google Scholar 

  35. J. WISE, K. T. GILLEN and R. L. CLOUGH, Polymer 38 (1997) 1929.

    Article  CAS  Google Scholar 

  36. J. C. M. DE BRUIJN, Adv. Chem. Sers. 249 (1996) 599.

    CAS  Google Scholar 

  37. G. E. SCHOOLENBERG and P. VINK, Polymer 32 (1991) 432.

    Article  CAS  Google Scholar 

  38. T. J. TURTON and J. R. WHITE, J. Mater.Sci. 36 (2001) 4617.

    Article  CAS  Google Scholar 

  39. Idem., Polym. Degrad. Stab. 74 (2001) 559.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to J. R. White.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Craig, I.H., White, J.R. Mechanical properties of photo-degraded recycled photo-degraded polyolefins. J Mater Sci 41, 993–1006 (2006). https://doi.org/10.1007/s10853-006-6596-6

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-006-6596-6

Keywords

Navigation