Abstract
Acrylic copolymer- and 5% acrylic acid (AA) modified terpolymer-silica hybrid nanocomposites were synthesized by free radical bulk polymerization of ethyl acrylate (EA), butyl acrylate (BA) and acrylic acid (AA) with simultaneous generation of silica from tetraethoxysilane by sol-gel reaction. The pure polymers were analyzed by using Fourier Transform infrared (FTIR) spectroscopy and solid state nuclear magnetic resonance (NMR) spectroscopy. The hybrid samples were characterized by scanning electron microscopy (SEM), FTIR spectroscopy, NMR spectroscopy, dynamic mechanical, mechanical and thermal properties. SEM images confirmed the presence of nanosilica particles within the polymer matrices, whose dispersion and particle size distribution and visual appearance were dependent on the relative polarity (hydrophilicity) of the polymer matrices and the concentration of the filler. There was no evidence of strong chemical interaction between the polymers and the dispersed silica phase, as confirmed from the FTIR results. Terpolymer-silica hybrids demonstrated superior mechanical properties compared to the copolymer-silica hybrids. They also showed higher dynamic storage modulus and positive shift in the loss tangent peaks. The thermal stability of the nanocomposites was marginally higher which was possibly due to the dipolar interaction at the organic-inorganic interface.
Similar content being viewed by others
References
A. OKADA and A. USUKI, Mater. Sci. Eng. 3 (1995) 109.
A. BANDYOPADHYAY, A. K. BHOWMICK and M. D. SARKAR, J. Appl. Polym. Sci. 93 (2004) 2579.
P. JEDRZEJOWSKI, J. E. KLEMBERG-SAPIEHA and L. MARTINU, Surf. Coati. Tech. 188–189 (2004) 371.
J. W. GILMAN, Appl. Clay Sci. 15 (1999) 31.
P. B. MESSERSMITH and E. P. GIANNELIS, J. Polym. Sci. Part A: Polym. Chem. 33 (1995) 1047.
W. CHEN, Q. XU and R. Z. YUAN, Comp. Sci. Tech. 61 (2001) 935.
D. Y. GODOVSKI, Adv. Polym. Sci., 119 (1995) 79.
A . BANDYOPADHYAY, M. D. SARKAR and A. K. BHOWMICK, J. Appl. Polym. Sci. 95 (2005) 1418.
Idem., Rubber Chem. Technol. 77 (2004) 830.
M. MAITY, S. SADHU and A. K. BHOWMICK, J Polym Sci. Part B: Polym. Phy. 42 (2004) 4489.
S. SADHU and A. K. BHOWMICK, Adv. Engg. Mater, 6 (2004) 738.
Idem., J. Polym Sci. Part B: Polym. Phy. 42 (2004) 1573.
Idem., Rubber Chem. Technol. 76 (2003) 860.
L. XILONG, S. ZHOU, L. WU, B. WANG and L. YANG, Polymer 45 (2001) 860.
B. K. COLTRAIN, C. J. T. LANDRY, J. M. O ’REILLY, A. M. CHAMBERLAIN, G. A. RAKES, J. S. SEDITA, L. W. KELTS, M. R. LANDRY and V. K. LONG, Chem. Mater. 5 (1993) 1445.
C. C. SUN and J. E. MARK, Polymer 30 (1989) 104.
Z. AHMAD, M. I. SARWAR and J. E. MARK, J. Mater. Chem. 7 (1997) 259.
G. S. SUR and J. E. MARK, Eur. Polym. J. 21 (1985) 1051.
B. SMARSLY, G. GARNWEITNER, R. ASSINK and C. J. BRINKER, Prog. Org. Coatings 47 (2002) 393.
G. KICKELBICK, Prog. Polym. Sci. 28 (2003) 83.
Y. P. WANG, X. W. PEI, X. Y. HE and K. YUAN, Euro. Polym. J. 41 (2005) 1326.
C. L. JACKSON, B. J . BAUER, A. I. NAKATANI and J. D. BARNES, Chem. Mater. 8 (1996) 727.
P. HAJJI, L. DAVID, J. F. GERAND and G. VIGIER, J. Polym. Sci. Part B: Polym. Phy. 37 (1999) 3172.
R. TAMAKI and Y. J. CHUJO, Mater. Chem. 8 (1998) 1113.
G . SOCRATES, Infrared Characteristic Group Frequencies, John Wiley (New York 1980).
S. D. L. MARTINO and M. KELCHTERMANS, J. Appl. Polym. Sci. 56 (1995) 1781.
S. PATEL, A. BANDYOPADHYAY, V. VIJAYABASKAR, A. K. BHOWMICK, Polymer 46 (2005) 8079.
W. W. SIMONS “The Sadtler Guide to Carbon -13 NMR Spectra,” Sadtler Research Laboratories, 1983.
A. K. BHOWMICK, Invited Lecture, International Workshop on Polymer Nanocomposites: Recent Developments and Applications, Melbourne, Australia, May 23–25, 2005.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Patel, S., Bandyopadhyay, A., Vijayabaskar, V. et al. Effect of acrylic copolymer and terpolymer composition on the properties of in-situ polymer/silica hybrid nanocomposites. J Mater Sci 41, 927–936 (2006). https://doi.org/10.1007/s10853-006-6576-x
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-6576-x