Abstract
The heterogeneous precipitation method has been successfully used to prepare SrCO3 nanoparticle-coated BTO (BaCO3 or TiO2) powders by using PAA (polyacrylic acid) and NH4HCO3 as the dispersant and precipitator, respectively. Compared to the mixture obtained by the direct ball milling of the BaCO3, SrCO3 and TiO2 powders during the conventional solid-state process, this coated structure is effective for the low temperature synthesis of barium strontium titanate (BST) powders. Sintering study of the powder synthesized by this method showed the dense and fine-grained BST ceramics could be obtained at a low sintering temperature. The grain size effect on the sensitivity of the dielectric constant vs. frequencies was discussed for the first time. Compared to the coarse-grained material, the fine-grained sample exhibits the better sensitivity of dielectric constant vs. frequency at ferroelectric state. It was shown that as the grain size decreased, the transition became diffuse, transition temperature (T c) decreased and the dielectric constant increased.
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References
Bethe K, Welz F (1971) Mater Res Bull 6:209
Paik D-S, Park S-E, Shrout TR, Hackenberger W (1999) J Mater Sci 34:469. DOI: 10.1023/A: 104578225228
Carlson CM, Rivkin TV, Parilla PA, Perkins JD, Ginley DS, Kozyrev AB, Oshadchy VN, Pavlov AS (2000) Appl Phys Lett 76:1920
Zhai JW, Yao X, Cheng XG, Zhang LY, Chen H (2002) J Mater Sci 37:3739. DOI: 10.1023/A: 1016525712077
Whatmore RW, Osbond PC, Shorrocks NM (1987) Ferroelectrics 76:351
Elissalde C, Reverón H, Aymonier C, Michau D, Cansell F, Maglione M (2005) Nanotechonology 16:797
Shen C, Liu Q, Liu QF (2004) Mater Sci Eng B 111:31
Roeder RK, Slamovich EB (1999) J Am Ceram Soc 82:1665
Hennings D, Mayr W (1978) J Solid State Chem 26:329
Rhim SM, Hong S, Kim OK (2000) J Am Ceram Soc 83:1145
Tuan WJ, Wu HH, Yang TJ (1995) J Mater Sci 30:855. DOI: 10.1007/BF01178417
Xiang PH, Dong XL, Feng CD, Wang YL (2003) J Am Ceram Soc 86:1631
Xiang PH, Zhong N, Dong XL, Liang RH, Yang H, Feng CD (2004) Mater Lett 58:2675
Liang RH, Dong XL, Xiang PH, Li HD (2004) Jpn J Appl Phys 43:201
Loiseau J, Doërr N, Suau JM, Egraz JB, Llauro MF, Ladavière C, Claverie J (2003) Macromolecules 36:3066
Zhang L, Zhong WL, Wang CL, Peng YP, Wang YG (1999) Eur Phys J B 11:565
Lee BW, Auh KH (1995) J Mater Res 10:1418
Shaikh AS, Vest RW, Vest GM (1998) IEEE Trans Ultrason Ferroelect Freq Contr 45:1444
Samara GA (1966) Phys Rev 151:378
Fang TT, Hsieh HL, Shiau FS (2000) J Am Ceram Soc 83:1145
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The authors gratefully acknowledge the financial support granted by the Foundational and Important Project of Shanghai City (No: 06JC14070).
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Mao, C., Dong, X., Zeng, T. et al. Fabrication and characterization of fine-grained barium strontium titanate ceramics by the heterogeneous precipitation method. J Mater Sci 42, 6917–6922 (2007). https://doi.org/10.1007/s10853-006-1291-1
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DOI: https://doi.org/10.1007/s10853-006-1291-1