Abstract
The basis for the development of computer controlled printing techniques for YBa2Cu3O7-δ (YBCO) coated conductors is discussed in detail. This method of continuous deposition of YBCO material potentially enables non-vacuum formation of complex multi-layer superconducting patterns on silver substrates. Sol–ink processes were used to print single droplets of YBCO on polycrystalline silver substrates under varying printing conditions. Droplet sizes were controlled from a range of 300 μm–1200 μm. The formation and the stability of the sol–ink with respect to pH and concentration has been studied and discussed herein. For optimum results, the pH of the ink had to regulated to 6.5. Printing and substrate parameters that alter solid–liquid interface properties were also investigated such as ink concentration and surface roughness, the best results produced were with an ink concentration of 0.025 M on a polished silver surface. In order to control the flow properties of the sol media dynamic viscosities were determined. Characterisation by X-Ray Diffraction, Differential Thermal Analysis, Thermal Gravitometry and Scanning Electron Microscopy was used to examine the sol–ink samples, whilst AC susceptibility was used to assess the superconductivity of the printed samples where they were discovered to have a characteristic T c of ∼83 K.
Similar content being viewed by others
References
Badin J et al (2001) Coated conductor technology roadmap - Priority research and development activities leading to economical commercial manufacturing. Energetics Inc., Oak Ridge National Laboratory, Los Alamos National Laboratory, Argonne National Laboratory
MacManus-Driscoll JL (2002) In: Cardwell DA, Ginley DS (eds) Handbook of superconducting materials. Institute of Physics. p 565
Dawley JT et al (2001) Thick sol–gel derived YBa2Cu3O7-δ films. IEEE Trans Appl Superconduct 11(1):2873
Van Driessche I et al (2002) Nonvacuum-based deposition techniques for superconducting ceramic coatings. Pure Appl Chem 74(11):2101
Marguillier D et al (2002) YBa2Cu3O7 tapes prepared by sol-gel deposition techniques: microstructure and structural characterizations. Phys C 372:715
Shi DL et al (2002) Deposition and interface structures of YBCO thin films via a non-fluorine sol–gel route. Phys C 371(2):97
Ma YW et al (2002) Observation of growth-mode change under a magnetic field in YBa2Cu3O7-x . Phys Rev B 65(17): part. no.-174528
Glowacki BA et al (1993) Distribution of the transport critical current in Ag-(Bi,Pb)2Sr2Ca2Cu3O x reinforced tape-form conductors. IEEE Trans Appl Superconduct 3(1):953
Glowacki BA (1998) Texture development of HTS powder-in-tube conductors. Superconduct Sci Technol 11(10):989
Acknowledgments
M.C.C. Cabrera for his help on sol–gel processing. St. Catharine’s College, and Prima Woods Ltd., for funding support. Domino UK Ltd., for their hardware support. Acknowledgement is also due to E.A. Robinson and D. Astill for help on the ink-jet printer.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mouganie, T., Glowacki, B.A. Chemical synthesis and microstructural analysis of superconducting YBa2Cu3O7-δ ink deposited by drop-on-demand ink-jet printing on silver substrates. J Mater Sci 41, 8257–8264 (2006). https://doi.org/10.1007/s10853-006-1002-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-1002-y