Skip to main content
Log in

Electrophoretic deposition of organic–inorganic nanocomposites

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The focus of this review is on a new class of nanocomposites containing inorganic nanoparticles in a polyelectrolyte matrix. The recent advances in the application of electrophoretic deposition for the fabrication of the nanocomposite films are reviewed. New electrochemical strategies are discussed which are based on the use of strong, weak polyelectrolytes, and polymer–metal ion complexes. Many parameters, such as the pH, molecular weight of polyelectrolyte and bath composition influence the deposition process, microstructure and properties of the nanocomposite materials. Various applications, in areas as diverse as catalysis, fuel cells, protection of metals, biomedical implants, quantum dots, superparamagnetic devices, and supercapacitors were proposed for these fascinating new materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Beecroft LL, Ober CK (1997) Chem Mater 9:1302

    Article  CAS  Google Scholar 

  2. Sanchez C, De GJ, Soler-Illia AA, Ribot F, Lalot T, Mayer CR, Cabuil V (2001) Chem Mater 13:3061

    Article  CAS  Google Scholar 

  3. Gangopadhyay R, De A (2000) Chem Mater 12:608

    Article  CAS  Google Scholar 

  4. Mitzi DB (2001) Chem Mater 13:3283

    Article  CAS  Google Scholar 

  5. Sasaki T, Ebina Y, Tanaka T, Harada M, Watanabe M (2001) Chem Mater 13:4661

    Article  CAS  Google Scholar 

  6. Cassagneau T, Guérin F, Fendler JH (2000) Langmuir 16:7318

    Article  CAS  Google Scholar 

  7. Kleinfeld ER, Ferguson GS (1995) Chem Mater 7:2327

    Article  CAS  Google Scholar 

  8. Fang M, Kim CH, Saupe GB, Kim H-N, Waraksa CC, Miwa T, Fujishima A, Mallouk TE (1999) Chem Mater 11:1526

    Article  CAS  Google Scholar 

  9. Mann S (1993) Nature 365:499

    Article  CAS  Google Scholar 

  10. Mann S, Ozin GA (1996) Nature 382:313

    Article  CAS  Google Scholar 

  11. Wang TC, Rubner MF, Cohen RE (2002) Langmuir 18:3370

    Article  CAS  Google Scholar 

  12. Dutta AK, Ho T, Zhang L, Stroeve P (2000) Chem Mater 12:1042

    Article  CAS  Google Scholar 

  13. Zhang L, Dutta AK, Jarero G, Stroeve P (2000) Langmuir 16:7095

    Article  CAS  Google Scholar 

  14. Shchukin DG, Radtchenko IL, Sukhorukov GB (2003) J Phys Chem B 107:86

    Article  CAS  Google Scholar 

  15. Van Der Biest O, Vandeperre LJ (1999) Annu Rev Mater Sci 29:327

    Article  Google Scholar 

  16. Sarkar P, Nicholson PS (1996) J Am Ceram Soc 79:1987

    Article  CAS  Google Scholar 

  17. Tabellion J, Clasen R (2004) J Mater Sci 39:803

    Article  CAS  Google Scholar 

  18. Limmer SJ, Seraji S, Wu Y, Chou TP, Nguyen C, Cao G (2002) Adv Funct Mater 12:59

    Article  CAS  Google Scholar 

  19. Kaya C, Kaya F, Su B, Thomas B, Boccaccini AR (2005) Surf Coat Technol 191:303

    Article  CAS  Google Scholar 

  20. Boccaccini AR, Zhitomirsky I (2002) Curr Opin Sol State Mater Sci 6:251

    Article  CAS  Google Scholar 

  21. Zhitomirsky I (2002) Adv Colloid Interface Sci 97:279

    Article  CAS  Google Scholar 

  22. Rivas BL, Geckeler KE (1992) Adv Polym Sci 102:171

    CAS  Google Scholar 

  23. Griffiths PC, Paul A, Stilbs P, Petterson E (2005) Macromolecules 38:3539

    Article  CAS  Google Scholar 

  24. Zhu X, Tang F, Suzuki TS, Sakka Y (2003) J Am Ceram Soc 86:189

    Article  CAS  Google Scholar 

  25. Baklouti S, Pagnoux C, Chartier T, Baumard JF (1997) J Eur Ceram Soc 17:1387

    Article  CAS  Google Scholar 

  26. Kirwan LJ, Papastavrou G, Borkovec M, Behrens SH (2004) Nano Lett 4:149

    Article  CAS  Google Scholar 

  27. Caruso F (2001) Adv Mater 13:11

    Article  CAS  Google Scholar 

  28. Radtchenko IL, Giersig M, Sukhorukov GB (2002) Langmuir 18:8204

    Article  CAS  Google Scholar 

  29. Kampf N, Raviv U, Klein J (2004) Macromolecules 37:1134

    CAS  Google Scholar 

  30. Shepherd R, Reader S, Falshaw A (1997) Glycoconj J 14:535

    Article  CAS  Google Scholar 

  31. Rabea EI, Badawy ME-T, Stevens CV, Smagghe G, Steurbaut W (2003) Biomacromolecules 4:1457

    Article  CAS  Google Scholar 

  32. Sorlier P, Denuzière A, Viton C, Domard A (2001) Biomacromolecules 2:765

    Article  CAS  Google Scholar 

  33. Bartkowiak A, Hunkeler D (1999) Chem Mater 11:2486

    Article  CAS  Google Scholar 

  34. Rivas BL, Pereira ED, Moreno-Villoslada I (2003) Prog Polym Sci 28:173

    Article  CAS  Google Scholar 

  35. Bekturov EA, Bimendina LA (1997) J Macromol Sci Rev Macromol Chem Phys C 37:501

    Google Scholar 

  36. Varma AJ, Deshpande SV, Kennedy JF (2004) Carbohydr Polym 55:77

    Article  CAS  Google Scholar 

  37. Von Zelewsky A, Barbosa L, Schläpfer CW (1993) Coordination Chem Rev 123:229

    Article  Google Scholar 

  38. Kobayashi S, Suh K-D, Shirokura Y (1989) Macromolecules 22:2363

    Article  CAS  Google Scholar 

  39. Wang X, Du Y, Liu H (2004) Carbohydr Polym 56:21

    Article  CAS  Google Scholar 

  40. Wang J, Gao L (1999) J Mater Sci Lett 18:1891

    Article  CAS  Google Scholar 

  41. Pettersson A, Marino G, Pursiheimo A, Rosenholm JB (2000) J Colloid Interface Sci 228:73

    Article  CAS  Google Scholar 

  42. Blanco López MC, Rand B, Riley FL (2000) J Eur Ceram Soc 20:1587

    Article  Google Scholar 

  43. Wang H, Nakamura H, Yao K, Uehara M, Nishimura S, Maeda H, Abe E (2002) J Am Ceram Soc 85:1937

    Article  CAS  Google Scholar 

  44. Dietrich A, Neubrand A (2001) J Am Ceram Soc 84:806

    CAS  Google Scholar 

  45. Hoogeveen NG, Cohen Stuart MA, Fleer GJ (1996) J Colloid Interface Sci 182:133

    Article  CAS  Google Scholar 

  46. Hoogeveen NG, Cohen Stuart MA, Fleer GJ (1996) J Colloid Interface Sci 182:146

    Article  CAS  Google Scholar 

  47. Mészáros R, Thompson L, Bos M, De Groot P (2002) Langmuir 18:6164

    Article  CAS  Google Scholar 

  48. Chaufer B, Rabiller-Baudry M, Bouguen A, Labbé JP, Quémerais A (2000) Langmuir 16:1852

    Article  CAS  Google Scholar 

  49. Zhitomirsky I, Petric A (2004) J Mater Sci 39:825

    Article  CAS  Google Scholar 

  50. Tang F, Uchikoshi T, Sakka Y (2002) J Am Ceram Soc 85:2161

    CAS  Google Scholar 

  51. Ferrari B, Moreno R (1997) J Eur Ceram Soc 17:549

    Article  CAS  Google Scholar 

  52. Moreno R, Ferrari B (2000) Am Ceram Soc Bull 79:44

    CAS  Google Scholar 

  53. Harbach F, Nienburg H (1998) J Eur Ceram Soc 18:675

    Article  CAS  Google Scholar 

  54. Biesheuvel PM, Verweij H (1999) J Am Ceram Soc 82:1451

    Article  CAS  Google Scholar 

  55. Ohshima H (1995) Colloids Surf A 103:249

    Article  CAS  Google Scholar 

  56. Ohshima H (2001) J Colloid Interface Sci 233:142

    Article  CAS  Google Scholar 

  57. Netz RR (2003) J Phys Chem B 107:8208

    Article  CAS  Google Scholar 

  58. Bühme U, Scheler U (2003) Colloids Surf A 222:35

    Article  CAS  Google Scholar 

  59. Walldal C, Åkerman B (1999) Langmuir 15:5237

    Article  CAS  Google Scholar 

  60. Dukhin SS, Zimmermann R, Werner C (2005) J Colloid Interface Sci 286:761

    Article  CAS  Google Scholar 

  61. André P, Long D, Ajdari A (1998) Eur Phys J B 4:307

    Google Scholar 

  62. Zhitomirsky I (2000) JOM-e 52, http://www.tms.org/pubs/journals/JOM/0001/Zhitomirsky/Zhitomirsky-0001.html as on 20 February 2000

  63. Zhitomirsky I, Petric A (2000) Mater Lett 42:273

    Article  CAS  Google Scholar 

  64. Zhitomirsky I, Petric A (2000) J Mater Chem 10:1215

    Article  CAS  Google Scholar 

  65. Zhitomirsky I, Petric A (2000) Mater Lett 46:1

    Article  CAS  Google Scholar 

  66. Zhitomirsky I, Petric A, Niewczas M (2002) JOM 54:31

    CAS  Google Scholar 

  67. Zhitomirsky I, Petric A (2001) JOM 53:48

    CAS  Google Scholar 

  68. Zhitomirsky I, Petric A (2001) Ceram Int 27:149

    Article  CAS  Google Scholar 

  69. Zhitomirsky I, Petric A (2000) Mater Sci Eng B 78:125

    Article  Google Scholar 

  70. Pang X, Zhitomirsky I, Niewczas M (2005) Surf Coat Technol 195:138

    Article  CAS  Google Scholar 

  71. Zhitomirsky I, Niewczas M, Petric A (2003) Mater Lett 57:1045

    Article  CAS  Google Scholar 

  72. Zhitomirsky I, Petric A (2002) Can Metallurgical Q 41:497

    CAS  Google Scholar 

  73. Mcnally EA, Zhitomirsky I, Wilkinson DS (2005) Mater Chem Phys 91:391

    Article  CAS  Google Scholar 

  74. Zhitomirsky I (2004) J Appl Electrochem 34:235

    Article  CAS  Google Scholar 

  75. Zhitomirsky I (2004) Mater Lett 58:420

    Article  CAS  Google Scholar 

  76. Bon P, Zhitomirsky I, Embury JD (2004) Mater Chem Phys 86:44

    Article  CAS  Google Scholar 

  77. Wu L-Q, Yi H, Li S, Rubloff GW, Bentley WE, Ghodssi R, Payne GF (2003) Langmuir 19:519

    Article  CAS  Google Scholar 

  78. Wu L-Q, Gadre AP, Yi H, Kastantin MJ, Rubloff GW, Bentley WE, Payne GF, Ghodssi R (2002) Langmuir 18:8620

    Article  CAS  Google Scholar 

  79. Yi H, Wu L-Q, Ghodssi R, Rubloff GW, Payne GF, Bentley WE (2004) Anal Chem 76:365

    Article  CAS  Google Scholar 

  80. Wu L-Q, Lee K, Wang X, English DS, Losert W, Payne GF (2005) Langmuir 21:3641

    Article  CAS  Google Scholar 

  81. López-León T, Carvalho ELS, Seijo B, Ortega-Vinuesa JL, Bastos-González D (2005) J Colloid Interface Sci 283:344

    Article  CAS  Google Scholar 

  82. Xu J-J, Luo X-L, Du Y, Chen H-Y (2004) Electrochem Commun 6:1169

    Article  CAS  Google Scholar 

  83. Pang X, Zhitomirsky I (2005) Int J Nanosci 4:409

    Article  CAS  Google Scholar 

  84. Pang X, Zhitomirsky I (2005) Mater Chem Phys 94:245

    Article  CAS  Google Scholar 

  85. Gorelikov I, Kumacheva E (2004) Chem Mater 16:4122

    Article  CAS  Google Scholar 

  86. Hasegawa K, Tatsumisago M, Minami T (1997) J Ceram Soc Jpn 105:569

    CAS  Google Scholar 

  87. Zhitomirsky I (2004) Surf Eng 20:43

    Article  CAS  Google Scholar 

  88. Bon P, Zhitomirsky I, Embury JD (2004) Surf Eng 20:5

    Article  CAS  Google Scholar 

  89. Zhitomirsky I (2003) Mater Lett 57:3761

    Article  CAS  Google Scholar 

  90. Nagarajan N, Humadi H, Zhitomirsky I (2006) Electrochim Acta 51:3039

    Article  CAS  Google Scholar 

  91. Pang X, Zhitomirsky I (2004) Langmuir 20:2921

    Article  CAS  Google Scholar 

  92. Cao J, Zhitomirsky I, Niewczas M (2006) Mater Chem Phys 96:289

    Article  CAS  Google Scholar 

  93. Bardetsky D, Zhitomirsky I (2005) Surf Eng 21:125

    Article  CAS  Google Scholar 

  94. Wang J, De Boer J, De Groot K (2004) J Dent Res 83:296

    Article  CAS  Google Scholar 

  95. Redepenning J, Venkataraman G, Chen J, Stafford N (2003) J Biomed Mater Res A 66:411

    Article  CAS  Google Scholar 

Download references

Acknowledgement

The author gratefully acknowledges the financial support of the Natural Science and Engineering Research Council of Canada.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. Zhitomirsky.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhitomirsky, I. Electrophoretic deposition of organic–inorganic nanocomposites. J Mater Sci 41, 8186–8195 (2006). https://doi.org/10.1007/s10853-006-0994-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-006-0994-7

Keywords

Navigation