Skip to main content
SpringerLink
Log in

Experimental determination of solid–liquid interfacial energy for succinonitrile solid solution in equilibrium with the succinonitrile–(D) camphor eutectic liquid

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The equilibrated grain boundary groove shapes for Succinonitrile (SCN) solid solution in equilibrium with the Succinonitrile (SCN)–D Camphor (DC) eutectic liquid were directly observed. From the observed grain boundary groove shapes, the Gibbs–Thomson coefficient and solid–liquid interface energy for SCN solid solution in equilibrium with the SCN–DC eutectic liquid has been determined to be (5.39 ± 0.27) × 10−8 K m and (7.88 ± 0.79) × 10−3 J m−2 with present numerical method and Gibbs–Thomson equation, respectively. The grain boundary energy of SCN rich phase of the SCN–DC eutectic system has been determined to be (14.95 ± 1.79) × 10−3 J m−2 from the observed grain boundary groove shapes. Thermal conductivity ratio of the liquid phase to the solid phase for SCN–0.16 mole % DC alloy has also been measured.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Jones DRH, Chadwick GA (1970) Phil Mag 22:291

    Article  CAS  Google Scholar 

  2. Jones DRH, Chadwick GA (1971) J Cryst Growth 11:260

    Article  CAS  Google Scholar 

  3. Jones DRH (1978) Phil Mag 27:569

    Article  Google Scholar 

  4. Schaefer RJ, Glicksman ME, Ayers JD (1975) Phil Mag 32:725

    Article  CAS  Google Scholar 

  5. Hardy SC (1977) Phil Mag 35:471

    Article  CAS  Google Scholar 

  6. Nash GE, Glicksman ME (1971) Phil Mag 24:577

    Article  CAS  Google Scholar 

  7. Bolling GF, Tiller WA (1960) J Appl Phys 31/8:1345

    Article  Google Scholar 

  8. Singh NB, Glicksman ME (1989) J Cryst Growth 98:573

    Article  CAS  Google Scholar 

  9. Stalder I, Bilgram JH (2003) J Chem Phys 118:7981

    Article  CAS  Google Scholar 

  10. Gündüz M, Hunt JD (1985) Acta Metall 33/9:651

    Google Scholar 

  11. Gündüz M, Hunt JD (1989) Acta Metall 37/7:839

    Google Scholar 

  12. Maraşlı N, Hunt JD (1996) Acta Mater 44/3:1085

    Article  Google Scholar 

  13. Keşlioğlu K, Maraşlı N (2004) Mater Sci Eng A 369:294

    Article  Google Scholar 

  14. Keşlioğlu K, Maraşlı N (2004) Metall Mater Trans A 35A:3665

    Article  Google Scholar 

  15. Keşlioğlu K, Gündüz M, Kaya H, Çadırlı E (2004) Mater Lett 58:3067

    Article  Google Scholar 

  16. Erol M, Maraşlı N, Keşlioğlu K, Gündüz M (2004) Scripta Mater 51:131

    Article  CAS  Google Scholar 

  17. Keşlioğlu K, Erol M, Maraşlı N, Gündüz M (2004) J Alloy Compd 385:207

    Article  Google Scholar 

  18. Bayender B, Maraşlı N, Çadırlı E, Şişman H, Gündüz M (1998) J Cryst Growth 194/1:119

    Article  Google Scholar 

  19. Bayender B, Maraşlı N, Çadırlı E, Gündüz M (1999) Mater Sci Eng A 270:343

    Article  Google Scholar 

  20. Maraşlı N, Keşlioğlu K, Arslan B (2003) J Cryst Growth 247:613

    Article  Google Scholar 

  21. Witusiewicz VT, Sturz L, Hecht U, Rex S (2004) Acta Mater 52:4561

    Article  CAS  Google Scholar 

  22. Derollez P, Lefebvre J, Descamps M, Press W, Fontaine H (1990) Condens Matter 2:6893

    Article  CAS  Google Scholar 

  23. Woodruff DP (1973) The solid–liquid interface. Cambridge University Press, Cambridge, p 4

    Google Scholar 

Download references

Acknowledgements

This project was supported by the Erciyes University Scientific Research Project Unit under the contract no FBT-05-06. Authors would like to thank to Erciyes University Scientific Research Project Unit for their financial supports.

Author information

Authors and Affiliations

  1. Department of Physics, Faculty of Arts and Sciences, Erciyes University, 38039, Kayseri, Turkey

    K. Keşlioğlu & N. Maraşlı

  2. Institute of Science and Technology, Erciyes University, 38039, Kayseri, Turkey

    U. Böyük & M. Erol

Authors
  1. K. Keşlioğlu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. U. Böyük
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Erol
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. Maraşlı
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. Maraşlı.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Keşlioğlu, K., Böyük, U., Erol, M. et al. Experimental determination of solid–liquid interfacial energy for succinonitrile solid solution in equilibrium with the succinonitrile–(D) camphor eutectic liquid. J Mater Sci 41, 7939–7943 (2006). https://doi.org/10.1007/s10853-006-0861-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-006-0861-6

Keywords

Search

Navigation