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Journal of Materials Science

, Volume 42, Issue 13, pp 4738–4744 | Cite as

Fabrication of metallic nanowire arrays by electrodeposition into nanoporous alumina membranes: effect of barrier layer

  • Gaurav Sharma
  • Michael V. Pishko
  • Craig A. GrimesEmail author
Article

Abstract

Deposition into nanoporous alumina membranes is widely used for nanowire fabrication. Herein using AC electrodeposition ternary Fe–Co–Ni nanowires are fabricated within the nanoscale-pores of alumina membranes. Using an electrodeposition frequency of 1,000 Hz, 15 Vrms, consistently and repeatably yield nanowire arrays over membranes several cm2 in extent. Electrochemical Impedance Spectroscopy (EIS) is used to explain the effects of AC electrodeposition frequency. The impedance of the residual alumina barrier layer, separating the underlying aluminum metal and the nanoporous membrane, decreases drastically with electrodeposition frequency facilitating uniform pore-filling of samples several cm2 in area. Anodic polarization studies on thin films having alloy compositions identical to the nanowires display excellent corrosion resistance properties.

Keywords

Electrochemical Impedance Spectroscopy Barrier Layer High Resolution Transmission Electron Microscopy Nanowire Array Anodization Voltage 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgment

The authors gratefully acknowledge support of this work under NIH grant NIH-1R01EB000684-01.

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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Gaurav Sharma
    • 1
  • Michael V. Pishko
    • 2
  • Craig A. Grimes
    • 1
    • 3
    Email author
  1. 1.Department of Materials Science and EngineeringThe Pennsylvania State UniversityUniversity ParkUSA
  2. 2.Department of Chemical EngineeringThe Pennsylvania State UniversityUniversity ParkUSA
  3. 3.Department of Electrical EngineeringThe Pennsylvania State UniversityUniversity ParkUSA

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