Abstract
The corrosion behavior of a new Mg–9Al–1Zn (AZ91) magnesium alloy containing neodymium (Nd) is investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), immersion tests and electrochemical experiments. The results indicate that Nd decreases the size and volume fraction of the β (Mg17Al12) phase and forms Al2Nd in the alloy. In addition, during corrosion, Nd is incorporated into corrosion film in the form of Nd2O3. AZ91 alloy containing 1.0 wt.% Nd possesses an outstanding passivation property and excellent corrosion resistance. The corrosion resistance enhancement is attributed to the reduction in the size and volume fraction of the β phase and the incorporation of Nd2O3 in the corrosion film.
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References
Ballerini G, Bardi U, Bignucolo R, Ceraolo G (2005) Corros Sci 47:2173
Song G, Atrens A, Stjohn D, Nairn J, Li Y (1997) Corros Sci 39:855
Avedesian MM, Baker H (1999) Magnesium and magnesium alloys. ASM International Material Park, USA, p 226
Lu YZ, Wang QD, Zeng XQ, Ding WJ, Zhai CQ, Zhu YP (2000) Mater Sci Eng A 278:66
Wang QD, Lu YZ, Zeng XQ, Ding WJ, Zhu YP, Li QH, Lan J (1999) Mater Sci Eng A 271:109
Pettersen G, Westengen H, Hoier R, Lohne O (1996) Mater Sci Eng A 207:115
Moreno IP, Nandy TK, Jones JW, Allison JE, Pollock TM (2003) Scr Mater 48:1029
Lunder O, Nisancioglu K (1993) Progress in the understanding and prevention of corrosion. The Institute of Materials, London, p 1249
Nordlien JH, Nisancioglu K, Ono S, Masuko N (1997) J Electrochem Soc 144:461
Song GL, Stjohn DH (2002) J Light Metals 2:1
Wei LY, Dunlop GL (1996) J Alloys Compd 232:264
Song GL, Bowles AL, Stjohn DH (2004) Mater Sci Eng A 366:74
Song GL, Atrens A, Wu XL, Zhang B (1998) Corros Sci 40:1769
Ambat R, Aung NN, Zhou W (2000) Corros Sci 42:1433
Lunder O, Lein JE, Aune TK, Nisancioglu K (1989) Corrosion 45:741
Song GL, Atrens A (1999) Adv Eng Mater 1:11
Song GL, Atrens A, Dargusch M (1999) Corros Sci 41:249
Yao HB, Li Y, Wee ATS, Pan JS, Chai JW (2001) Appl Surf Sci 173:54
Yao HB, Li Y, Wee ATS (2003) Electrochem Acta 48:4197
Rosalbino F, Angemini E, de Negri S, Saccone A, Delfino S (2005) Intermetallics 13:55
Krishnamurthy S, Khobaib M, Robertson E (1988) Mater Sci Eng 99:507
Acknowledgements
This work was supported by The Program of Science and Technology Development in Jilin Province (No. 20040315) and “985 project” of Jilin University.
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Song, Y.L., Liu, Y.H., Yu, S.R. et al. Effect of neodymium on microstructure and corrosion resistance of AZ91 magnesium alloy. J Mater Sci 42, 4435–4440 (2007). https://doi.org/10.1007/s10853-006-0661-z
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DOI: https://doi.org/10.1007/s10853-006-0661-z