Skip to main content

Advertisement

SpringerLink
Log in

Preparation of hydroxyapatite ceramics by hydrothermal hot-pressing method at 300 °C

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Hydroxyapatite (HA) ceramics were prepared by a hydrothermal hot-pressing (HHP) method at a low temperature (300 °C). DCPD (CaHPO4·2H2O) + Ca(OH)2, OCP (Ca8H2(PO4)6·5H2O) + Ca(OH)2, DCPD + NH3·H2O, OCP + NH3·H2O or α-TCP (Ca3(PO4)2) + NH3·H2O were used as the precursors. The mixture was treated by HHP under a condition of 300 °C/40 MPa. In sample DCPD + Ca(OH)2 and OCP + Ca(OH)2, the HA ceramics obtained showed a porous and homogenous microstructure, and the bending strength were 9.9 MPa and 10.9 MPa, respectively. In sample α-TCP+NH3·H2O, rod-like HA crystals produced. When the starting materials were DCPD + NH3·H2O, OCP + NH3·H2O, the HA particles produced exhibited plate-like features. It appeared that the plate-like HA particles stacked into a lamellar structure. The formation of the lamellar structure leads to a noticeable improvement in fracture property of the HA ceramic. The bending strength and the fracture toughness of the sample prepared from OCP and ammonia water reach 90 MPa and 2.3 MPam1/2, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Suchanek W, Yoshimura M (1998) J. Mater. Res. 1:94

    Google Scholar 

  2. Akao M, Aoki H, Kato K (1981) J Mater Sci 16:809. Doi: 10.1007/BF00552220

  3. Vanlanduyt P, Li F, Keustermans JP, Streydio JM, Delannay F, Munting E (1995) J Mater Sci Mater Med 6:8

    Article  CAS  Google Scholar 

  4. Lu H, Qu Z, Zhou Y (1998) J Mater Sci Mater Med 9:583

    Article  Google Scholar 

  5. Murray MGS, Wang J, Ponton CB, Marquis PM (1995) J Mater Sci 30:3061. Doi: 10.1007/BF01209218

    Google Scholar 

  6. Goto T, Wakamatsu N, Kamemizu H, Iijima M, Doi Y, Moriwaki Y (1991) J Mater Sci Mater Med 2:149

    Article  CAS  Google Scholar 

  7. Halouani R, Assolant DB, Champion E, Ababou A (1994) J Mater Sci Mater Med 5:563

    Article  CAS  Google Scholar 

  8. Suchanek W, Yashima M, Kakihana M, Yoshimura M (1997) Biomaterials 18:923

    Article  CAS  Google Scholar 

  9. De with G, Vandijk HJA, Hattu N, Prijs K (1981) J Mater Sci 16:1592. Doi: 10.1007/BF00553971

    Google Scholar 

  10. Choi JW, Kong YM, Kim HE (1998) J Am Ceram Soc 81[7]:1743

    Article  CAS  Google Scholar 

  11. Suchanek W, Yashima M, Kakihana M, Yoshimura M (1997) J Am Ceram Soc 80:2805

    Article  CAS  Google Scholar 

  12. LeGeros RZ (1981) Prog Crystal Growth Charact 4:1

    Article  CAS  Google Scholar 

  13. Takagi M, Mochida M, Uchida N, Saito K, Uematsu K (1993) J Mater Sci Mater Med 4:50

    Google Scholar 

  14. Matsuno T, Watanabe K, Ono K, Koishi M (1996) J Ceram Soc Jap 104:845

    Google Scholar 

  15. Ahn ES, Gleason NJ, Ying JY (2005) J Am Ceram Soc 88:3374

    Article  CAS  Google Scholar 

  16. Kim Hae-Won, Kong Young-Min, Koh Young-Hag, Kim Hyoun-Ee, Kim Hyun-Man, Jea Seung Ko (2003) J Am Ceram Soc 86:2019

    Article  CAS  Google Scholar 

  17. Sui Lin Shi, Wei Pan, Ming Hao Fang, Zhen Yi Fang (2006) J Am Ceram Soc 89:743

  18. Champion E, Gautier S, Bernach-Assollant D (1996) J Mater Sci Mater Med 7:125

    Article  CAS  Google Scholar 

  19. Gautier S, Champion E, Bernach-Assollant (1999) J Mater Sci Mater Med 19:533

    Article  Google Scholar 

  20. Ruys AJ, Wei M, Sorrell CC, Dickson MR, Brandwood A, Milthorpe BK (1995) Biomaterials 16:409

    Article  CAS  Google Scholar 

  21. Hosoi K, Hashida T, Takahashi H, Yamasaki N, Korenaga T (1996) J Am Ceram Soc 79:2771

    Article  CAS  Google Scholar 

  22. Onoki T, Hosoi K, Hashida T (2001) In Proceedings of Asia Pacific conference on fracture and strength’01 and International Conference on Advanced Technology in Experimental Mechanics’01, Sendai, October, p 511

  23. Martin RI, Brown PW (1995) J Mater Sci Mater Med 6:138

    Article  CAS  Google Scholar 

  24. Miyamoto Y, Ishikawa K, Fukao H, Sawada M, Nagayama M, Kon M, Asaoka K (1995) Biomaterials 16:855

    Google Scholar 

  25. Shi Hong Li, de Wijn JR, Pierre Layrolle, Klaas de Groot (2003) J Am Ceram Soc 86:65

  26. Bonfield W (1988) J Biomed Eng 10:522

    Article  CAS  Google Scholar 

  27. Sinha A, Nayar S, Agrawal A, Bhattacharyya D, Ramachandrarao P (2003) J Am Ceram Soc 86:357

    Google Scholar 

  28. Greish YE, Brown PW (2002) J Am Ceram Soc 85:1738

    Article  CAS  Google Scholar 

  29. Liming Fang, Yang Leng, Ping Gao (2006) Biomaterials 27:3701

    Google Scholar 

  30. Greish YE, Bender JD, Lakshmi S, Brown PW, Allcock HR, Laurencin CT (2005) Biomaterials 26:1

    Article  CAS  Google Scholar 

  31. Athanasiou KA, Niederauer GG, Agrawal CM (1996) Biomaterials, 17:93

    Article  CAS  Google Scholar 

  32. Ignatius AA, Claes LE (1996) Biomaterials, 17:831

    Article  CAS  Google Scholar 

  33. Jackson AP, Vincent JFV, Briggs D, Crick RA, Davies SF, Hearn MJ, Turner RM (1986) J Mater Sci Lett 5:975

    Article  CAS  Google Scholar 

  34. Jackson AP, Vincent JFV, Turner RM (1990) J Mater Sci 25:3173. Doi: 10.1007/BF00587670

  35. Nakahira A, Aoki S, Sakamoto K, Yamaguchi S (2001) J Mater Sci Mater Med 12:793

    Article  CAS  Google Scholar 

  36. Testing Methods for Fracture Toughness of Fine Ceramics, Japanese industrial standard, JIS R 1607–1995

  37. Lide D (2000) Handbook of chemistry and physics, 83rd edn. CRC press

Download references

Acknowledgements

This study was supported in part by the Japan Ministry of Health, Labor and Welfare under Grants-in Aid for Research on Advanced Medical Technology.

Author information

Authors and Affiliations

  1. Fracture and Reliability Research Institute, Graduate School of Engineering, Tohoku University, Sendai, 980-8579, Japan

    Junguo Li & Toshiyuki Hashida

  2. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Department of Materials Science, Wuhan University of Technology, 122 Luoshi Road, Hongshan, Wuhan, Hubei Province, 430070, China

    Junguo Li

Authors
  1. Junguo Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Toshiyuki Hashida
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Junguo Li.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, J., Hashida, T. Preparation of hydroxyapatite ceramics by hydrothermal hot-pressing method at 300 °C. J Mater Sci 42, 5013–5019 (2007). https://doi.org/10.1007/s10853-006-0613-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-006-0613-7

Keywords

Search

Navigation