Abstract
Novel electroluminescent (EL) polymer based on fluorene having benzothiazolylpyrazoline unit in the main chain was synthesized. The result polymer possessed satisfactory thermal stability with onset decomposition temperature (T d) of 401 °C and glass-transition temperature (T g) of 213 °C. The polymer emits green fluorescence with high photoluminescence (PL) quantum yield of 47%. Polymer light-emitting diode (PLED) was fabricated with the configuration of ITO/PEDT 40 nm/PVK 40 nm/polymer(80 nm)/Ba(4 nm)/Al(160 nm) showed turn-on voltage of 4.5 V, and it can emit green light with maximum brightness of 1726 cd m−2 with the maximum external quantum efficiency of 1.59%.
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Burrousghes JH, Bradey DDC, Brown AR, Marks RN, Mackay K, Friend RH, Burns PL, Holmes AB (1990) Nature 347:539
Segura JL (1998) Acta Polym 49:319
Kraft A, Grimsdale AC, Holmes AB (1998) Angew Chem Int Ed 37:402
Friend RH, Gymer RW, Holmes AB, Burrousghes JH, Marks RN, Taliani C, Bradey DDC, Dos Satos DA, Bredas JL, Logdlund M, Salaneck WR (1999) Nature 397:121
Bernius MT, Inbasekaran M, O’Brien J, Wu WW (2000) Adv Mater 12:1737
Jenekhe SA, Osaheni JA (1994) Science 26:765
Yang Y, Pei Q (1996) J Am Chem Soc 118:7416
Virgili T, Lidzey DG, Bradley DDC (2000) Adv Mater 12:58
Zhang XH, Wu SK, Gao ZQ, Lee CS, Lee ST, Kwong HL (2000) Thin Solid Films 371:40
Lu ZY, Jiang Q, Zhu WG, Xie MG, Hou YB, Chen XH, Wang ZJ (2000) Synth Met 111:465
Sano T, Fujii T, Nishio Y, Hamada Y, Shibata K, Kuroki K (1995) Jpn J Appl Phys 34:3124
Dilthey D (1921) J Prakt Chem 101:202
Li DF, Jiang GJ, Li JS (1990) Chem J Chin Univ 11:205
Yu WL, Pei J, Cao Y, Huang W, Heeger AJ (1999) Chem Commun 1837
Coulson DR (1972) Inorg Synth 13:121
Greenham NC, Samuel IDW, Hayes GR, Philips RT, Kessener YAR, Moratti SC, Homes AB, Friend RH (1995) Chem Phys Lett 241:89
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This work was supported by the key foundation of education ministry of China (project NO. 105142).
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Zhang, H., Li, Y., Jiang, Q. et al. Novel green-emitting polymer containing fluorene and 1-(2-benzothiazolyl)-3,5-diphenylpyrazoline. J Mater Sci 42, 4476–4479 (2007). https://doi.org/10.1007/s10853-006-0234-1
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DOI: https://doi.org/10.1007/s10853-006-0234-1