Abstract
Nanoporous carbon materials have always presented a special interest due to their properties, which include adsorption (especially of gases), catalyst activity, fluorescence, and luminescence. Their porosity leads to a high surface area, making them suited for assisting processes, such as synthesis (especially carboxylation and electrolytic reduction), catalysis (particularly electrocatalysts and photocatalysis), and separation. Considering these features, carbon nanotubes, graphene oxide, and graphene quantum dots have been extensively investigated for pharmaceutical applications. Coming from either organic, inorganic or synthetic precursors, the nanoporous carbon composites are of great value as adsorbent for the removal of various pollutants. Apart from the removal of pollutants, nanopores serve to separate single stranded and double stranded DNA in solution and rapid DNA sequencing. While the size of the pores depends on the method used for preparation, from a usage standpoint, the nanopores are micropores (\(< \! 2 ~ \text {nm}\)), mesopores (\(2 \!- \! 50 ~\text {nm}\)) and macropores (\(> \! 50 ~ \text {nm}\)). The methods of investigation related with nanoporous carbon materials often include X ray diffraction, scanning electron microscopy, fourier transform infrared spectroscopy, transmission electron microscopy, X ray photoelectron spectroscopy, thermogravimetric analysis and X ray powder diffraction. This review summarizes the most recent studies in developing nanoporous carbon materials for various pharmacautical applications including bio-sensing, drug delivery, tissue engineering, biomedicine, gene transfection or cancer therapy. New porous carbon materials, including metal organic frameworks, carbon dots and nanotubes, have been detailed in this review.
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Cooney, D.O.: Activated charcoal: antidotal and other medical uses. Marcel Dekker, New York (1980)
Wrench, J.: Origin, properties and uses of activated carbon. J. Oil Fat Ind. 8(12), 441–453 (1931). https://doi.org/10.1007/BF02574469
Baker, F.S., Miller, C.E., Repik, E.D.: Kirk-Othmer encyclopedia of chemical technology, vol. 4. Wiley, New York (1992)
Debye, P., Scherrer, P.: X-ray interference produced by irregularly oriented particles. III. Constitution of graphite and amorphous carbon. Phys. Z. 18, 291–301 (1917)
Yuan, W., Feng, Y., Xie, A., Zhang, X., Huang, F., Li, S., Zhang, X., Shen, Y.: Nitrogen-doped nanoporous carbon derived from waste pomelo peel as a metal-free electrocatalyst for the oxygen reduction reaction. Nanoscale 8, 8704–8711 (2016). https://doi.org/10.1039/C6NR00764C
Venkateshaiah, A., Cheong, J.Y., Shin, S.H., Akshaykumar, K.P., Yun, T.G., Bae, J., Waclawek, S., Cerník, M., Agarwal, S., Greiner, A., Padil, V.V.T., Kim, I.D., Varma, R.S.: Recycling non-food-grade tree gum wastes into nanoporous carbon for sustainable energy harvesting. Green Chem. 22, 1198–1208 (2020). https://doi.org/10.1039/C9GC04310A
Li, Z., Xu, J., Sun, D., Lin, T., Huang, F.: Nanoporous carbon foam for water and air purification. ACS Appl. Nano Mater. 3(2), 1564–1570 (2020). https://doi.org/10.1021/acsanm.9b02347
Joseph, S., Saianand, G., Benzigar, M.R., Ramadass, K., Singh, G., Gopalan, A.I., Yang, J.H., Mori, T., Al-Muhtaseb, A.H., Yi, J., Vinu, A.: Recent advances in functionalized nanoporous carbons derived from waste resources and their applications in energy and environment. Adv. Sustain. Syst. 5(1), 2000169 (2021). https://doi.org/10.1002/adsu.202000169
Le, T.X.H., Cowan, M.G., Drobek, M., Bechelany, M., Julbe, A., Cretin, M.: Fe-nanoporous carbon derived from mil-53(Fe): a heterogeneous catalyst for mineralization of organic pollutants. Nanomaterials 9(4), 641 (2019). https://doi.org/10.3390/nano9040641
Yoon, J., Moon, S., Ha, S., Lim, H.K., Jin, H.J., Yun, Y.S.: Nanoconfinement effect of nanoporous carbon electrodes for ionic liquid-based aluminum metal anode. J. Energy Chem. 74, 121–127 (2022). https://doi.org/10.1016/j.jechem.2022.06.048
Lim, J.S., Kim, J.H., Woo, J., Baek, D.S., Ihm, K., Shin, T.J., Sa, Y.J., Joo, S.H.: Designing highly active nanoporous carbon \(\text{ H}_{2}\text{O}_{2}\) production electrocatalysts through active site identification. Chem 7(11), 3114–3130 (2021). https://doi.org/10.1016/j.chempr.2021.08.007
Aleksandrzak, M., Baranowska, D., Kedzierski, T., Sielicki, K., Zhang, S., Biegun, M., Mijowska, E.: Superior synergy of \(\text{g }-\text{C}_{3}\text{N}_{4}/\text{Cd }\) compounds and Al-MOF-derived nanoporous carbon for photocatalytic hydrogen evolution. Appl. Catal. B 257, 117906 (2019). https://doi.org/10.1016/j.apcatb.2019.117906
Zahed, M.A., Salehi, S., Madadi, R., Hejabi, F.: Biochar as a sustainable product for remediation of petroleum contaminated soil. Curr. Res. Green Sustain. Chem. 4, 100055 (2021). https://doi.org/10.1016/j.crgsc.2021.100055
Cagnon, B., Secula, M., Bayazit, S.: In: Bartoli, M., Frediani, M., Rosi, L. (eds.) Carbon-based material for environmental protection and remediation. IntechOpen (2021). https://doi.org/10.5772/intechopen.91355. https://EconPapers.repec.org/RePEc:ito:pchaps:192598
Yang, Z., Dang, F., Zhang, C., Sun, S., Zhao, W., Li, X., Liu, Y., Chen, X.: Harvesting low-grade heat via thermal-induced electric double layer redistribution of nanoporous graphene films. Langmuir 35(24), 7713–7719 (2019). https://doi.org/10.1021/acs.langmuir.9b00646
Yan, B., Huang, H., Qin, X., Xiu, S., Choi, J., Ko, D., Chen, T., Zhang, W., Quan, B., Diao, G., Jin, X., Piao, Y.: Facile self-template synthesis of a nitrogen-rich nanoporous carbon wire and its application for energy storage devices. ACS Appl. Energy Mater. 4(12), 13735–13747 (2021). https://doi.org/10.1021/acsaem.1c02463
Jiang, Y., Mei, C., Zhang, Z., Dong, Z.: Immobilizing \(\text{CsPbBr}_{3}\) perovskite nanocrystals on nanoporous carbon powder for visible-light-driven \(\text{CO}_{2}\) photoreduction. Dalton Trans. 50, 16711–16719 (2021). https://doi.org/10.1039/D1DT03099J
Ramesh, A., Jeyavelan, M., Rajju Balan, J.A., Srivastava, O., Leo Hudson, M.S.: Supercapacitor and room temperature H, \(\text{CO}_{2}\) and \(\text{CH}_{4}\) gas storage characteristics of commercial nanoporous activated carbon. J. Phys. Chem. Solids 152, 109969 (2021). https://doi.org/10.1016/j.jpcs.2021.109969
Smuthkochorn, A., Katunyoo, N., Kaewtrakulchai, N., Atong, D., Soongprasit, K., Eiad-ua, A.: Nanoporous carbon from cattial leaves for carbon dioxide capture. Mater. Today Proc. 17, 1240–1248 (2019). The First Materials Research Society of Thailand International Conference, October 31–November 3, 2017 https://doi.org/10.1016/j.matpr.2019.06.012. https://www.sciencedirect.com/science/article/pii/S2214785319312441
Casanova, A., Raymundo-Piñero, E., Ania, C.M.C.O., Gomis-Berenguer, A.: Synthetic strategies for the preparation of nanoporous carbons. In: Advanced materials for energy production, conversion and storage. CRC Press (2022). https://hal.science/hal-03884293
Hu, C., Dai, Q., Dai, L.: Multifunctional carbon-based metal-free catalysts for advanced energy conversion and storage. Cell Rep. Phys. Sci. 2(2), 100328 (2021). https://doi.org/10.1016/j.xcrp.2021.100328
Martínez, A.A., Gasnier, A., Gennari, F.C.: From iron to copper: the effect of transition metal catalysts on the hydrogen storage properties of nanoconfined libh4 in a graphene-rich n-doped matrix. Molecules 27(9), 2921 (2022). https://doi.org/10.3390/molecules27092921
Harmanli, I.: Towards catalytic activation of nitrogen in ionic liquid/nanoporous carbon interfaces for electrochemical ammonia synthesis. Doctoralthesis, Universität Potsdam (2020). https://doi.org/10.25932/publishup-48359
Fu, Y., Li, K., Batmunkh, M., Yu, H., Donne, S., Jia, B., Ma, T.: Unsaturated p-metal-based metal-organic frameworks for selective nitrogen reduction under ambient conditions. ACS Appl. Mater. Interfaces 12(40), 44830–44839 (2020). https://doi.org/10.1021/acsami.0c13902
He, X., Ling, Z., Peng, X., Yang, X., Ma, L., Lu, S.: Facile synthesis of \(\text{Cu}_{2}\text{SnS}_{3}\) nanocrystals for efficient nitrogen reduction reaction. Electrochem. Commun. 148, 107441 (2023). https://doi.org/10.1016/j.elecom.2023.107441
Mokhati, A., Benturki, O., Bernardo, M., Kecira, Z., Matos, I., Lapa, N., Ventura, M., Soares, O., Dorego, A.B., Fonseca, I.: Nanoporous carbons prepared from argan nutshells as potential removal agents of diclofenac and paroxetine. J. Mol. Liq. 326, 115368 (2021). https://doi.org/10.1016/j.molliq.2021.115368
Menshchikov, I., Shkolin, A., Khozina, E., Fomkin, A.: Thermodynamics of adsorbed methane storage systems based on peat-derived activated carbons. Nanomaterials 10(7), 1379 (2020). https://doi.org/10.3390/nano10071379
Zuo, S., Zhang, W., Wang, Y., Xia, H.: Low-cost preparation of high-surface-area nitrogen-containing activated carbons from biomass-based chars by ammonia activation. Ind. Eng. Chem. Res. 59(16), 7527–7537 (2020). https://doi.org/10.1021/acs.iecr.9b06836
Nanaji, K., Nirogi, A., Srinivas, P., Anandan, S., Vijay, R., Bathe, R.N., Pramanik, M., Narayan, K., Ravi, B., Rao, T.N.: Translational materials research—from laboratory to product: a 1200F cylindrical supercapacitor from petroleum coke derived activated carbon sheets. J. Energy Storage 55, 105650 (2022). https://doi.org/10.1016/j.est.2022.105650
Ma, C., Lu, T., Demir, M., Yu, Q., Hu, X., Jiang, W., Wang, L.: Polyacrylonitrile-derived n-doped nanoporous carbon fibers for Co2 adsorption. ACS Appl. Nano Mater. 5(9), 13473–13481 (2022). https://doi.org/10.1021/acsanm.2c03126
Ban, L.L., Crawford, D., Marsh, H.: Lattice-resolution electron microscopy in structural studies of non-graphitizing carbons from polyvinylidene chloride (PVDC). J. Appl. Crystallogr. 8(4), 415–420 (1975). https://doi.org/10.1107/S0021889875010904
Kipling, J., Sherwood, J., Shooter, P., Thompson, N.: The pore structure and surface area of high-temperature polymer carbons. Carbon 1(3), 321–328 (1964). https://doi.org/10.1016/0008-6223(64)90286-6
Smith, M.A., Foley, H.C., Lobo, R.F.: A simple model describes the pdf of a non-graphitizing carbon. Carbon 42(10), 2041–2048 (2004). https://doi.org/10.1016/j.carbon.2004.04.009
Becker, P., Glenk, F., Kormann, M., Popovska, N., Etzold, B.J.: Chlorination of titanium carbide for the processing of nanoporous carbon: a kinetic study. Chem. Eng. J. 159(1), 236–241 (2010). https://doi.org/10.1016/j.cej.2010.02.011
Durairaj, A., Sakthivel, T., Ramanathan, S., Obadiah, A., Vasanthkumar, S.: Conversion of laboratory paper waste into useful activated carbon: a potential supercapacitor material and a good adsorbent for organic pollutant and heavy metals. Cellulose 26(5), 3313–3324 (2019). https://doi.org/10.1007/s10570-019-02277-4
Kwiatkowski, M., Broniek, E.: An evaluation of the reliability of the results obtained by the LBET, QSDFT, BET, and DR methods for the analysis of the porous structure of activated carbons. Materials 13(18), 3929 (2020). https://doi.org/10.3390/ma13183929
Wei, S., Kamali, A.R.: Dual-step air-thermal treatment for facile conversion of pet into porous carbon particles with enhanced dye adsorption performance. Diam. Relat. Mater. 107, 107914 (2020). https://doi.org/10.1016/j.diamond.2020.107914
Shrestha, L.K., Shrestha, R.G., Maji, S., Pokharel, B.P., Rajbhandari, R., Shrestha, R.L., Pradhananga, R.R., Hill, J.P., Ariga, K.: High surface area nanoporous graphitic carbon materials derived from lapsi seed with enhanced supercapacitance. Nanomaterials 10(4), 728 (2020). https://doi.org/10.3390/nano10040728
Shrestha, L., Thapa, M., Shrestha, R., Maji, S., Pradhananga, R., Ariga, K.: Rice husk-derived high surface area nanoporous carbon materials with excellent iodine and methylene blue adsorption properties. C 5(1), 10 (2019). https://doi.org/10.3390/c5010010
Hadden, M., Martinez-Martin, D., Yong, K.T., Ramaswamy, Y., Singh, G.: Recent advancements in the fabrication of functional nanoporous materials and their biomedical applications. Materials 15(6), 2111 (2022). https://doi.org/10.3390/ma15062111
Shrestha, L.K., Wei, Z., Subramaniam, G., Shrestha, R.G., Singh, R., Sathish, M., Ma, R., Hill, J.P., Nakamura, J., Ariga, K.: Nanoporous hollow carbon spheres derived from fullerene assembly as electrode materials for high-performance supercapacitors. Nanomaterials 13(5), 946 (2023). https://doi.org/10.3390/nano13050946
Montiel-Centeno, K., García-Villén, F., Barrera, D., Amaya-Roncancio, S., Sánchez-Espejo, R., Arroyo-Gómez, J.J., Sandri, G., Viseras, C., Sapag, K.: Biocompatible nanoporous carbons as a carrier system for controlled release of cephalexin. Colloids Surf. B 220, 112937 (2022). https://doi.org/10.1016/j.colsurfb.2022.112937
Oschatz, M., Walczak, R.: Crucial factors for the application of functional nanoporous carbon-based materials in energy and environmental applications. C 4(4), 56 (2018). https://doi.org/10.3390/c4040056
Yamada, Y., Ishii, M., Nakamura, T., Yano, K.: Artificial black opal fabricated from nanoporous carbon spheres. Langmuir 26(12), 10044–10049 (2010). https://doi.org/10.1021/la1001732
Torad, N.L., Li, Y., Ishihara, S., Ariga, K., Kamachi, Y., Lian, H.Y., Hamoudi, H., Sakka, Y., Chaikittisilp, W., Wu, K.C.W., Yamauchi, Y.: Mof-derived nanoporous carbon as intracellular drug delivery carriers. Chem. Lett. 43(5), 717–719 (2014). https://doi.org/10.1246/cl.131174
Bello, R., Rodríguez-Aguado, E., Smith, V.A., Grachev, D., Castellòn, E.R., Bashkova, S.: Ni-doped ordered nanoporous carbon prepared from chestnut wood tannins for the removal and photocatalytic degradation of methylene blue. Nanomaterials 12(10), 1625 (2022). https://doi.org/10.3390/nano12101625
Ariyanto, T., Sarwendah, R.A., Amimmal, Y.M., Laksmana, W.T., Prasetyo, I.: Modifying nanoporous carbon through hydrogen peroxide oxidation for removal of metronidazole antibiotics from simulated wastewater. Processes 7(11), 835 (2019). https://doi.org/10.3390/pr7110835
Ngene, P., van den Berg, R., Verkuijlen, M.H.W., de Jong, K.P., de Jongh, P.E.: Reversibility of the hydrogen desorption from nabh4 by confinement in nanoporous carbon. Energy Environ. Sci. 4, 4108–4115 (2011). https://doi.org/10.1039/C1EE01481A
Tang, J., Liu, J., Torad, N.L., Kimura, T., Yamauchi, Y.: Tailored design of functional nanoporous carbon materials toward fuel cell applications. Nano Today 9(3), 305–323 (2014). https://doi.org/10.1016/j.nantod.2014.05.003
Kumar, N., Wani, T.A., Pathak, P.K., Bera, A., Salunkhe, R.R.: Multifunctional nanoarchitectured porous carbon for solar steam generation and supercapacitor applications. Sustain. Energy Fuels 6, 1762–1769 (2022). https://doi.org/10.1039/D2SE00092J
Liu, J., Wickramaratne, N.P., Qiao, S.Z., Jaroniec, M.: Molecular-based design and emerging applications of nanoporous carbon spheres. Nat. Mater. 14(8), 763–774 (2015). https://doi.org/10.1038/nmat4317
Wang, Z., Li, F., Stein, A.: Direct synthesis of shaped carbon nanoparticles with ordered cubic mesostructure. Nano Lett. 7(10), 3223–3226 (2007). https://doi.org/10.1021/nl072068j
Ouyang, Y., Shi, H., Fu, R., Wu, D.: Highly monodisperse microporous polymeric and carbonaceous nanospheres with multifunctional properties. Sci. Rep. 3(1), 1430 (2013). https://doi.org/10.1038/srep01430
Choma, J., Jamiola, D., Augustynek, K., Marszewski, M., Gao, M., Jaroniec, M.: New opportunities in Stöber synthesis: Preparation of microporous and mesoporous carbon spheres. J. Mater. Chem. 22, 12636–12642 (2012). https://doi.org/10.1039/C2JM31678A
Jong, S., Jin, G., Seok, C.: Method for preparing nanoporous carbons with enhanced mechanical strength and the nanoporous carbons prepared by the method. Patent US7326396 B2 (2002)
Gogotsi, Y., Yushin, G., Hoffman, E., Barsoum, M.: Process for producing nanoporous carbide derived carbon with large specific surface area. Patent WO2007062095 A1 (2007)
Mohun, W.: Mineral active carbon and process for producing same. Patent US3066099 A (1959)
Khan, J.H., Lin, J., Young, C., Matsagar, B.M., Wu, K.C., Dhepe, P.L., Islam, M.T., Rahman, M.M., Shrestha, L.K., Alshehri, S.M., Ahamad, T., Salunkhe, R.R., Kumar, N.A., Martin, D.J., Yamauchi, Y., Hossain, M.S.A.: High surface area nanoporous carbon derived from high quality jute from Bangladesh. Mater. Chem. Phys. 216, 491–495 (2018). https://doi.org/10.1016/j.matchemphys.2018.05.082
Jang, J., Nam, Y.T., Kim, D., Kim, Y.J., Kim, D.W., Jung, H.T.: Turbostratic nanoporous carbon sheet membrane for ultrafast and selective nanofiltration in viscous green solvents. J. Mater. Chem. A 8, 8292–8299 (2020). https://doi.org/10.1039/D0TA00804D
Wang, Y., Wang, X., Antonietti, M., Zhang, Y.: Facile one-pot synthesis of nanoporous carbon nitride solids by using soft templates. ChemSusChem 3(4), 435–439 (2010). https://doi.org/10.1002/cssc.200900284
Shrestha, R.G., Maji, S., Shrestha, L.K., Ariga, K.: Nanoarchitectonics of nanoporous carbon materials in supercapacitors applications. Nanomaterials 10(4), 639 (2020). https://doi.org/10.3390/nano10040639
Barsoum, M., Gogotsi, Y.: Nanoporous carbide derived carbon with tunable pore size. Patent WO2005007566 A3 (2004)
Goncharov, A., Guglya, A., Melnikova, E.: On the feasibility of developing hydrogen storages capable of adsorption hydrogen both in its molecular and atomic states. Int. J. Hydrog. Energy 37(23), 18061–18073 (2012). https://doi.org/10.1016/j.ijhydene.2012.08.142
Lin, Z., Taberna, P.L., Simon, P.: Advanced analytical techniques to characterize materials for electrochemical capacitors. Curr. Opin. Electrochem. 9, 18–25 (2018). https://doi.org/10.1016/j.coelec.2018.03.004
Sultana, I., Rahman, M.M., Glushenkov, A.M., Mateti, S., Tanwar, K., Huang, S., Chen, Y.: Nano germanium incorporated thin graphite nanoplatelets: a novel germanium based lithium-ion battery anode with enhanced electrochemical performance. Electrochim. Acta 391, 139001 (2021). https://doi.org/10.1016/j.electacta.2021.139001
Sing, K.S.W.: Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (provisional). Pure Appl. Chem. 54(11), 2201–2218 (1982). https://doi.org/10.1351/pac198254112201
Sing, K.S.W.: Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (recommendations 1984). Pure Appl. Chem. 57(4), 603–619 (1985). https://doi.org/10.1351/pac198557040603
Stoeckli, H.: Microporous carbons and their characterization: the present state of the art. Carbon 28(1), 1–6 (1990). https://doi.org/10.1016/0008-6223(90)90086-E
Stewart, J.Q., Korff, S.A.: The refractive index of sodium vapor and the width of the \(d\) lines in absorption. Phys. Rev. 32, 676–680 (1928). https://doi.org/10.1103/PhysRev.32.676
McCave, I.N., Bryant, R.J., Cook, H.F., Coughanowr, C.A.: Evaluation of a laser-diffraction-size analyzer for use with natural sediments. J. Sediment. Res. 56(4), 561–564 (1986). https://doi.org/10.1306/212F89CC-2B24-11D7-8648000102C1865D
Liu, X., Wang, C., Wu, Q., Wang, Z.: Magnetic porous carbon-based solid-phase extraction of carbamates prior to hplc analysis. Microchim. Acta 183(1), 415–421 (2016). https://doi.org/10.1007/s00604-015-1664-8
Trognko, L., Lecante, P., Ratel-Ramond, N., Rozier, P., Daffos, B., Taberna, P.L., Simon, P.: Tic-carbide derived carbon electrolyte adsorption study by ways of X-ray scattering analysis. Mater. Renew. Sustain. Energy 4(4), 17 (2015). https://doi.org/10.1007/s40243-015-0059-4
Prehal, C., Koczwara, C., Jäckel, N., Schreiber, A., Burian, M., Amenitsch, H., Hartmann, M.A., Presser, V., Paris, O.: Quantification of ion confinement and desolvation in nanoporous carbon supercapacitors with modelling and in situ x-ray scattering. Nat. Energy 2(3), 16215 (2017). https://doi.org/10.1038/nenergy.2016.215
Sztucki, M., Narayanan, T.: Development of an ultra-small-angle X-ray scattering instrument for probing the microstructure and the dynamics of soft matter. J. Appl. Crystallogr. 40(s1), s459–s462 (2007). https://doi.org/10.1107/S0021889806045833
Koczwara, C., Prehal, C., Haas, S., Boesecke, P., Huesing, N., Paris, O.: Towards real-time ion-specific structural sensitivity in nanoporous carbon electrodes using in situ anomalous small-angle x-ray scattering. ACS Appl. Mater. Interfaces 11(45), 42214–42220 (2019). https://doi.org/10.1021/acsami.9b14242
Abell, A., Willis, K., Lange, D.: Mercury intrusion porosimetry and image analysis of cement-based materials. J. Colloid Interface Sci. 211(1), 39–44 (1999). https://doi.org/10.1006/jcis.1998.5986
Oschatz, M.: New routes towards nanoporous carbon materials for electrochemical energy storage and gas adsorption. Phd thesis, Technical University of Dresda (2014)
Wollmann, P., Leistner, M., Stoeck, U., Grünker, R., Gedrich, K., Klein, N., Throl, O., Grählert, W., Senkovska, I., Dreisbach, F., Kaskel, S.: High-throughput screening: speeding up porous materials discovery. Chem. Commun. 47, 5151–5153 (2011). https://doi.org/10.1039/C1CC10674K
Wollmann, P., Leistner, M., Grählert, W., Throl, O., Dreisbach, F., Kaskel, S.: Infrasorb: optical detection of the heat of adsorption for high throughput adsorption screening of porous solids. Microporous Mesoporous Mater. 149(1), 86–94 (2012). https://doi.org/10.1016/j.micromeso.2011.08.028
Jäntschi, L., Bolboaca, S.D.: Nanoporous carbon, p. 13. Apple Academic Press, New York (2020). https://doi.org/10.1201/9780429022944-28
Langmuir, I.: The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc. 40(9), 1361–1403 (1918). https://doi.org/10.1021/ja02242a004
Brunauer, S., Emmett, P.H., Teller, E.: Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 60(2), 309–319 (1938). https://doi.org/10.1021/ja01269a023
International Organization for Standardization: Determination of the specific surface area of solids by gas adsorption—bet method. Standard ISO 9277:2022(E), 3rd edn. International Organization for Standardization, Geneva, CH (2022)
ASTM International: Standard test method for carbon black—total and external surface area by nitrogen adsorption. Standard ASTM D6556-21, ASTM International, West Conshohocken, PA, USA (2021). https://doi.org/10.1520/D6556-14
Emmett, P.H.: Adsorption and pore-size measurements on charcoals and whetlerites. Chem. Rev. 43(1), 69–148 (1948). https://doi.org/10.1021/cr60134a003
Dubinin, M.M.: The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces. Chem. Rev. 60(2), 235–241 (1960). https://doi.org/10.1021/cr60204a006
Biggs, M.J., Buts, A.: Virtual porous carbons: what they are and what they can be used for. Mol. Simul. 32(7), 579–593 (2006). https://doi.org/10.1080/08927020600836242
Thommes, M., Kaneko, K., Neimark, A.V., Olivier, J.P., Rodriguez-Reinoso, F., Rouquerol, J., Sing, K.S.: Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (iupac technical report). Pure Appl. Chem. 87(9–10), 1051–1069 (2015). https://doi.org/10.1515/pac-2014-1117
Mayoral, E.P., Matos, I., Bernardo, M., Durán-Valle, C., Fonseca, I.: In: Sadjadi, S.(ed.) Emerging carbon materials for catalysis, pp. 299–352. Elsevier (2021). https://doi.org/10.1016/B978-0-12-817561-3.00009-3. https://www.sciencedirect.com/science/article/pii/B9780128175613000093
Biesmans, G., Mertens, A., Duffours, L., Woignier, T., Phalippou, J.: Polyurethane based organic aerogels and their transformation into carbon aerogels. J. Non Cryst. Solids 225, 64–68 (1998). https://doi.org/10.1016/S0022-3093(98)00010-6
Reichenauer, G., Fricke, J.: Gas transport in sol-gel derived porous carbon aerogels. MRS Online Proc. Lib. 464, 345 (1996). https://doi.org/10.1557/PROC-464-345
Lu, T., Liu, Y., Xu, X., Pan, L., Alothman, A.A., Shapter, J., Wang, Y., Yamauchi, Y.: Highly efficient water desalination by capacitive deionization on biomass-derived porous carbon nanoflakes. Sep. Purif. Technol. 256, 117771 (2021). https://doi.org/10.1016/j.seppur.2020.117771
Lee, J., Han, S., Hyeon, T.: Synthesis of new nanoporous carbon materials using nanostructured silica materials as templates. J. Mater. Chem. 14, 478–486 (2004). https://doi.org/10.1039/B311541K
Rojas-Cervantes, M.L.: Some strategies to lower the production cost of carbon gels. J. Mater. Sci. 50(3), 1017–1040 (2015). https://doi.org/10.1007/s10853-014-8617-1
Pekala, R., Alviso, C., Lu, X., Gross, J., Fricke, J.: New organic aerogels based upon a phenolic-furfural reaction. J. Non Cryst. Solids 188(1), 34–40 (1995). https://doi.org/10.1016/0022-3093(95)00027-5
Wu, X., Zhang, X., Wang, X., Zhang, C., Zhu, Q., Du, A., Zhang, Z., Shen, J.: Aqueous-based, high-density nanoporous carbon xerogels with high specific surface area for supercapacitors. J. Porous Mater. 29(1), 87–95 (2022). https://doi.org/10.1007/s10934-021-01149-2
Li, W., Guo, S.: Preparation of low-density carbon aerogels from a cresol/formaldehyde mixture. Carbon 38(10), 1520–1523 (2000). https://doi.org/10.1016/S0008-6223(00)00114-7
Babic, B., Kokuneoski, M., Miljkovic, M., Prekajski, M., Matovic, B., Gulicovski, J., Bucevac, D.: Synthesis and characterization of the sba-15/carbon cryogel nanocomposites. Ceram. Int. 38(6), 4875–4883 (2012). https://doi.org/10.1016/j.ceramint.2012.02.078
Shruti, M.K.: Polybenzoxazine aerogels: synthesis, characterization, conversion to porous carbons, and energetic composites. Phd thesis, Missouri University of Science and Technology (2013)
Edlabadkar, V.A., Gorla, S., Soni, R.U., Shaheenuddoulah, A.B.M., Gloriod, J., Hackett, S., Leventis, N., Sotiriou-Leventis, C.: Polybenzodiazine aerogels: all-nitrogen analogues of polybenzoxazines-synthesis, characterization, and high-yield conversion to nanoporous carbons. Chem. Mater. 35(2), 432–446 (2023). https://doi.org/10.1021/acs.chemmater.2c02797
Zhang, R., Li, W., Liang, X., Wu, G., Lü, Y., Zhan, L., Lu, C., Ling, L.: Effect of hydrophobic group in polymer matrix on porosity of organic and carbon aerogels from sol-gel polymerization of phenolic resole and methylolated melamine. Microporous Mesoporous Mater. 62(1), 17–27 (2003). https://doi.org/10.1016/S1387-1811(03)00386-X
Czakkel, O., Marthi, K., Geissler, E., László, K.: Influence of drying on the morphology of resorcinol-formaldehyde-based carbon gels. Microporous Mesoporous Mater. 86(1), 124–133 (2005). https://doi.org/10.1016/j.micromeso.2005.07.021
Kabbour, H., Baumann, T.F., Satcher, J.H., Saulnier, A., Ahn, C.C.: Toward new candidates for hydrogen storage: high-surface-area carbon aerogels. Chem. Mater. 18(26), 6085–6087 (2006). https://doi.org/10.1021/cm062329a
Shimoda, H., Oh, S., Geng, H., Walker, R., Zhang, X., McNeil, L., Zhou, O.: Self-assembly of carbon nanotubes. Adv. Mater. 14(12), 899–901 (2002)
Zhou, O., Shimoda, H., Gao, B., Oh, S., Fleming, L., Yue, G.: Materials science of carbon nanotubes: Fabrication, integration, and properties of macroscopic structures of carbon nanotubes. Acc. Chem. Res. 35(12), 1045–1053 (2002). https://doi.org/10.1021/ar010162f
Lee, S.H., Lee, D.H., Lee, W.J., Kim, S.O.: Tailored assembly of carbon nanotubes and graphene. Adv. Funct. Mater. 21(8), 1338–1354 (2011). https://doi.org/10.1002/adfm.201002048
Wu, D., Zhang, F., Liang, H., Feng, X.: Nanocomposites and macroscopic materials: assembly of chemically modified graphene sheets. Chem. Soc. Rev. 41, 6160–6177 (2012). https://doi.org/10.1039/C2CS35179J
Morishita, T., Tsumura, T., Toyoda, M., Przepiórski, J., Morawski, A., Konno, H., Inagaki, M.: A review of the control of pore structure in mgo-templated nanoporous carbons. Carbon 48(10), 2690–2707 (2010). https://doi.org/10.1016/j.carbon.2010.03.064
Kyotani, T., Nagai, T., Inoue, S., Tomita, A.: Formation of new type of porous carbon by carbonization in zeolite nanochannels. Chem. Mater. 9(2), 609–615 (1997). https://doi.org/10.1021/cm960430h
Malgras, V., Tang, J., Wang, J., Kim, J., Torad, N.L., Dutta, S., Ariga, K., Hossain, M.S.A., Yamauchi, Y., Wu, K.C.W.: Fabrication of nanoporous carbon materials with hard- and soft-templating approaches: a review. J. Nanosci. Nanotechnol. 19(7), 3673–3685 (2019). https://doi.org/10.1166/jnn.2019.16745
Jäntschi, L.: General chemistry, 3rd edn, AcademicDirect, Cluj-Napoca (2013). http://ph.academicdirect.org/GCC_v3.pdf
Maiti, D., Tong, X., Mou, X., Yang, K.: Carbon-based nanomaterials for biomedical applications: a recent study. Front. Pharmacol. 9(9), 1401 (2019). https://doi.org/10.3389/fphar.2018.01401
Gilbert, M.T., Knox, J.H., Kaur, B.: Porous glassy carbon, a new columns packing material for gas chromatography and high-performance liquid chromatography. Chromatographia 16(1), 138–146 (1982). https://doi.org/10.1007/BF02258884
Corbin, D., Foley, H., Shiflett, M.: Mixed matrix nanoporous carbon membranes. Patent US6740143 B2 (2001)
Ribeiro, R.P., Sauer, T.P., Lopes, F.V., Moreira, R.F., Grande, C.A., Rodrigues, A.E.: Adsorption of \(\text{CO}_{2}\), \(\text{CH}_{4}\), and \(\text{N}_{2}\) in activated carbon honeycomb monolith. J. Chem. Eng. Data 53(10), 2311–2317 (2008). https://doi.org/10.1021/je800161m
Shao, H., Wu, Y.C., Lin, Z., Taberna, P.L., Simon, P.: Nanoporous carbon for electrochemical capacitive energy storage. Chem. Soc. Rev. 49, 3005–3039 (2020). https://doi.org/10.1039/D0CS00059K
Atchudan, R., Samikannu, K., Perumal, S., Immanueledison, T.N.J., Vinodh, R., Lee, Y.R.: Aesculus turbinata biomass-originated nanoporous carbon for energy storage applications. Mater. Lett. 309, 131445 (2022). https://doi.org/10.1016/j.matlet.2021.131445
Dimeo, F., Carruthers, J., Wodjenski, M., McManus, J., Marzullo, J.: Nanoporous carbon materials, and systems and methods utilizing same. Patent WO2007136887 A2 (2007)
Carruthers, J., Dimeo, F., Bobita, B.: Nanoporous articles and methods of making same. Patent US2011220518 A1 (2011)
Ting, V.P., Ramirez-Cuesta, A.J., Bimbo, N., Sharpe, J.E., Noguera-Diaz, A., Presser, V., Rudic, S., Mays, T.J.: Direct evidence for solid-like hydrogen in a nanoporous carbon hydrogen storage material at supercritical temperatures. ACS Nano 9(8), 8249–8254 (2015). https://doi.org/10.1021/acsnano.5b02623
Biener, J., Baumann, T., Shao, L., Weissmueller, J.: Nanoporous carbon actuator and methods of use thereof. Patent Patent US2010230298 A1 (2010)
Falk, K., Coasne, B., Pellenq, R., Ulm, F.J., Bocquet, L.: Subcontinuum mass transport of condensed hydrocarbons in nanoporous media. Nat. Commun. 6(1), 6949 (2015). https://doi.org/10.1038/ncomms7949
Atwa, M., Li, X., Wang, Z., Dull, S., Xu, S., Tong, X., Tang, R., Nishihara, H., Prinz, F., Birss, V.: Scalable nanoporous carbon films allow line-of-sight 3d atomic layer deposition of Pt: towards a new generation catalyst layer for pem fuel cells. Mater. Horiz. 8, 2451–2462 (2021). https://doi.org/10.1039/D1MH00268F
Wei, S., Qiu, Y., Sun, X., Wang, X., Li, H., Lan, G., Liu, J., Li, Y.: Sustainable nanoporous carbon catalysts derived from melamine assisted cross-linking of poly(vinyl chloride) waste for acetylene hydrochlorination. ACS Sustain. Chem. Eng. 10(32), 10476–10485 (2022). https://doi.org/10.1021/acssuschemeng.2c01183
Bandosz, T.J.: In: Liu, J., Ding F. (eds.) Nanoporous materials for molecule separation and conversion. Micro and nano technologies, pp. 45–64. Elsevier (2020). https://doi.org/10.1016/B978-0-12-818487-5.00002-9. https://www.sciencedirect.com/science/article/pii/B9780128184875000029
Bandosz, T.: Exploring the silent aspect of carbon nanopores. Nanomaterials 11(2), 407 (2021). https://doi.org/10.3390/nano11020407
Wang, H., Min, S., Ma, C., Liu, Z., Zhang, W., Wang, Q., Li, D., Li, Y., Turner, S., Han, Y., Zhu, H., Abou-hamad, E., Hedhili, M.N., Pan, J., Yu, W., Huang, K.W., Li, L.J., Yuan, J., Antonietti, M., Wu, T.: Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting. Nat. Commun. 8(1), 13592 (2017). https://doi.org/10.1038/ncomms13592
Cagnon, B., Secula, M.S., Sena Bayazit, Sahika.: In: Bartoli, M., Frediani, M., Rosi L. (eds.) Carbon-based material for environmental protection and remediation, IntechOpen, Rijeka (2020). https://doi.org/10.5772/intechopen.91355
Mao, H., Tang, J., Xu, J., Peng, Y., Chen, J., Wu, B., Jiang, Y., Hou, K., Chen, S., Wang, J., Lee, H.R., Halat, D.M., Zhang, B., Chen, W., Plantz, A.Z., Lu, Z., Cui, Y., Reimer, J.A.: Revealing molecular mechanisms in hierarchical nanoporous carbon via nuclear magnetic resonance. Matter 3(6), 2093–2107 (2020). https://doi.org/10.1016/j.matt.2020.09.024
El Mohajir, A., Castro-Gutiérrez, J., Canevesi, R.L.S., Bezverkhyy, I., Weber, G., Bellat, J.P., Berger, F., Celzard, A., Fierro, V., Sanchez, J.B.: Novel porous carbon material for the detection of traces of volatile organic compounds in indoor air. ACS Appl. Mater. Interfaces 13(33), 40088–40097 (2021). https://doi.org/10.1021/acsami.1c10430
Zhu, J., Huang, W., Fu, L., Zhu, B., Li, X., Wang, X., Wang, Y., Chen, W.: Nanoporous asphalt-based activated carbon prepared from emulsified asphalt and graphene oxide as high-thermal-conducting adsorbers for n-hexane vapor recovery. ACS Appl. Nano Mater. 4(11), 12453–12460 (2021). https://doi.org/10.1021/acsanm.1c02954
Kim, M., Xin, R., Earnshaw, J., Tang, J., Hill, J.P., Ashok, A., Nanjundan, A.K., Kim, J., Young, C., Sugahara, Y., Na, J., Yamauchi, Y.: Mof-derived nanoporous carbons with diverse tunable nanoarchitectures. Nat. Protocols 17(12), 2990–3027 (2022). https://doi.org/10.1038/s41596-022-00718-2
Hsu, C.C., Lin, Y.C., Lin, Y.Y., Li, H.T., Ni, C.S., Liu, C.I., Chang, C.C., Lin, L.C., Pan, Y.T., Liu, S.F., Liu, T.Y., Chen, H.Y.: Trapa natans husk-derived nanoporous carbons as electrode materials for sustainable high-power microbial fuel cell supercapacitor systems. Adv. Energy Sustain. Res. 3(5), 2100163 (2022). https://doi.org/10.1002/aesr.202100163
Sun, X., Liu, Y., Xu, R., Chen, Y.: Mof-derived nanoporous carbon incorporated in the cation exchange membrane for gradient power generation. Membranes 12(3), 322 (2022). https://doi.org/10.3390/membranes12030322
Yang, C., Xue, Z., Wen, J.: Recent advances in mof-based materials for remediation of heavy metals and organic pollutants: insights into performance, mechanisms, and future opportunities. Sustainability 15(8), 6686 (2023). https://doi.org/10.3390/su15086686
Xin, S., Guo, Y.G., Wan, L.J.: Nanocarbon networks for advanced rechargeable lithium batteries. Acc. Chem. Res. 45(10), 1759–1769 (2012). https://doi.org/10.1021/ar300094m
Chen, X., Gao, J., Wang, L., Zhu, P., Zhao, X., Wang, G., Liu, S.: Core-shell structured nanoporous N-doped carbon decorated with embedded Co nanoparticles as bifunctional oxygen electrocatalysts for rechargeable Zn-air batteries. New J. Chem. 45, 2760–2764 (2021). https://doi.org/10.1039/D0NJ06196D
Roszak, R., Firlej, L., Roszak, S., Pfeifer, P., Kuchta, B.: Hydrogen storage by adsorption in porous materials: is it possible? Colloids Surf. A 496, 69–76 (2016). Characterization of porous materials: from Angstroms to millimeters—VII https://doi.org/10.1016/j.colsurfa.2015.10.046. https://www.sciencedirect.com/science/article/pii/S092777571530306X
Hirscher, M., Zhang, L., Oh, H.: Nanoporous adsorbents for hydrogen storage. Appl. Phys. A 129(2), 112 (2023). https://doi.org/10.1007/s00339-023-06397-4
Rodríguez-Reinoso, F., Silvestre-Albero, J.: Methane Storage on nanoporous carbons, pp. 209–226. Springer, Singapore (2019). https://doi.org/10.1007/978-981-13-3504-4_8
Memetova, A., Tyagi, I., Karri, R.R., Suhas, Memetov, N., Zelenin, A., Stolyarov, R., Babkin, A., Yagubov, V., Burmistrov, I., Tkachev, A., Bogoslovskiy, V., Shigabaeva, G., Galunin, E.: High-density nanoporous carbon materials as storage material for methane: A value-added solution. Chem. Eng. J. 433, 134608 (2022). https://doi.org/10.1016/j.cej.2022.134608
Mabrouk, M., Rajendran, R., Soliman, I.E., Ashour, M.M., Beherei, H.H., Tohamy, K.M., Thomas, S., Kalarikkal, N., Arthanareeswaran, G., Das, D.B.: Nanoparticle- and nanoporous-membrane-mediated delivery of therapeutics. Pharmaceutics 11(6), 294 (2019). https://doi.org/10.3390/pharmaceutics11060294
Cheng, X., Zhang, Y., Lü, H., Liu, X., Hou, S., Chen, A. (2021). Porous carbon nanomaterials based tumor targeting drug delivery system a review. J. Inorg. Mater. 36(1), 9. https://doi.org/10.15541/jim20200240
Chen, J., Xiao, G., Duan, G., Wu, Y., Zhao, X., Gong, X.: Structural design of carbon dots/porous materials composites and their applications. Chem. Eng. J. 421, 127743 (2021). https://doi.org/10.1016/j.cej.2020.127743
Han, Y., Liu, H., Fan, M., Gao, S., Fan, D., Wang, Z., Chang, J., Zhang, J., Ge, K.: Near-infrared-ii photothermal ultra-small carbon dots promoting anticancer efficiency by enhancing tumor penetration. J. Colloid Interface Sci. 616, 595–604 (2022). https://doi.org/10.1016/j.jcis.2022.02.083
De, B., Karak, N.: A green and facile approach for the synthesis of water soluble fluorescent carbon dots from banana juice. RSC Adv. 3, 8286–8290 (2013). https://doi.org/10.1039/C3RA00088E
Nocito, G., Calabrese, G., Forte, S., Petralia, S., Puglisi, C., Campolo, M., Esposito, E., Conoci, S.: Carbon dots as promising tools for cancer diagnosis and therapy. Cancers 13(9), 1991 (2021). https://doi.org/10.3390/cancers13091991
Chatzimitakos, T., Stalikas, C.: Recent advances in carbon dots. C 5(3), 41 (2019). https://doi.org/10.3390/c5030041
Naik, G.G., Alam, M.B., Pandey, V., Mohapatra, D., Dubey, P.K., Parmar, A.S., Sahu, A.N.: Multi-functional carbon dots from an ayurvedic medicinal plant for cancer cell bioimaging applications. J. Fluoresc. 30(2), 407–418 (2020). https://doi.org/10.1007/s10895-020-02515-0
Tejwan, N., Saini, A.K., Sharma, A., Singh, T.A., Kumar, N., Das, J.: Metal-doped and hybrid carbon dots: a comprehensive review on their synthesis and biomedical applications. J. Control. Release 330, 132–150 (2021). https://doi.org/10.1016/j.jconrel.2020.12.023
Dugam, S., Nangare, S., Patil, P., Jadhav, N.: Carbon dots: a novel trend in pharmaceutical applications. Ann. Pharm. Fr. 79(4), 335–345 (2021). https://doi.org/10.1016/j.pharma.2020.12.002
Luo, W.K., Zhang, L.L., Yang, Z.Y., Guo, X.H., Wu, Y., Zhang, W., Luo, J.K., Tang, T., Wang, Y.: Herbal medicine derived carbon dots: synthesis and applications in therapeutics, bioimaging and sensing. J. Nanobiotechnol. 19(1), 320 (2021). https://doi.org/10.1186/s12951-021-01072-3
Serp, P., Corrias, M., Kalck, P.: Carbon nanotubes and nanofibers in catalysis. Appl. Catal. A 253(2), 337–358 (2003). https://doi.org/10.1016/S0926-860X(03)00549-0
Quinn, B.M., Dekker, C., Lemay, S.G.: Electrodeposition of noble metal nanoparticles on carbon nanotubes. J. Am. Chem. Soc. 127(17), 6146–6147 (2005). https://doi.org/10.1021/ja0508828
Day, T.M., Unwin, P.R., Wilson, N.R., Macpherson, J.V.: Electrochemical templating of metal nanoparticles and nanowires on single-walled carbon nanotube networks. J. Am. Chem. Soc. 127(30), 10639–10647 (2005). https://doi.org/10.1021/ja051320r
Hoeben, F.J.M., Meijer, F.S., Dekker, C., Albracht, S.P.J., Heering, H.A., Lemay, S.G.: Toward single-enzyme molecule electrochemistry: [nife]-hydrogenase protein film voltammetry at nanoelectrodes. ACS Nano 2(12), 2497–2504 (2008). https://doi.org/10.1021/nn800518d
Lu, J.: Effect of surface modifications on the decoration of multi-walled carbon nanotubes with ruthenium nanoparticles. Carbon 45(8), 1599–1605 (2007). https://doi.org/10.1016/j.carbon.2007.04.013
Ombaka, L., Ndungu, P., Nyamori, V.: Usage of carbon nanotubes as platinum and nickel catalyst support in dehydrogenation reactions. Catal. Today 217, 65–75 (2013). https://doi.org/10.1016/j.cattod.2013.05.014
Jasti, R., Bertozzi, C.R.: Progress and challenges for the bottom-up synthesis of carbon nanotubes with discrete chirality. Chem. Phys. Lett. 494(1), 1–7 (2010). https://doi.org/10.1016/j.cplett.2010.04.067
Lee, H., Lee, H.J., Jeong, J., Lee, J., Park, N.B., Lee, C.: Activation of persulfates by carbon nanotubes: oxidation of organic compounds by nonradical mechanism. Chem. Eng. J. 266, 28–33 (2015). https://doi.org/10.1016/j.cej.2014.12.065
Pan, H., Xia, Q., Wang, Y., Shen, Z., Huang, H., Ge, Z., Li, X., He, J., Wang, X., Li, L., Wang, Y.: Recent advances in biodiesel production using functional carbon materials as acid/base catalysts. Fuel Process. Technol. 237, 107421 (2022). https://doi.org/10.1016/j.fuproc.2022.107421
Meng, L., Zhang, X., Lu, Q., Fei, Z., Dyson, P.J.: Single walled carbon nanotubes as drug delivery vehicles: targeting doxorubicin to tumors. Biomaterials 33(6), 1689–1698 (2012). https://doi.org/10.1016/j.biomaterials.2011.11.004
Kordzadeh, A., Zarif, M., Amjad-Iranagh, S.: Molecular dynamics insight of interaction between the functionalized-carbon nanotube and cancerous cell membrane in doxorubicin delivery. Comput. Methods Programs Biomed. 230, 107332 (2023). https://doi.org/10.1016/j.cmpb.2022.107332
Desale, K., Kuche, K., Jain, S.: Cell-penetrating peptides (cpps): an overview of applications for improving the potential of nanotherapeutics. Biomater. Sci. 9, 1153–1188 (2021). https://doi.org/10.1039/D0BM01755H
Anzar, N., Hasan, R., Tyagi, M., Yadav, N., Narang, J.: Carbon nanotube—a review on synthesis, properties and plethora of applications in the field of biomedical science. Sens. Int. 1, 100003 (2020). https://doi.org/10.1016/j.sintl.2020.100003
Zhou, H.C.J., Kitagawa, S.: Metal-organic frameworks (mofs). Chem. Soc. Rev. 43, 5415–5418 (2014). https://doi.org/10.1039/C4CS90059F
Öhrström, L., Amombo Noa, F.M.: Metal-organic frameworks, American Chemical Society, Washington, DC, USA (2021). https://doi.org/10.1021/acs.infocus.7e4004. https://pubs.acs.org/doi/abs/10.1021/acs.infocus.7e4004
Yu, D., Song, Q., Cui, J., Zheng, H., Zhang, Y., Liu, J., Lv, J., Xu, T., Wu, Y.: Designing core-shell metal-organic framework hybrids: toward high-efficiency electrochemical potassium storage. J. Mater. Chem. A 9, 26181–26188 (2021). https://doi.org/10.1039/D1TA08215A
Cai, L.F., Zhan, J.M., Liang, J., Yang, L., Yin, J.: Structural control of a novel hierarchical porous carbon material and its adsorption properties. Sci. Rep. 12(1), 3118 (2022). https://doi.org/10.1038/s41598-022-06781-9
Eddaoudi, M., Li, H., Yaghi, O.M.: Highly porous and stable metal-organic frameworks: structure design and sorption properties. J. Am. Chem. Soc. 122(7), 1391–1397 (2000). https://doi.org/10.1021/ja9933386
Mai, Z., Liu, D.: Synthesis and applications of isoreticular metal-organic frameworks irmofs-n (n = 1, 3, 6, 8). Cryst. Growth Des. 19(12), 7439–7462 (2019). https://doi.org/10.1021/acs.cgd.9b00879
Cohen, S.M.: Postsynthetic methods for the functionalization of metal-organic frameworks. Chem. Rev. 112(2), 970–1000 (2012). https://doi.org/10.1021/cr200179u
Chavan, S., Vitillo, J.G., Gianolio, D., Zavorotynska, O., Civalleri, B., Jakobsen, S., Nilsen, M.H., Valenzano, L., Lamberti, C., Lillerud, K.P., Bordiga, S.: H2storage in isostructural UiO-67 and UiO-66 mofs. Phys. Chem. Chem. Phys. 14, 1614–1626 (2012). https://doi.org/10.1039/C1CP23434J
Wu, M.X., Yang, Y.W.: Metal-organic framework (mof)-based drug/cargo delivery and cancer therapy. Adv. Mater. 29(23), 1606134 (2017). https://doi.org/10.1002/adma.201606134
Micero, A., Hashem, T., Gliemann, H., Léon, A.: Hydrogen separation performance of uio-66-nh2 membranes grown via liquid-phase epitaxy layer-by-layer deposition and one-pot synthesis. Membranes 11(10), 735 (2021). https://doi.org/10.3390/membranes11100735
Du, L., Chen, W., Zhu, P., Tian, Y., Chen, Y., Wu, C.: Applications of functional metal-organic frameworks in biosensors. Biotechnol. J. 16(2), 1900424 (2021). https://doi.org/10.1002/biot.201900424
Liu, J., Yang, Y., Zhu, W., Yi, X., Dong, Z., Xu, X., Chen, M., Yang, K., Lu, G., Jiang, L., Liu, Z.: Nanoscale metal-organic frameworks for combined photodynamic & radiation therapy in cancer treatment. Biomaterials 97, 1–9 (2016). https://doi.org/10.1016/j.biomaterials.2016.04.034
Wang, X., Lan, P.C., Ma, S.: Metal-organic frameworks for enzyme immobilization: beyond host matrix materials. ACS Cent. Sci. 6(9), 1497–1506 (2020). https://doi.org/10.1021/acscentsci.0c00687
Dou, Y., Grande, C., Kaiser, A., Zhang, W.: Highly structured metal-organic framework nanofibers for methane storage. Sci. China Mater. 64(7), 1742–1750 (2021). https://doi.org/10.1007/s40843-020-1575-2
Wang, H.S., Wang, Y.H., Ding, Y.: Development of biological metal-organic frameworks designed for biomedical applications: from bio-sensing/bio-imaging to disease treatment. Nanoscale Adv. 2, 3788–3797 (2020). https://doi.org/10.1039/D0NA00557F
Peller, M., Böll, K., Zimpel, A., Wuttke, S.: Metal-organic framework nanoparticles for magnetic resonance imaging. Inorg. Chem. Front. 5, 1760–1779 (2018). https://doi.org/10.1039/C8QI00149A
Ghosh, S.K.: Metal-organic frameworks (MOFs) for environmental applications, Elsevier, Amsterdam, (2019). https://doi.org/10.1016/C2017-0-01721-4. https://www.sciencedirect.com/book/9780128146330
Jiao, L., Seow, J.Y.R., Skinner, W.S., Wang, Z.U., Jiang, H.L.: Metal-organic frameworks: structures and functional applications. Mater. Today 27, 43–68 (2019). https://doi.org/10.1016/j.mattod.2018.10.038
Rezaee, T., Fazel-Zarandi, R., Karimi, A., Ensafi, A.A.: Metal-organic frameworks for pharmaceutical and biomedical applications. J. Pharm. Biomed. Anal. 221, 115026 (2022). https://doi.org/10.1016/j.jpba.2022.115026
El-Bindary, A.A., Toson, E.A., Shoueir, K.R., Aljohani, H.A., Abo-Ser, M.M.: Metal-organic frameworks as efficient materials for drug delivery: synthesis, characterization, antioxidant, anticancer, antibacterial and molecular docking investigation. Appl. Organomet. Chem. 34(11), e5905 (2020). https://doi.org/10.1002/aoc.5905
Rutkowski, S., Si, T., Gai, M., Frueh, J., He, Q.: Hydrodynamic electrospray ionization jetting of calcium alginate particles: effect of spray-mode, spraying distance and concentration. RSC Adv. 8, 24243–24249 (2018). https://doi.org/10.1039/C8RA03490G
Horcajada, P., Serre, C., Vallet-Regí, M., Sebban, M., Taulelle, F., Férey, G.: Metal-organic frameworks as efficient materials for drug delivery. Angew. Chem. Int. Ed. 45(36), 5974–5978 (2006). https://doi.org/10.1002/anie.200601878
Beg, S., Rahman, M., Jain, A., Saini, S., Midoux, P., Pichon, C., Ahmad, F.J., Akhter, S.: Nanoporous metal organic frameworks as hybrid polymer-metal composites for drug delivery and biomedical applications. Drug Discov. Today 22(4), 625–637 (2017). https://doi.org/10.1016/j.drudis.2016.10.001
McKinlay, A., Morris, R., Horcajada, P., Férey, G., Gref, R., Couvreur, P., Serre, C.: Biomofs: metal-organic frameworks for biological and medical applications. Angew. Chem. Int. Ed. 49(36), 6260–6266 (2010). https://doi.org/10.1002/anie.201000048
Motakef-Kazemi, N., Shojaosadati, S.A., Morsali, A.: In situ synthesis of a drug-loaded mof at room temperature. Microporous Mesoporous Mater. 186, 73–79 (2014). https://doi.org/10.1016/j.micromeso.2013.11.036
Horcajada, P., Gref, R., Baati, T., Allan, P.K., Maurin, G., Couvreur, P., Férey, G., Morris, R.E., Serre, C.: Metal-organic frameworks in biomedicine. Chem. Rev. 112(2), 1232–1268 (2012). https://doi.org/10.1021/cr200256v
Zhuang, J., Young, A.P., Tsung, C.K.: Integration of biomolecules with metal-organic frameworks. Small 13(32), 1700880 (2017). https://doi.org/10.1002/smll.201700880
Haldorai, Y., Choe, S.R., Huh, Y.S., Han, Y.K.: Metal-organic framework derived nanoporous carbon/Co3O4 composite electrode as a sensing platform for the determination of glucose and high-performance supercapacitor. Carbon 127, 366–373 (2018). https://doi.org/10.1016/j.carbon.2017.11.022
He, S., Wu, L., Li, X., Sun, H., Xiong, T., Liu, J., Huang, C., Xu, H., Sun, H., Chen, W., Gref, R., Zhang, J.: Metal-organic frameworks for advanced drug delivery. Acta Pharm. Sin. B 11(8), 2362–2395 (2021). https://doi.org/10.1016/j.apsb.2021.03.019
Nazarian, D., Camp, J.S., Chung, Y.G., Snurr, R.Q., Sholl, D.S.: Large-scale refinement of metal-organic framework structures using density functional theory. Chem. Mater. 29(6), 2521–2528 (2017). https://doi.org/10.1021/acs.chemmater.6b04226
Yallappa, S., Manaf, S.A.A., Hegde, G.: Synthesis of a biocompatible nanoporous carbon and its conjugation with florescent dye for cellular imaging and targeted drug delivery to cancer cells. New Carbon Mater. 33(2), 162–172 (2018). https://doi.org/10.1016/S1872-5805(18)60332-4
Chaikittisilp, W., Hu, M., Wang, H., Huang, H.S., Fujita, T., Wu, K.C.W., Chen, L.C., Yamauchi, Y., Ariga, K.: Nanoporous carbons through direct carbonization of a zeolitic imidazolate framework for supercapacitor electrodes. Chem. Commun. 48, 7259–7261 (2012). https://doi.org/10.1039/C2CC33433J
Salunkhe, R.R., Kaneti, Y.V., Kim, J., Kim, J.H., Yamauchi, Y.: Nanoarchitectures for metal-organic framework-derived nanoporous carbons toward supercapacitor applications. Acc. Chem. Res. 49(12), 2796–2806 (2016). https://doi.org/10.1021/acs.accounts.6b00460
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Jäntschi, L. Nanoporous carbon, its pharmaceutical applications and metal organic frameworks. J Incl Phenom Macrocycl Chem 103, 245–261 (2023). https://doi.org/10.1007/s10847-023-01194-1
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DOI: https://doi.org/10.1007/s10847-023-01194-1