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Directed synthesis and study of their spectroscopic behavior in solution of rare-earth phthalocyaninates substituted by benzyloxy- and methylphenylethylphenoxy-groups

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Abstract

Novel neodymium phthalocyaninates based on template condensation of 4-[(4-benzyloxy)phenoxy]- or 4-(1-methyl-1-phenylethyl)phenoxyphthalonitriles with neodymium salts were obtained. The most selective preparation of neodymium sandwich complexes was found to occur with neodymium acetate as a template. The spectroscopic properties of neodymium metal complexes synthesized in organic solvents were studied. It was determined sandwich complexes of neodymium forms a mixture of in "blue" and "green" forms in the solution.

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Acknowledgements

This work was carried out with the financial support of the Russian Science Foundation (project 17-73-20017) using the equipment of the Center for Collective Usage of Ivanovo State University of Chemistry and Technology.

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  1. Ivanovo State University of Chemistry and Technology, Sheremetevsky Ave. 7, Ivanovo, Russian Federation, 153000

    A. A. Botnar, A. N. Bychkova, N. P. Domareva, T. V. Tikhomirova & A. S. Vashurin

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  1. A. A. Botnar
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  2. A. N. Bychkova
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Correspondence to T. V. Tikhomirova.

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Botnar, A.A., Bychkova, A.N., Domareva, N.P. et al. Directed synthesis and study of their spectroscopic behavior in solution of rare-earth phthalocyaninates substituted by benzyloxy- and methylphenylethylphenoxy-groups. J Incl Phenom Macrocycl Chem 102, 303–311 (2022). https://doi.org/10.1007/s10847-021-01120-3

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