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Novel optically active 2D materials based on λ-zirconium phosphate and chiral monocarboxylic acids: Synthesis and characterization

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Abstract

Five novel chiral 2D materials with general formula λ-ZrPO4(OH)1-x(RCOO)x(dmso) have been prepared by covalent anchoring of five different chiral carboxylic acids to the sheets of λ-zirconium phosphate (λ-ZrP), namely (S)-(+)-Mandelic acid (MAN), (R)-(−)-α-Methoxyphenylacetic acid (MPA), (S)-(+)-Ibuprofen (IBU), (S)-(+)-6-Methoxy-α-methyl-2-naphthaleneacetic acid (MMN) and (−)-Menthyloxyacetic acid (MEN). The synthesized materials were characterized by X-ray diffractometry, FT-IR spectrophotometry, elemental and thermogravimetric analyses and polarimetry. The X-ray diffraction patterns revealed that the interlayer separations increase from 1.02 nm (pure λ-ZrP) to 1.31–2.31 nm as a result of the incorporation of the mentioned acids within the interlayer gallery. The polarimetry measurements showed that the synthesized materials have appreciable optical activities suggesting they could have protentional applications in the field of chiral separation techniques.

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Acknowledgements

The authors are thankful to the Qatar Charity for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Al-Azhar University - Gaza, 1277, Gaza, Palestine

    Hussein Alhendawi & Huda Alkahlout

  2. Departamento de Química Orgánica, Universidad Autónoma de Madrid, Facultad de Ciencias C-I-602, 28049, Madrid, Spain

    Ernesto Brunet & Elena Rodríguez Payán

Authors
  1. Hussein Alhendawi
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  2. Ernesto Brunet
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  3. Elena Rodríguez Payán
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  4. Huda Alkahlout
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Correspondence to Hussein Alhendawi.

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Alhendawi, H., Brunet, E., Payán, E.R. et al. Novel optically active 2D materials based on λ-zirconium phosphate and chiral monocarboxylic acids: Synthesis and characterization. J Incl Phenom Macrocycl Chem 99, 217–226 (2021). https://doi.org/10.1007/s10847-021-01043-z

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  • DOI: https://doi.org/10.1007/s10847-021-01043-z

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