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Synthesis, characterization of novel rotaxanes depend on cyclodextrins

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Abstract

In the present work, new bis hexachloro methanoisoindol derivatives (1) and (3) were prepared. Also, novel interlocked compounds [2] rotaxane (2) and [3] rotaxane (4) have been synthesized. [2] rotaxane (2) was formed by threading of β-cyclodextrin into succinic dihydrazide to give pseudorotaxane that was trapped by using chlorendic anhydride. [3] rotaxane (4) was obtained by entering α-cyclodextrin rings through sebacoyl chloride to afford the corresponding pseudorotaxane and locked in the terminal groups by using N-amino-1,4,5,6,7,7-hexachloro-5-norbornene-2,3-dicarboximide. The chemical structure of the obtained compounds was confirmed by FT-IR, 1H-NMR, 13C-NMR and 2D-NMR (cosy) spectra. The morphology of [2] and [3] rotaxanes was examined by Scanning Electron Microscope.

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Acknowledgements

The author is grateful to her father, Prof. Aly of organic chemistry and her family.

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  1. Chemistry Department, Faculty of Science, South Valley University, Qena, Egypt

    Hemat M. Dardeer

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Correspondence to Hemat M. Dardeer.

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Dardeer, H.M. Synthesis, characterization of novel rotaxanes depend on cyclodextrins. J Incl Phenom Macrocycl Chem 91, 105–114 (2018). https://doi.org/10.1007/s10847-018-0805-1

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