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Synthesis of a linearly linked triscalixarene consisting of calix[4]arene units with combined axial chirality and inherent chirality

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Abstract

A linearly linked triscalix[4]arene, in which each calix[4]arene unit possesses both axial chirality and inherent chirality, was synthesized by repeated use of two stereoselective Williamson etherification on calix[4]arene. In the crystal lattice of the biscalix[4]arene intermediate, there are interesting alternate layers of biscalixarene molecules and solvent molecules in the ab plane.

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Acknowledgements

The authors are grateful to the National Natural Science Foundation of China (NSFC) (Grant No. 20902029) and the Fundamental Research Funds for the Central Universities (HUST: No. 2014QN130) for financial support. The Analytical and Testing Center of Huazhong University of Science and Technology is thanked for measurement service.

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Authors and Affiliations

  1. Tongji School of Pharmacy, Huazhong University of Science and Technology, No. 13 Hangkong Road, Wuhan, 430030, China

    Hui Ma, Wen-Zhen Zhang, Jun Luo & Guang-Ya Xiang

  2. School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510275, China

    Jun-Min Liu

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  1. Hui Ma
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  2. Wen-Zhen Zhang
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  3. Jun Luo
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  4. Jun-Min Liu
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Corresponding authors

Correspondence to Jun Luo or Jun-Min Liu.

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Ma, H., Zhang, WZ., Luo, J. et al. Synthesis of a linearly linked triscalixarene consisting of calix[4]arene units with combined axial chirality and inherent chirality. J Incl Phenom Macrocycl Chem 89, 91–104 (2017). https://doi.org/10.1007/s10847-017-0722-8

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  • DOI: https://doi.org/10.1007/s10847-017-0722-8

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