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Cerium(IV) phenylphosphonates and para-substituted phenylphosphonates: preparation and characterization

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Abstract

Cerium(IV) phenylphosphonates and 4-substituted phenylphosphonates were prepared by reaction of a cerium(IV) salt with corresponding acids (phenylphosphonic, 4-carboxyphenylphosphonic, 4-sulfamoylphenylphosphonic, 1,4-benzenediphosphonic, 1,4-biphenyldiphosphonic and 4-sulfophenylphosphonic acid) and characterized by elemental analysis, energy-dispersive X-ray analysis, TGA, powder X-ray diffraction and infrared spectroscopy. Three different cerium phenylphosphonates can be prepared in dependence on the reaction conditions. On the other hand, only one compound is formed in each 4-substituted phosphonate system regardless the variation of the reaction conditions. All three phenylphosphonates, 4-carboxyphenylphosphonate and 4-sulfamoylphenylphosphonate are layered with the organic parts pointed below and above the plane of the metal phosphonate layers, with the functional groups placed at the end of the organic part. 4-Sulfophenylphosphonate, 1,4-benzenediphosphonate and 4,4′-biphenyldiphosphonate form pillared structures. Cerium 4-carboxyphenylphosphonate is able to intercalate aliphatic amines due to the presence of the free carboxylic groups in its interlayer space.

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Acknowledgements

The authors thank the Czech Science Foundation (Grant No 14-13368S) for financial support.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry of Academy of Sciences of the Czech Republic, Heyrovský Sq. 2, 162 06, Prague 6, Czech Republic

    K. Melánová, J. Svoboda, V. Zima, M. Trchová & M. Vlček

  2. Faculty of Chemical Technology, University of Pardubice, Studentská 95, 532 10, Pardubice, Czech Republic

    L. Beneš & N. Almonasy

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  1. K. Melánová
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  2. L. Beneš
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  3. J. Svoboda
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Correspondence to L. Beneš.

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Melánová, K., Beneš, L., Svoboda, J. et al. Cerium(IV) phenylphosphonates and para-substituted phenylphosphonates: preparation and characterization. J Incl Phenom Macrocycl Chem 87, 331–339 (2017). https://doi.org/10.1007/s10847-017-0701-0

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  • DOI: https://doi.org/10.1007/s10847-017-0701-0

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