Abstract
Cyclodextrins are cyclic oligosaccharides, which form complexes with different organic substances such as drugs, odors, and etc. Due to the complexing abilities of cyclodextrins (CDs), they may also be used in textile industry as an auxiliary in washing, dyeing, and wastewater treatment. Fixation of CDs on textiles is possible using reactive derivatives of cyclodextrins or crosslinking agents. In this study we have investigated the use of polyaminocarboxylic acids (PACAs) as novel crosslinking agents for the fixation of β-CD on cotton fabrics. Fixation of β-CD on cotton fabric has been quantified by measuring the weight increase of the treated samples. The influence of the concentration of the catalyst (sodium hypophosphite) was studied, too. The presence of β-CD on the cotton has been investigated by the phenolphthalein test and host–guest complexation with organic volatile molecules: cyclohexene, chlorobenzene, cyclohexene-1-one and toluene.
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Buschmann, H.-J., Denter, U., Knittel, D., Schollmeyer, E.: The use of cyclodextrins in textile processes-an overview. J. Text. I(89), 554–561 (1998)
Szejtli, J.: Cyclodextrin Technology. Kluwer, Dordrecht (1988)
Lo Nostro, P., Fratoni, L., Ridi, F., Baglioni, P.: Surface treatment on tencel fabric: grafting with β-cyclodextrin. J. Appl. Polym. Sci. 88, 706–715 (2003)
Buschmann, H.-J., Knittel, D., Schollmeyer, E.: New textile applications of cyclodextrins. J. Incl. Phenom. Macro. 40, 169–172 (2001)
Denter, U., Buschmann, H.-J., Knittel, D., Schollmeyer, E.: Modifizierung von Faseroberflächen durch die permanente Fixierung supermolekulare Komponenten, Teil 2: cyclodextrin. Angew. Macromol. Chem. 248, 165–188 (1997)
Schollmayer, E., Buschmann, H.-J., Jansen, K., Wego, A.: Surface modification of polymers using supramolecular compounds. Prog. Coll. Pol. Sci. S. 121, 39–42 (2002)
Denter, U., Schollmeyer, E. In: Szejtli, J., Szente, L. (eds.) Proceedings of the VIIIth international symposium on cyclodextrins. pp. 559–564. Budapest (1996)
Reuscher, H., Hirsenkorn, R.: Beta W7 MCT - New ways in surface modification. J. Inclusion Phenom. Mol. Recognit. Chem. 25, 191–196 (1996)
Denter, U., Schollmeyer, E.: Surface modification of synthetic and natural fibers by fixation of cyclodextrin derivatives. J. Inclusion Phenom. Mol. Recognit. Chem. 25, 197–202 (1996)
Lo Nostro, P., Fratoni, L., Baglioni, P.: Modification of a cellulosic fabric with β-cyclodextrin for textile finishing applications. J. Incl. Phenom. Macro. 44, 423–427 (2002)
Lee, M., Yoon, K., Ko, S.-W.: Synthesis of a vinyl monomer containing β-cyclodextrin and grafting onto cotton fiber. J. Appl. Polym. Sci. 80, 438–446 (2001)
Szejtli, J., Zsadon, B., Fenyvesi, E., Horvarth, O., Tudos, F.: Patent No. 4,357,468, US 1982
Buschmann, H.-J., Knittel, D., Schollmeyer, E.: Hochveredlung von Baumwolle in Anwesenheit von Cyclodextrinen zur Einlagerung von Duftstoffen. Melliand Textilberichte. 72, 198–199 (1991)
Martel, B., Weltrowski, M., Ruffin, D., Morcellet, M.: Polycarboxylic acids as crosslinking agents for grafting cyclodextrins onto cotton and wool fabrics: study of the process parameters. J. Appl. Polym. Sci. 83, 1449–1456 (2002)
Martel, B., Morcellet, M., Ruffin, D., Weltrowski, M.: Finishing of polyester fabrics with cyclodextrins and polycarboxylic acids as crosslinking agents. J. Incl. Phenom. Macro. 44, 443–446 (2002)
Voncina, B., Majcen Le Marechal, A.: Grafting of cotton with β-cyclodextrin via poly(carboxylic acid). J. Appl. Polym. Sci. 96, 1323–1328 (2005)
Voncina, B., Vivod, V., Chen, W.-T.: Surface modification of PET fibers with the use of β-cyclodextrin. J. Appl. Polym. Sci. 113, 3891–3895 (2009)
Ducoroy, L., Martel, B., Bacquet, M., Morcellet, M.: Cation exchange finishing of nonwoven polyester with polycarboxylic acids and cyclodextrins. J. Appl. Polym. Sci. 103, 3730–3738 (2007)
Buschmann, H-J., Ameri Dehabadi, V., Gutmann, J.: Multi-functional finish of cotton using polyaminocarboxylic Acids. In: ITC & DC Book of Proceedings, ISSN 1847-7275, pp 185-190. Dubrovnik (2012)
Ameri Dehabadi, V., Buschmann, H.-J., Gutmann, J.: Durable press finishing of cotton fabrics with polyamino carboxylic acids. Carbohyd. Polym. 89, 558–563 (2012)
Ameri Dehabadi, V., Buschmann, H.-J., Gutmann, J.: Pretreatment of cotton fabrics with polyamino carboxylic acids for salt-free dyeing with reactive dyes. Color. Technol. 129(2), 155–158 (2013)
Ameri Dehabadi, V., Buschmann, H.-J., Gutmann, J.: Study of easy care and biostatic properties of finished cotton with polyamino carboxylic acids. J. Text. I. 104(4), 414–418 (2013)
Ameri Dehebadi, V., Buschmann, H-J., Gutmann, J.: Flame retardant finishing of cotton fabrics using polyamino carboxylic acids and sodium hypophosphite. Fire Mat. DOI: 10.1002/fam.2170
Grechin, A., Buschmann, H.-J., Schollmeyer, E.: Quantification of cyclodextrins fixed onto cellulose fibers. Text. Res. J. 77(3), 161–164 (2007)
Dantz, D.A., Meschke, C., Buschmann, H.-J., Schollmayer, E.: Complexation of volatile organic molecules from the gas phase with cucurbituril and β-Cylodextrin. Supramol. Chem. 9, 79–83 (1998)
Acknowledgments
The research project (IGF-Nr. 17082 N) of the Forschungskuratorium Textil e. V. was funded by the Arbeitsgemeinschaft industrieller Forschungsvereinigungen e. V. (AiF) within the program “Industrielle Gemeinschaftsforschung und –entwicklung (IGF)” by the Bundesministerium für Wirtschaft und Technologie based on a decision of the Deutsche Bundestag.
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Dehabadi, V.A., Buschmann, HJ. & Gutmann, J.S. A novel approach for fixation of β-cyclodextrin on cotton fabrics. J Incl Phenom Macrocycl Chem 79, 459–464 (2014). https://doi.org/10.1007/s10847-013-0368-0
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DOI: https://doi.org/10.1007/s10847-013-0368-0