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Studies on inclusion complexes of 2,4-dinitrophenol, 2,4-dinitroaniline, 2,6-dinitroaniline and 2,4-dinitrobenzoic acid incorporated with β-cyclodextrin used for a novel UV absorber for ballpoint pen ink

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Abstract

The inclusion complexes of β-cyclodextrin with different dinitrocompounds like 2,4-dinitrophenol, 2,4-dinitroaniline, 2,6-dinitroaniline and 2,4-dinitrobenzoic acid appears the UV absorption bands in different wavelength region below 400 nm, a combination of these dinitro aromatic compounds of inclusion complexes can improve the UV protection properties of ball point pen ink against photo degradation. The formation of inclusion complexes were characterized by FT-IR, 1H NMR and 2D ROESY NMR spectroscopy. The UV protecting properties of these inclusion complexes were calculated their sun protection factor was discussed. The stability of the ballpoint pen ink has been confirmed by UV–visible spectroscopic method.

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Acknowledgments

One of the authors K. Srinivasan acknowledges to UGC-BSR for providing Research Fellowship for Science Meritorious (AU/UGC-BSR/IC/1069/2011) and SAIF IIT Madras for utilizing the 1H NMR spectra facility and also thankful to S. Radhakrishnan, Scientist, CECRI, Karaikudi for utilizing the 2D ROESY NMR spectra facility.

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  1. Department of Industrial Chemistry, School of Chemical Sciences, Alagappa University, Karaikudi, 630 003, Tamilnadu, India

    K. Srinivasan & T. Stalin

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  1. K. Srinivasan
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  2. T. Stalin
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Correspondence to T. Stalin.

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Srinivasan, K., Stalin, T. Studies on inclusion complexes of 2,4-dinitrophenol, 2,4-dinitroaniline, 2,6-dinitroaniline and 2,4-dinitrobenzoic acid incorporated with β-cyclodextrin used for a novel UV absorber for ballpoint pen ink. J Incl Phenom Macrocycl Chem 78, 337–350 (2014). https://doi.org/10.1007/s10847-013-0304-3

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