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Synthesis and spectral characterization of azo dyes derived from calix[4]arene and their application in dyeing of fibers

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Abstract

In this study, the synthesis and characterization of two new upper rim functionalized azocalix[4]arene dyes have been obtained by coupling calix[4]arene with different diazo compounds of 3,5-dicarboxyaniline and 4-aminobenzene sulphon amide. The characterization of these dyes has been carried out by elemental analysis, FT-IR and 1H NMR spectra. The effect of varying dielectric constants of solvents on the absorption spectra of azocalix[4]arenes (1, 2, 3, 4) and commercial Isolan Gelb SGL (T) have been examined by UV–Vis spectrophotometer. These azocalix[4]arene dyes have also been used for dyeing textile fibers like cotton, wool, acetate, polyester and polyamide fibers. Their dyeing and fastness properties have also been discussed.

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Acknowledgments

Authors thank to the Research Foundation of Pamukkale University for the financial support (BAP, 2010FBE011) and Deniz Textile Factory.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Pamukkale University, 20017, Denizli, Turkey

    Serkan Elçin & Hasalettin Deligöz

  2. Deniz Textile Factory, Organized Industrial District, 20017, Denizli, Turkey

    Murat Muzaffer İlhan

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  1. Serkan Elçin
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  2. Murat Muzaffer İlhan
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  3. Hasalettin Deligöz
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Correspondence to Serkan Elçin.

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Elçin, S., İlhan, M.M. & Deligöz, H. Synthesis and spectral characterization of azo dyes derived from calix[4]arene and their application in dyeing of fibers. J Incl Phenom Macrocycl Chem 77, 259–267 (2013). https://doi.org/10.1007/s10847-012-0240-7

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