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Single step preparation and conformational analysis of novel thiophosphorylated ligands based on calix[4]resorcinol matrix

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Abstract

We have synthesized novel calix[4]resorcinols with four 2-thioxo-1,3,2-dioxaphospholane groups introduced in aromatic substituents in the methylidene bridges of macromolecules by the condensation of new thiophosphorylated benzaldehyde with resorcinol and its derivatives in acidic media with high yields. The formation of only one rctt isomer with corresponding chair conformation is observed, which was determined by 2D NMR-experiments.

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Acknowledgments

The work was supported by the Russian Foundation for Basic Research (grant 11-03-00416-a) and DAAD (Deutscher Akademischer Austauschdienst).

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Authors and Affiliations

  1. State Budgetary-Funded Institution of Science, A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Str. 8, 420088, Kazan, Russian Federation

    Irina R. Knyazeva, Victoria I. Sokolova, Julia K. Voronina, Alexander R. Burilov & Michael A. Pudovik

  2. TU Dresden, Institute of Organic Chemistry, Bergstr. 66, 01069, Dresden, Germany

    Margit Gruner & Wolf D. Habicher

Authors
  1. Irina R. Knyazeva
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  2. Victoria I. Sokolova
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  3. Margit Gruner
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  4. Wolf D. Habicher
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  5. Julia K. Voronina
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  6. Alexander R. Burilov
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  7. Michael A. Pudovik
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Correspondence to Irina R. Knyazeva.

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Knyazeva, I.R., Sokolova, V.I., Gruner, M. et al. Single step preparation and conformational analysis of novel thiophosphorylated ligands based on calix[4]resorcinol matrix. J Incl Phenom Macrocycl Chem 76, 231–235 (2013). https://doi.org/10.1007/s10847-012-0190-0

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  • DOI: https://doi.org/10.1007/s10847-012-0190-0

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