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Enhancement inhibition efficiency of PBTCA depending on the inclusion complex with hydroxypropyl-β-cyclodextrin

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Abstract

For the first time, hydroxypropyl-β-cyclodextrin (HP-β-CD) has been brought in to include 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) in order to enhance inhibition efficiency of PBTCA, which leads a new approach to study oil–gas field corrosion inhibition in the process of acid treatment. Based on the host–guest inclusion reaction, the inclusion complex of PBTCA with HP-β-CD has been prepared in the laboratory. UV–Vis absorption spectrum was applied to study the inclusion behavior of PBTCA with HP-β-CD. The results revealed that PBTCA with HP-β-CD can form a 1:1 stoichiometry inclusion complex. The 1:1 inclusion complex synthesized by using lyophilization was further characterized by Fourier transform infrared spectroscopy. Besides, inhibition effect of the inclusion complex on the corrosion inhibition of Q235 carbon steel has been investigated in 0.1 M sulfuric acid (H2SO4) solution using potentiodynamic polarization, electrochemical impedance spectroscopy techniques and scanning electron microscopy (SEM). It was found that the presence of the inclusion complex better achieved the anti-corrosion property in aggressive medium than was the case with alone PBTCA and the highest inhibition efficiency of the inclusion complex over 90 % was obtained, which are suggestive of the active effect of the inclusion complex for improving inhibition efficiency of PBTCA. Meanwhile, the results obtained from SEM further showed that the inclusion complex acts as a more efficient corrosion inhibitor for Q235 carbon steel in H2SO4 medium.

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Acknowledgments

This work has been supported by the National High Technology Research and Development Program (“863” Program) of China (2007AA11A117) from the Ministry of Science and Technology of China. Financial support of the “863” Program is highly appreciated.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, China

    Chang Jun Zou, Quan Wu Tang & Gui Hong Lan

  2. Yunnan Chemical Research Institute, Yunnan, China

    Qiang Tian

  3. Liaohe Oilfield Co, PetroChina, Panjin, China

    Tai Yu Wang

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  1. Chang Jun Zou
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  2. Quan Wu Tang
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Correspondence to Chang Jun Zou.

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Zou, C.J., Tang, Q.W., Lan, G.H. et al. Enhancement inhibition efficiency of PBTCA depending on the inclusion complex with hydroxypropyl-β-cyclodextrin. J Incl Phenom Macrocycl Chem 76, 61–68 (2013). https://doi.org/10.1007/s10847-012-0173-1

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