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Inclusion complexes of sodium perchlorate into [CuLSS] and [CuLrac]; H2LSS = bis(3-methoxy-2-hydroxy-1-benzylidene)-1S,2S-cyclohexanediamine, H2Lrac = its racemic form

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Abstract

Inclusion complexes of LiClO4 or NaClO4 into [CuLSS] or [CuLrac] are reported, where [CuLSS] denotes bis(3-methoxy-2-oxy-1-benzylidene)-1S,2S-cyclohexanediaminecopper(II) and [CuLrac] denotes the racemic complex. The inclusion reaction of LiClO4 and NaClO4 into [CuLSS] gave the [1 + 1] adduct of [CuLSS(H2O)LiClO4] and the [2 + 1] adduct of [(CuLSS)2Na(H2O)3]ClO4, respectively, while that of NaClO4 into [CuLrac] gave the [2 + 2] adduct of [CuLracNaClO4]2·CH3CN ([(CuLSSNaClO4)(CuLRRNaClO4)]·CH3CN).

Graphical Abstract

Reaction of NaClO4 and [CuLSS] gave the [2 + 1] adduct [(CuLSS)2Na(H2O)3]ClO4, while the reaction of NaClO4 and the racemic complex [CuLrac] gave the [2 + 2] adduct [CuLracNaClO4]2, where [CuLSS] denotes bis(3-methoxy-2-oxy-1-benzylidene)-1S,2S-cyclohexanediaminecopper(II).

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References

  1. Lehn, J.M.: Toward self-organization and complex matter. Science 295, 2400–2403 (2002)

    Article  CAS  Google Scholar 

  2. Seidel, S.R., Stang, P.J.: High-symmetry Coordination Cages via Self-assembly. Acc. Chem. Res. 35, 972–983 (2002)

    Article  CAS  Google Scholar 

  3. Gruber, S.J., Harris, C.M., Sinn, E.: Metal complexes as ligands bi- and tri-nuclear complexes containing similar and dissimilar metal atoms. J. Inorg. Nucl. Chem. 3, 495–499 (1967)

    Article  CAS  Google Scholar 

  4. Armstrong, L. G., Lip, H. C., Lindoy, L. F., McPartlin, M., Tasker, P. A.: Alkali-metal salt adducts of Ni(II) complexes of quadridentate Schiff-base ligands. The X-ray structure of N,N’-ethylenebis(acetylacetoniminato)nickel(II). J. Chem. Soc. Dalton Trans. 1771-1774 (1977)

  5. Maruno, Y., Yabe, K., Hagiwara, H., Fujinami, T., Matsumoto, N., Re, N., Mrozinski, J.: Cyclic and linear structures constructed by ionic bonds between alkali ion and pinwheel pentanuclear [GdIII(CuIIL)4] core of M[GdIII(CuIIL)4] (M+ = Na+, K+, and Cs+; H3L = N-(4-methyl-6-oxo-3-azahept-4-enyl)oxamic acid). Bull. Chem. Soc. Jpn. 83, 1511–1517 (2010)

    Article  CAS  Google Scholar 

  6. Jiang, Z., Lu, H., Wu, D., Zhou, X., Shen, Z., Kobayashi, N.: Color difference caused by chirality. Inorg. Chem. Commun. 14, 13–1416 (2011)

    Article  CAS  Google Scholar 

  7. Leung, D., Follmer-Andersen, J.F., Lynch, V.M., Anslyn, E.V.: Using Enantioselective Indicator Displacement Assays to determine the Enantiomeric Excess of α-Amino-Acids. J. Am. Chem. Soc. 130, 12318–12327 (2008)

    Article  CAS  Google Scholar 

  8. Mamdouh, W., Uji-i, H., Gesquière, A., De Feyter, S., Amabilino, D.B., Abdel-Mottaleb, M.M.S., Veciana, J., Schryver, F.C.: A nanoscale view of supramolecular stereochemistry in self-assembled monolayers of enantiomers and racemates. Langmuir 20, 9628–9635 (2004)

    Article  CAS  Google Scholar 

  9. Katsuki, I., Motoda, Y., Sunatsuki, Y., Matsumoto, N., Nakashima, T., Kojima, M.: Spontaneous resolution induced by self-organization of chiral self-complementary cobalt (III) complexes with achiral tripod-type ligands containing three imidazole groups. J. Am. Chem. Soc. 124, 629–640 (2002)

    Article  CAS  Google Scholar 

  10. Stefankiewicz, A. R., Walesa, M., jankowski, P, Ciesielski, A., Patroniak, V., Kubicki, M., Hnatejko, M., Harrowfield, J. M., Lehn, J-M.: Quetrpyridine Ligands forming Helical Complexes of Mono- and Bi-nuclear (Helicate) Forms. Eur. J. Inorg. Chem. 2910–2920 (2008)

  11. Shimogori, Y., Hamamatsu, T., Fujinami, T., Hagiwara, H., Matsumoto, N., Re, N., Mrozinski, J., Ishikawa, Y., Igashira-Kamiyama, A., Konno, T.: Linear CuII-GdIII-CuII-GdIII complex derived from assembly reaction of [NaCuIIH3Ldpen(meso)] and [GdIII(thd)3(H2O)2] (H3L = meso-1,2-diphenyl-1-(2-oxybenzamido)-2-(2-oxy-3-ethoxybenzylideneamino)ethane and Hthd = 2,2,6,6-tetra-methyl-3,5-heptanedione). Polyhedron 30, 1127–1133 (2011)

    Article  CAS  Google Scholar 

  12. Hamamatsu, T., Matsumoto, N., Re, N., Mrozinski, J.: Chiral ferromagnetic chain of Copper(II)–Gadolinium(III) complex. Chem. Lett. 38, 762–763 (2009)

    Article  CAS  Google Scholar 

  13. Szlyk, E., Surdykowski, A., Barwiolek, M., Larsen, E.: Spectroscopy and stereochemistry of the optically active copper(II), cobalt(II) and Ni(II) complexes with Schiff Bases N, N′-(1R, 2R)-(−)-1, 2-cyclohexylenebis(3-methylbenzylideniminato) and N, N′-(1R, 2R)-(−)-1, 2-cyclohexylenebis(5-methylbenzylideniminato). Polyhedron 21, 2711–2717 (2002)

    Article  CAS  Google Scholar 

  14. CrystalStructure 4.0: Crystal Structure Analysis Package, Rigaku Corporation (2000–2010). Tokyo 196-8666, Japan

  15. Flack, H.D.: On enantiomorph-polarity estimation. Acta Cryst. A39, 876–881 (1983)

    CAS  Google Scholar 

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Authors and Affiliations

  1. Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Kumamoto, 860-8555, Japan

    Takeshi Fujinami, Ryuichi Kinoshita, Hirokazu Kawashima & Naohide Matsumoto

  2. Institut de Science et d’Ingénierie Supramoléculaires, Université de Strasbourg, 8, allée Gaspard Monge, 67083, Strasbourg, France

    Jack H. Harrowfield

  3. Department of Chemistry and Advanced Materials, Kosin University, 149-1, Dongsam-dong, Yeongdo-gu, Busan, 606-701, South Korea

    Yang Kim

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  1. Takeshi Fujinami
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  2. Ryuichi Kinoshita
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  3. Hirokazu Kawashima
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  4. Naohide Matsumoto
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  5. Jack H. Harrowfield
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  6. Yang Kim
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Correspondence to Naohide Matsumoto.

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Dedicated to Professor Len Lindoy, one of the originators of the field of chemistry concerned in this article, on the occasion of his 75th birthday.

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Fujinami, T., Kinoshita, R., Kawashima, H. et al. Inclusion complexes of sodium perchlorate into [CuLSS] and [CuLrac]; H2LSS = bis(3-methoxy-2-hydroxy-1-benzylidene)-1S,2S-cyclohexanediamine, H2Lrac = its racemic form. J Incl Phenom Macrocycl Chem 71, 463–469 (2011). https://doi.org/10.1007/s10847-011-9980-z

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  • DOI: https://doi.org/10.1007/s10847-011-9980-z

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