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Lamellar molybdenum oxide as a molecular sieve towards nitrogen containing molecules: intercalation compounds with pyridazine, acrylamid and tris(hydroxymethyl)aminomethane

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Abstract

The synthesis and characterization (by CHN elemental analysis, FTIR spectroscopy, XRD diffractometry, thermogravimetry and SEM microscopy) of MoO3 intercalation compounds with pyridazine (pdz), acrylamid (ald) and tris(hydroxymethyl)aminomethane (tham) is reported. Such investigation was performed taking into account the possible uses of molybdenum trioxide as a molecular sieve towards nitrogen containing compounds. It is verified that the affinity of MoO3 towards the investigated species follows the sequence: ald ≅ tham > pdz.

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Authors and Affiliations

  1. Departamento de Química, Universidade Federal de Roraima, Cx. Postal 167, 69301-970, Boa Vista, Roraima, Brazil

    Robson F. de Farias

  2. Department of Chemistry, Faculty of Education, Port-Said, Suez-Canal University, Port Said, Egypt

    Moamen S. Refat

  3. Department of Physics, Faculty of Science, Zagazig University, Zagazig, Egypt

    Hassan A. Hashem

Authors
  1. Robson F. de Farias
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  2. Moamen S. Refat
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  3. Hassan A. Hashem
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Correspondence to Robson F. de Farias.

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de Farias, R.F., Refat, M.S. & Hashem, H.A. Lamellar molybdenum oxide as a molecular sieve towards nitrogen containing molecules: intercalation compounds with pyridazine, acrylamid and tris(hydroxymethyl)aminomethane. J Incl Phenom Macrocycl Chem 61, 113–118 (2008). https://doi.org/10.1007/s10847-007-9402-4

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  • DOI: https://doi.org/10.1007/s10847-007-9402-4

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