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Thermal and spectral analyses of complexes of zinc(II)tetra-tertbutylphthalocyanine with amines

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Abstract

Spectral and thermochemical studies of complexes of zinc(II)tetra-tertbutylphthalocyanine (Zn(t-Bu)4Pc) with some amines have been carried out. Spectral effects of the complex formation of the metallophthalocyanine with amines have been established. It has been found that an ability of Zn(t-Bu)4Pc to coordinate amines depends on both their nature and conditions of preparation. Similarity of the crystal structures of biligand and monoligand of Zn(t-Bu)4Pc complexes to individual β- and α-polymorphs of Zn(t-Bu)4Pc, respectively is proved by IR spectroscopy and X-ray diffraction method.

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Acknowledgements

This work was supported by Russian Academy of Sciences (Document of Presidium of RAS “About organization of works of young researchers in priority directions of fundamental studies” No10324-812 and Program of federal budget of RAS “Directional synthesis of compounds with prescribed properties and creation of functional materials on their basis” No8P).

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  1. Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheska st., 1, Ivanovo, 153045, Russia

    Nataliya Sh. Lebedeva, Elena A. Malkova, Elena V. Parfenyuk & Anatoliy I. Vyugin

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  1. Nataliya Sh. Lebedeva
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  2. Elena A. Malkova
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  3. Elena V. Parfenyuk
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  4. Anatoliy I. Vyugin
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Correspondence to Nataliya Sh. Lebedeva.

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Lebedeva, N.S., Malkova, E.A., Parfenyuk, E.V. et al. Thermal and spectral analyses of complexes of zinc(II)tetra-tertbutylphthalocyanine with amines. J Incl Phenom Macrocycl Chem 59, 71–80 (2007). https://doi.org/10.1007/s10847-007-9295-2

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  • DOI: https://doi.org/10.1007/s10847-007-9295-2

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