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Synthesis of Rigid Cyclodextrin-Containing Polymeric Resins for Adsorption

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Abstract

Cyclodextrins (CDs) are a family of cyclic-oligosaccharides with usually 6–8 glucopyranose units. Because of their unique donut-shaped steric structure they are able to form inclusion complexes selectively with some guest molecules. CDs are in starch-like powder form and are soluble in water to certain extents. It is desirable to produce insoluble CD-containing particles for adsorption, liquid chromatography and other applications. This work presents a novel method of synthesizing CD-containing resins. Resins synthesized with this method possess high contents of CDs and some favorable physical properties. Adsorption isotherms for three small aromatic compounds, namely phenylalanine, tryptophan and aspartame, were obtained experimentally.

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Author notes

  1. Gow-jen Tsai

    Present address: Wyeth-Ayerst Research, N. Middletown Road, Building 96A, Room 216, Pearl River, NY, 10965, USA

Authors and Affiliations

  1. Department of Chemical Engineering, Ohio University, Athens, OH, 45701, USA

    Tingyue gu

  2. School of Chemical Engineering, Purdue University, West Lafayette, IN, 47907, USA

    Gow-jen Tsai & George T. Tsao

Authors
  1. Tingyue gu
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  2. Gow-jen Tsai
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  3. George T. Tsao
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Correspondence to Tingyue gu.

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gu, T., Tsai, Gj. & Tsao, G.T. Synthesis of Rigid Cyclodextrin-Containing Polymeric Resins for Adsorption. J Incl Phenom Macrocycl Chem 56, 375–379 (2006). https://doi.org/10.1007/s10847-006-9119-9

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  • DOI: https://doi.org/10.1007/s10847-006-9119-9

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