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Fencing of Photoinduced Electron Transfer in Nonconjugated Bichromophoric System by β-cyclodextrin Nanocavity

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Abstract

Fencing of photoinduced electron transfer (PET) between the donor and acceptor in nonconjugated bichromophoric system by inclusion of donor group in the hydrophobic β-cyclodextrin nanocavity has been observed using steady state and time resolved fluorescence technique. The molecular modelling calculations further confirm the inclusion of donor group in the β-cyclodextrin nanocavity.

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References

  1. Balzani V.: Electron Transfer in Chemistry, Wiley-VCH, Weinheim, Germany, (2001)

    Google Scholar 

  2. deSilva A.P., Gunaratne H.Q.N., Gunnlaugsson T., Huxley A.J.M., McCoy C.P., Rademacher J.T., Rice T.E.: Chem. Rev. 97: 1515 (1997)

    Article  CAS  Google Scholar 

  3. Callan J.F., de Silva A.P., Magri D.C. Tetrahedron 61: 8551 (2005)

    Article  CAS  Google Scholar 

  4. Czarnik A.W., J.-P. Desvergne (eds.), Chemosensors for Ion and Molecule Recognition, Kluwer, Dordrecht, The Netherlands (1997)

    Google Scholar 

  5. Martínez-Máñez R., Sancenón F.: Chem. Rev. 103: 4419 (2003)

    Article  Google Scholar 

  6. Ramamurthy V.: Photochemistry in Organized and Constrained Media, VCH, New York (1991)

    Google Scholar 

  7. Bhattacharyya K. Acc. Chem. Res. 36: 95 (2003)

    Article  CAS  Google Scholar 

  8. Breslow R., Dong S.D.: Chem. Rev. 98: 1997 (1998)

    Article  CAS  Google Scholar 

  9. A special issue of cyclodextrin, Chem. Rev. 98 (1998), and references cited therein

  10. Hayashita T., Yamauchi A., Tong A.-J., Lee J.C., Smith B.D., Teramae N. J. Incl. Phenom. Macrocycl. Chem. 50: 87 (2004)

    CAS  Google Scholar 

  11. A.-J. Tong, A. Yamauchi, T. Hayashita, Z.-Y. Zhang, and N. Teramae: Anal. Chem. 73: 1530 (2001)

    Google Scholar 

  12. Thiagrajan V., Ramamurthy P., Thirumalai D., Ramakrishnan V.T.: Org. Lett. 7: 657 (2005)

    Article  Google Scholar 

  13. Thiagarajan V., Selvaraju C., E.J. Padma Malar, Ramamurthy P. Chem.Phys Chem. 5: 1200 (2004)

    CAS  Google Scholar 

  14. Selvaraju C., Ramamurthy P.: Chem. Eur. J. 10: 2253 (2004)

    Article  CAS  Google Scholar 

  15. S. Singh, S. Chhina, V.K. Sharma, and S.S. Sachdev: Chem. Commun. 453 (1982)

  16. Srividya N., Ramamurthy P., Shanmugasundaram P., Ramakrishnan V.T. J. Org. Chem. 61: 5083 (1996)

    Article  CAS  Google Scholar 

  17. Srividya N., Ramamurthy P., Ramakrishnan V.T. Spectrochim. Acta A. 54: 245 (1998)

    Article  Google Scholar 

  18. Indirapriyadharshini V.K., Karunanithi P., Ramamurthy P. Langmuir. 17: 4056 (2001)

    CAS  Google Scholar 

  19. Karunanithi P., Ramamurthy P., Ramakrishnan V.T. J. Incl. Phenom. Macrocycl. Chem. 34: 105 (1999)

    Article  CAS  Google Scholar 

  20. Benesi H.A., Hildebrand J.H.: J. Am. Chem. Soc. 71: 2703 (1949)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We gratefully acknowledge the grants from CSIR and DST-IRPHA, India. We also thank Dr. N. Subramanian and R. Parthasarathi CLRI, Chennai for molecular modeling work.

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Authors and Affiliations

  1. National Centre for Ultrafast Processes, University of Madras, Taramani Campus, Chennai, 600 113, India

    V. Thiagarajan, V.K. Indirapriyadharshini & P. Ramamurthy

  2. Department of Inorganic Chemistry, University of Madras, Guindy Campus, Chennai, 600 025, India

    V. Thiagarajan & P. Ramamurthy

Authors
  1. V. Thiagarajan
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  2. V.K. Indirapriyadharshini
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  3. P. Ramamurthy
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Correspondence to P. Ramamurthy.

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Thiagarajan, V., Indirapriyadharshini, V. & Ramamurthy, P. Fencing of Photoinduced Electron Transfer in Nonconjugated Bichromophoric System by β-cyclodextrin Nanocavity. J Incl Phenom Macrocycl Chem 56, 309–313 (2006). https://doi.org/10.1007/s10847-005-9043-4

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  • DOI: https://doi.org/10.1007/s10847-005-9043-4

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