Abstract
α-Cyclodextrin having cinnamamide at 6- or 3-positions (6-CiNH-α-CD, 3-CiNH-α-CD) and β-cyclodextrin with cinnamamide on 6-position (6-CiNH-β-CD) have been prepared. Supramolecular structures were formed in the solid state or aqueous solutions and characterized by measurements of NMR and vapor pressure osmometry (VPO). The results indicate that 6-CiNH-β-CD formed insoluble supramolecular polymers in the solid state, while 6-CiNH-α-CD and 3-CiNH-α-CD formed supramolecular complexes in aqueous solutions. 6-CiNH-α-CD was found to form a dimer in an aqueous solution. 3-CiNH-α-CD formed intermolecular complexes to give supramolecular polymers. The differences of the position of guest part on cyclodextrins caused to give a variety of supramolecular structures in aqueous solutions.
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Miyauchi, M., Kawaguchi, Y. & Harada, A. Formation of Supramolecular Polymers Constructed by Cyclodextrins with Cinnamamide. J Incl Phenom Macrocycl Chem 50, 57–62 (2004). https://doi.org/10.1007/s10847-003-8839-3
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DOI: https://doi.org/10.1007/s10847-003-8839-3