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Dielectric and magnetic investigations of mixed cubic spinel Co-ferrites with controlled Mg content

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Abstract

High temperature frequency dependent dielectric properties, and room temperature magnetic behavior of mixed ferrites with controlled content of Mg in Co 1−x Mg x Fe 2 O 4(x=0.0,0.1,0.3,0.5,0.7,0.9 and 1.0) compositions are studied. Single phase spinel structure with cubic symmetry, lattice parameters, crystallite size, magnetic and dielectric properties were substantiated with x-ray diffractometer, transmission electron microscope, vibrating sample magnetometer and impedance analysis, respectively. Due to interfacial polarization, dielectric behavior of all the compositions shows dispersion with increase in frequency. The dielectric data was investigated by comparing the tangent loss and electric modulus for assigning the type and mechanism of dielectric relaxation. Temperature dependent dielectric constant, tangent loss and AC conductivity increase due to thermal activation of charge carriers and drift mobility. Furthermore, room temperature weak ferromagnetic behavior is observed due to the incorporation of non-magnetic Mg ions.

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References

  1. A.S. Ponce, E.F. Chagas, R.J. Prado, C.H.M. Fernandes, A.J. Terezo, E.B. Saitovitch, J. Magn. Magn. Mater. 344, 182 (2013)

    Article  Google Scholar 

  2. R. Skomski, J. Phys-Condens. Mat. 15, R841 (2003)

    Google Scholar 

  3. Y.C. Mattei, O.P. Perez, O.N.C. Uwakweh, Mater. Chem. Phys. 132, 999 (2012)

    Article  Google Scholar 

  4. A.T. Ngo, M.P. Pileni, J. Phys. Chem. B. 105, 53 (2001)

    Article  Google Scholar 

  5. T.L. Templeton, A.S. Arrott, A.E. Curzon, M.A. Gee, X.Z. Li, Y. Yoshida, P. Schurer, J.L. LaCombe, J. Appl. Phys. 73, 6728 (1993)

    Article  Google Scholar 

  6. F. Nakagomi, S.W. da Silva, V.K. Garg, A.C. Oliveira, P.C. Morais, A. Jr. Franco, E.C.D. Lima, Vol. 101. (2007), p. 09M514

  7. J. Gwak, A. Ayral, V. Rouessac, L. Cot, J.C. Grenier, J.H. Choy, Microporous Mesoporous Mater. 63, 177 (2003)

    Article  Google Scholar 

  8. T. Pannaparayil, S. Komarneni, K. Marande, M. Zadarko, J. Appl. Phys. 67, 5509 (1990)

    Article  Google Scholar 

  9. G.B. Ji, S.L. Tang, S.K. Ren, F.M. Zhang, B.X. Gu, Y.W. Du, J. Cryst. Growth. 270, 156 (2004)

    Article  Google Scholar 

  10. S.F. Yan, W. Ling, E.L. Zhou, J. Cryst. Growth. 273, 226 (2004)

    Article  Google Scholar 

  11. Z.X. Yue, J.H. Shan, X.W. Qi, Mater. Sci. Eng. B99, 217 (2003)

    Google Scholar 

  12. S. Arul Antory, K.S. Nagaraja, O.M. Sreedharan, J. Nucl. Mater. 295, 189 (2001)

    Google Scholar 

  13. Z.H. Zhou, J.M. Xue, J. Wang, H.S.O. Chan, T. Yu, Z.X. Shen, J. Appl. Phys. 91, 6015 (2002)

    Article  Google Scholar 

  14. L.A. Garcia-Cerda, V.A. Torres-Garcia, J.A. Matutes-Aquino, J.A. Matutes-Aquino, J. Alloy. Compd. 369, 148 (2004)

    Article  Google Scholar 

  15. F.X. Cheng, Z.Y. Peng, C.S. Liao, Z.G. Xu, S. Gao, C.H. Yan, Solid State Commun. 107, 471 (1998)

    Article  Google Scholar 

  16. J. Gwak, A. Ayral, V. Rouessac, L. Cot, J.C. Grenier, J.H. Choy, Microporous Mesoporous Mater. 63, 177 (2003)

    Article  Google Scholar 

  17. C. Liu, B. Zou, A.J. Rondinone, Z.J. Zhang, J. Am. Chem. Soc. 122, 6263 (2000)

    Article  Google Scholar 

  18. V. Pillai, D.O. Shah, J. Magn. Mater. 163, 243 (1996)

    Article  Google Scholar 

  19. J.L.H. Chau, M.K. Hsu, C.C. Kao, Mater. Lett. 60, 947 (2006)

    Article  Google Scholar 

  20. H.M. Deng, J. Ding, Y. Shi, X.Y. Liu, J. Wang, J. Mater. Sci. 36, 3273 (2001)

    Article  Google Scholar 

  21. X.W. Qi, J. Zhou, Z.X. Yue, Z.L. Gui, L.T. Li, Ceram. Int. 29, 347 (2003)

    Article  Google Scholar 

  22. S.R. Naik, A.V. Salker, S.M. Yusuf, S.S. Meena, J. Alloy. Compd. 566, 54 (2013)

    Article  Google Scholar 

  23. B.H. Liu, J. Ding, Appl. Phys. Lett. 042506-1, 88 (2006)

    Google Scholar 

  24. M. Mali, A. Ataie, Scripta Materialia. 53, 1065 (2005)

    Article  Google Scholar 

  25. K.C. Patil, S.T. Aruna, S. Ekambaram, Curr. Opin. Solid St. M. 2, 158 (1997)

    Article  Google Scholar 

  26. G.X. Xi, L. Yang, M.X. Lu, Mater. Lett. 60, 3582 (2006)

    Article  Google Scholar 

  27. N. Singh, A. Agarwal, S. Sanghi, Curr. Appl. Phys. 11, 783 (2011)

    Article  Google Scholar 

  28. N. Singh, A. Agarwal, S. Sanghi, J. alloys Compd. 323, 486 (2011)

    Google Scholar 

  29. N. Singh, A. Agarwal, S. Sanghi, Physica B. 406, 687 (2011)

    Article  Google Scholar 

  30. M.A. Rehman, M.A. Malik, M. Akram, M. Kamran, K. Khan, A. Maqsood, J. Supercond. Nov. Magn. (2011). doi:10.1007/s10948-011-1244-z.

  31. A. Jr. Franco, F.C. e Silva, S. Vivien, J. Zapf, Appl. Phys. 111, 07B530 (2012)

    Article  Google Scholar 

  32. K. Verma, A. Kumar, D. Varshney, J. Alloys Comp. 526, 91 (2012)

    Article  Google Scholar 

  33. R.D. Shannon, Acta Cryst. A. 32, 751 (1976)

    Article  Google Scholar 

  34. M. Saleem, S.A. Siddiqi, S. Atiq, M.S. Anwar, S. Riaz, J. Chin. Chem. Phys. 23, 469 (2010)

    Article  Google Scholar 

  35. N. Sinakumar, A. Narayanasamy, C.N. Chinnasamy, B. Jeyadevan, J. Phys. 366201, 19 (2007)

    Google Scholar 

  36. M. Saleem, S.A. Siddiqi, S. Atiq, M.S. Anwar, Chin. Phys. Lett. 116103, 28 (2011)

    Google Scholar 

  37. K.W. Wagner, Ann. Phys. 40, 817 (1913)

    Article  Google Scholar 

  38. C.G. Koops, Phys. Rev. 83, 121 (1951)

    Article  Google Scholar 

  39. J. Lin, G. C-Duan, G. W-Yin, W.N. Mei, R.W. Smith, J.R. Hardy, J. Chem. Phys. 119, 2812 (2003)

    Google Scholar 

  40. R. Gerhardt, J. Phys. Chem. Solids. 12, 1491 (1995)

    Google Scholar 

  41. R. Bergman, J. Appl. Phys. 88, 1356 (2000)

    Article  Google Scholar 

  42. N. Ponpandian, P. Balaya, A. Narayanasamy, J. Phys. Condens. Matter. 14, 3221 (2002)

    Article  Google Scholar 

  43. M.A. Hiti, J. Magn. Magn. Mater. 192, 305 (1999)

    Article  Google Scholar 

  44. D. Varshney, K. Verma, A. Kumar. J. Mol. Struct. 1006, 447 (2011)

    Article  Google Scholar 

  45. F. Huixia, C. Baiyi, Z. Deyi, Z. Jianqiang, T. Lin, J. Magn. Magn. Mater. 356, 68 (2014)

    Article  Google Scholar 

  46. M.A. Gabal, Y.M. Al Angari, H.M. Zaki, J. Magn. Mater. 363, 6 (2014)

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Acknowledgments

The authors would like to extend their sincere appreciation to the Deanship of Scientific Research at King Saud University for funding this Research group No. RG 1435-004.

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Authors and Affiliations

  1. School of Science and Engineering (SSE), Lahore University of Management Sciences (LUMS), Opposite Sector U, D.H.A., Lahore, 54792, Pakistan

    Afaq H. Piracha, Murtaza Saleem & Muhammad Sabieh Anwar

  2. Centre of Excellence in Solid State Physics, University of the Punjab, Quaid-e-Azam Campus, Lahore, 54590, Pakistan

    Shahid Atiq

  3. Interdisciplinary Research Centre in Biomedical Materials (IRCBM), COMSATS Institute of Information Technology, Defence Road, Off Raiwind Road, Lahore, Pakistan

    Saadat A. Siddiqi

  4. Physics and Astronomy Department, College of Science, King Saud University, P.O. Box 800, Riyadh, 11421, Saudi Arabia

    Shahid M. Ramay

Authors
  1. Afaq H. Piracha
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  2. Shahid M. Ramay
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  3. Shahid Atiq
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  4. Saadat A. Siddiqi
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  5. Murtaza Saleem
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  6. Muhammad Sabieh Anwar
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Correspondence to Murtaza Saleem.

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Piracha, A.H., Ramay, S.M., Atiq, S. et al. Dielectric and magnetic investigations of mixed cubic spinel Co-ferrites with controlled Mg content. J Electroceram 34, 122–129 (2015). https://doi.org/10.1007/s10832-014-9960-y

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  • DOI: https://doi.org/10.1007/s10832-014-9960-y

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