Advertisement

Journal of Electroceramics

, Volume 27, Issue 2, pp 93–107 | Cite as

Crystal chemistry and properties of mixed ionic-electronic conductors

  • Arumugam ManthiramEmail author
  • Jung-Hyun Kim
  • Young Nam Kim
  • Ki-Tae Lee
Article

Abstract

Oxides exhibiting mixed oxide-ion and electronic conducting (MIEC) properties have been attracting great interest in recent years due to their technological applications in solid-state electrochemical devices such as solid oxide fuel cells (SOFC), oxygen separation membranes, and electrochemical sensors. This article provides an overview of the composition-structure–property-performance relationships of several mixed conducting oxides: disordered ABO3 perovskite oxides, A-site ordered layered LnBaCo2O5+δ (Ln = lanthanide) perovskite oxides, Ruddlesden-Popper series of perovskite-based (La,Sr)n+1MnO3n+1 (n = 1–3 and M = Fe, Co, and Ni) intergrowth oxides, and hexagonal RBa(Co1-yMy)4O7 (R = rare earth or alkaline earth and M = Zn) oxides. Based on the available data, the role of chemical composition, crystal chemistry, and chemical bonding on the electrical and ionic transport, thermal, and electrochemical properties is discussed.

Keywords

Mixed ionic-electronic conductors Metal oxides Crystal chemistry Electronic properties Solid oxide fuel cells Oxygen separation membranes 

Notes

Acknowledgement

Financial support by the Welch Foundation Grant F-1254 is gratefully acknowledged.

References

  1. 1.
    N.Q. Minh, T. Takahashi, Science and technology of ceramic fuel cells (Elsevier, Amsterdam, 1995)Google Scholar
  2. 2.
    S.C. Singhal, K. Kendall, High temperature solid oxide fuel cells: Fundamental, design, and applications (Elsevier Ltd., Oxford, 2003)Google Scholar
  3. 3.
    H.J.M. Bouwmeestere, A.J. Burggraaf, The CRC handbook of solid state electrochemistry (CRC press, New York, 1997)CrossRefGoogle Scholar
  4. 4.
    S.P. Jiang, J. Mater. Sci. 43, 6799 (2008)CrossRefGoogle Scholar
  5. 5.
    H. Yokokawa, N. Sakai, T. Kawada, M. Dokiya, Solid State Ionics 40–41, 398 (1990)CrossRefGoogle Scholar
  6. 6.
    Y. Teraoka, H.M. Zhang, S. Furukawa, N. Yamazoe, Chem. Lett. 11, 1743 (1985)CrossRefGoogle Scholar
  7. 7.
    Y. Teraoka, T. Nobunaga, N. Yamazoe, Chem. Lett. 3, 503 (1988)CrossRefGoogle Scholar
  8. 8.
    Y. Teraoka, H. Zhang, K. Okamoto, N. Yamazoe, Mater. Res. Bull. 23, 51 (1988)CrossRefGoogle Scholar
  9. 9.
    J.P. Hodges, S. Short, J.D. Jorgensen, J. Solid State Chem. 151, 190 (2000)CrossRefGoogle Scholar
  10. 10.
    A.J. Jacobson, Chem. Mater. 22, 660–674 (2010)CrossRefGoogle Scholar
  11. 11.
    M.A. Señarís-Rodríguez, J.B. Goodenough, J. Solid State Chem. 118, 323 (1995)CrossRefGoogle Scholar
  12. 12.
    Z. Shao, S.M. Haile, Nature 431, 170 (2004)CrossRefGoogle Scholar
  13. 13.
    H. Ullmann, N. Trofimenco, F. Tietz, D. Stöver, A. Ahmad-Khanlou, Solid State Ionics 138, 79 (2000)CrossRefGoogle Scholar
  14. 14.
    C. Peters, A. Weber, E. Ivers-Tiffée, J. Electrochem. Soc. 155, B730 (2008)CrossRefGoogle Scholar
  15. 15.
    J.-M. Bae, B.C.H. Steele, Solid State Ionics 106, 247 (1998)CrossRefGoogle Scholar
  16. 16.
    E.P. Murray, M.J. Sever, S.A. Barnett, Solid State Ionics 148, 27 (2002)CrossRefGoogle Scholar
  17. 17.
    G. Kim, S. Wang, A.J. Jacobson, L. Reimus, P. Brodersen, C.A. Mims, J. Mater. Chem. 17, 2500 (2007)CrossRefGoogle Scholar
  18. 18.
    J.-H. Kim, A. Manthiram, J. Electrochem. Soc. 155, B385 (2008)CrossRefGoogle Scholar
  19. 19.
    A. Manthiram, F. Prado, T. Armstrong, Solid State Ionics 152–153, 647 (2002)CrossRefGoogle Scholar
  20. 20.
    J.A. Kilner, C.K.M. Shaw, Solid State Ionics 154–155, 523 (2002)CrossRefGoogle Scholar
  21. 21.
    V.M. Goldschmidt, T. Barth, G. Lunde, W. Zachariasen, Pt. VII Skrifter Norske Videnskabs-Akademi, Oslo. 117 (1926)Google Scholar
  22. 22.
    J.A. Kilner, R.J. Brook, Solid State Ionics 6, 237 (1982)CrossRefGoogle Scholar
  23. 23.
    R.L. Cook, A.F. Sammells, Solid State Ionics 45, 311 (1991)CrossRefGoogle Scholar
  24. 24.
    R.L. Cook, J.J. Osborne, J.H. White, R.C. MacDuff, A.F. Sammells, J. Electrochem. Soc. 139, L19 (1992)CrossRefGoogle Scholar
  25. 25.
    M. Mogensen, D. Lybye, N. Bonanos, P.V. Hendriksen, F.W. Poulsen, Solid State Ionics 174, 279 (2004)CrossRefGoogle Scholar
  26. 26.
    J.-H. Kim, A. Manthiram, Chem. Mater. 22, 822 (2010)CrossRefGoogle Scholar
  27. 27.
    H. Ullmann, N. Trofimenko, J. Alloys Compd. 316, 153 (2001)CrossRefGoogle Scholar
  28. 28.
    R.H. Mitchell, Perovskites: Modern and ancient (Almaz Press, Ontario, 2002)Google Scholar
  29. 29.
    J. Mizusaki et al., Solid State Ionics 129, 163 (2000)CrossRefGoogle Scholar
  30. 30.
    A.N. Petrov, O.F. Kononchuk, A.V. Andreev, V.A. Cherepanov, P. Kofstad, Solid State Ionics 80, 189 (1995)CrossRefGoogle Scholar
  31. 31.
    K.T. Lee, A. Manthiram, J. Electrochem. Soc. 153, A794 (2006)CrossRefGoogle Scholar
  32. 32.
    J. Mizusaki, Y. Mima, S. Yamauchi, K. Fueki, J. Solid State Chem. 80, 102 (1989)CrossRefGoogle Scholar
  33. 33.
    K.T. Lee, A. Manthiram, J. Electrochem. Soc. 152, A197 (2005)CrossRefGoogle Scholar
  34. 34.
    Y. Teraoka, K. Nobunaga, K. Okamoto, N. Miura, N. Yamazoe, Solid State Ionics 48, 207 (1991)CrossRefGoogle Scholar
  35. 35.
    V.V. Kharton, E.N. Naumovich, A.A. Vecher, A.V. Nikolaev, J. Solid State Chem. 120, 128 (1995)CrossRefGoogle Scholar
  36. 36.
    A.V. Kovalevsky, V.V. Kharton, V.N. Tikhonovich, E.N. Naumovich, A.A. Tonoyan, O.P. Reut, L.S. Boginsky, Mater. Sci. Eng. B 52, 105 (1998)CrossRefGoogle Scholar
  37. 37.
    I.O. Troyanchuk, N.V. Kasper, D.D. Khalyavin, Phys. Rev. B 58(5), 2418 (1998)CrossRefGoogle Scholar
  38. 38.
    M. Mori, N.M. Sammes, Solid State Ionics 146, 301 (2002)CrossRefGoogle Scholar
  39. 39.
    M. Mori, Y. Hiei, N.M. Sammes, G.A. Tompsett, J. Electrochem. Soc. 147, 1295 (2000)CrossRefGoogle Scholar
  40. 40.
    K.T. Lee, A. Manthiram, Solid State Ionics 176, 1521 (2005)CrossRefGoogle Scholar
  41. 41.
    K.T. Lee, A. Manthiram, J. Power Sources 158, 1202 (2006)CrossRefGoogle Scholar
  42. 42.
    L.W. Tai, M.M. Nasrallah, H.U. Anderson, D.M. Sparlin, S.R. Sehlin, Solid State Ionics 76, 259 (1995)CrossRefGoogle Scholar
  43. 43.
    M.B. Phillipps, N.M. Sammes, O. Yamamoto, Solid State Ionics 123, 131 (1999)CrossRefGoogle Scholar
  44. 44.
    GCh Kostogloudis, P. Fertis, Ch Ftikos, Solid State Ionics 118, 241 (1999)CrossRefGoogle Scholar
  45. 45.
    H.J.M. Bouwmeester, M.W. Den Otter, B.A. Boukamp, J. Solid State Electrochem. 8, 599 (2004)CrossRefGoogle Scholar
  46. 46.
    Y. Moritomo, M. Takeo, X.J. Liu, T. Akimoto, A. Nakamura, Phys. Rev. B 58(20), R13–R334 (1998)CrossRefGoogle Scholar
  47. 47.
    A. Maignan, C. Martin, D. Pelloquin, N. Nguyen, B. Raveau, J. Solid State Chem. 142, 247 (1999)CrossRefGoogle Scholar
  48. 48.
    T. Vogt, P.M. Woodward, P. Karen, B.A. Hunter, P. Henning, A.R. Moodenbaugh, Phys. Rev. Lett. 84(13), 2969 (2000)CrossRefGoogle Scholar
  49. 49.
    C. Martin, A. Maignan, D. Pelloquin, N. Nguyen, B. Raveau, Appl. Phys. Lett. 71, 1421 (1997)CrossRefGoogle Scholar
  50. 50.
    J.-H. Kim, F. Prado, A. Manthiram, J. Electrochem. Soc. 155, B1023 (2008)CrossRefGoogle Scholar
  51. 51.
    C. Frontera, A. Caneiro, A.E. Carrillo, J. Oró-Solé, J.L. García-Muñoz, Chem. Mater. 17, 5439 (2005)CrossRefGoogle Scholar
  52. 52.
    S. Streule, A. Podlesnyak, D. Sheptyakov, E. Pomjakushina, M. Stingaciu, K. Conder, M. Medarde, M.V. Patrakeev, I.A. Leonidov, V.L. Kozhevnikov, J. Mesot, Phys. Rev. B 73, 094203 (2006)CrossRefGoogle Scholar
  53. 53.
    J.-H. Kim, L. Mogni, F. Prado, A. Caneiro, J.A. Alonso, A. Manthiram, J. Electrochem. Soc. 156, B1376 (2009)CrossRefGoogle Scholar
  54. 54.
    A. Tarancón, D. Marrero-López, J. Peña-Martínez, J.C. Ruiz-Morales, P. Núñez, Solid State Ionics 179, 611 (2008)CrossRefGoogle Scholar
  55. 55.
    A. Chang, S.J. Skinner, J.A. Kilner, Solid State Ionics 177, 2009 (2006)CrossRefGoogle Scholar
  56. 56.
    A.A. Taskin, A.N. Lavro, Y. Ando, Appl. Phys. Lett. 86, 091910 (2005)CrossRefGoogle Scholar
  57. 57.
    A. Tarankon, S.J. Skinner, R.J. Chater, F.H. Ramírez, J.A. Kilner, J. Mater. Chem. 17, 3175 (2007)CrossRefGoogle Scholar
  58. 58.
    J.H. Kim, M. Cassidy, J.T.S. Irvine, J. Bae, Chem. Mater. 22, 883 (2010)CrossRefGoogle Scholar
  59. 59.
    J.-H. Kim, A. Manthiram, Electrochim. Acta 54, 7551 (2009)CrossRefGoogle Scholar
  60. 60.
    Y.N. Kim, J.-H. Kim, A. Manthiram, J. Power Sources 195, 6411 (2010)CrossRefGoogle Scholar
  61. 61.
    Q. Zhou, Y. Zhang, Y. Shen, T. He, J. Electrochem. Soc. 157, B628 (2010)CrossRefGoogle Scholar
  62. 62.
    S.H. Jo, P. Muralidharan, D.K. Kim, Electrochem. Commun. 11, 2085 (2009)CrossRefGoogle Scholar
  63. 63.
    S.N. Ruddlesden, P. Popper, Acta Crystallogr. 11, 54 (1958)CrossRefGoogle Scholar
  64. 64.
    F. Prado, L. Mogni, G.J. Cuello, A. Caneiro, Solid State Ionics 178, 77 (2007)CrossRefGoogle Scholar
  65. 65.
    V.V. Kharton, E.V. Tsipis, E.N. Naumovich, A. Thursfield, M.V. Patrakeev, V.A. Kolotygin, J.C. Waerenborgh, I.S. Metcalfe, J. Solid State Chem. 181, 1425 (2008)CrossRefGoogle Scholar
  66. 66.
    A. Aguadero, J.A. Alonso, M.J. Escudero, L. Daza, Solid State Ionics 179, 393 (2008)CrossRefGoogle Scholar
  67. 67.
    F. Prado, T. Armstrong, A. Caneiro, A. Manthiram, J. Electrochem. Soc. 148, J7 (2001)CrossRefGoogle Scholar
  68. 68.
    F. Prado, A. Manthiram, J. Solid State Chem. 158, 307 (2001)CrossRefGoogle Scholar
  69. 69.
    T. Armstrong, F. Prado, A. Manthiram, Solid State Ionics 140, 89 (2001)CrossRefGoogle Scholar
  70. 70.
    K.T. Lee, A. Manthiram, Chem. Mater. 18, 1621 (2006)CrossRefGoogle Scholar
  71. 71.
    K.T. Lee, D.M. Bierschenk, A. Manthiram, J. Electrochem. Soc. 153, A1255 (2006)CrossRefGoogle Scholar
  72. 72.
    P. Batti, Ann. Chim. (Rome) 52, 941 (1962)Google Scholar
  73. 73.
    J.Y. Lee, J.S. Swinnea, H. Steinfink, W.M. Reiff, S. Pei, J.D. Jorgensen, J. Solid State Chem. 103, 1 (1993)CrossRefGoogle Scholar
  74. 74.
    M. Karppinen, H. Yamauchi, S. Otani, T. Fujita, T. Motohashi, Y.-H. Huang, M. Valkeapää, H. Fjellvåg, Chem. Mater. 18, 490 (2006)CrossRefGoogle Scholar
  75. 75.
    M. Valldor, Solid State Sci. 6, 251 (2004)CrossRefGoogle Scholar
  76. 76.
    A. Maignan, V. Caignaert, D. Pelloquin, S. Hébert, V. Pralong, Phys. Rev. B 74, 165110 (2006)CrossRefGoogle Scholar
  77. 77.
    E.V. Tsipis, V.V. Kharton, J.R. Frade, Solid State Ionics 177, 1823 (2006)CrossRefGoogle Scholar
  78. 78.
    H. Hao, J. Cui, C. Chen, L. Pan, J. Hu, X. Hu, Solid State Ionics 177, 631 (2006)CrossRefGoogle Scholar
  79. 79.
    S. Kadota, M. Karppinen, T. Motohashi, H. Yamauchi, Chem. Mater. 20, 6378 (2008)CrossRefGoogle Scholar
  80. 80.
    Y. Jia, H. Jiang, M. Valkeapää, H. Yamauchi, M. Karppinen, E. Kauppinen, J. Am. Chem. Soc. 131, 4880 (2009)CrossRefGoogle Scholar
  81. 81.
    T. Motohashi, S. Kadota, H. Fjellvag, M. Karppinen, H. Yamauchi, Mater. Sci. Eng. B 148, 196 (2008)CrossRefGoogle Scholar
  82. 82.
    O. Chmaissema, H. Zheng, A. Huq, P.W. Stephens, J.F. Mitchell, J. Solid State Chem. 181, 664 (2008)CrossRefGoogle Scholar
  83. 83.
    J.-H. Kim, Y.N. Kim, S.M. Cho, H. Wang, A. Manthiram, Electrochim. Acta 55, 5312 (2010)CrossRefGoogle Scholar
  84. 84.
    V.B. Vert, J.M. Serra, J.L. Jorda, Electrochem. Commun. 12, 278 (2010)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Arumugam Manthiram
    • 1
    Email author
  • Jung-Hyun Kim
    • 1
  • Young Nam Kim
    • 1
  • Ki-Tae Lee
    • 1
    • 2
  1. 1.Electrochemical Energy Laboratory & Materials Science and Engineering ProgramUniversity of Texas at AustinAustinUSA
  2. 2.Division of Advanced Materials EngineeringChonbuk National UniversityJeonju-CityRepublic of Korea

Personalised recommendations