Abstract
The piezoelectric properties of Pb[(Ni1/3Sb2/3)xTiyZrz]O3 solid solution, where x+y+z = 1, x = 0.08 and y = 0.44–0.49 have been investigated in a wide temperature region using a resonance technique. The physical properties of PZT near the morphotropic phase boundary modified with the relaxor Pb(Ni1/3Sb2/3)O3 have been studied. The coefficients s 11, k 31 and d 31 have been calculated basing on the damped harmonic oscillator model of piezoelectricly vibrating sample. Several anomalies in the temperature dependence of piezoelectric coefficients within the temperature range from 300 to 600 K have been found. For y > 0.46 the coexistence of rhombohedral and tetragonal phases occurs. The observed low piezoelectric activity confirms the existence of polar regions above T m in Pb[(Ni1/3Sb2/3)xTiyZrz]O3.
Similar content being viewed by others
References
H. Jaffe, D.A. Berlincourt, Piezoelectric Transduces materials. Proc. IEEE 53, 1372–86 (1965)
B. Jaffe, R.W. Cook, H. Jaffe, Piezoelectric Ceramics (Academic, London, 1971)
J.M. Herbert, (Ferrolectric transducers and sensors (Gordon and Breach, New York, 1982)
R.W. Whatmore, P.C. Osbond, N.M. Shorrocks, Ferroelectrics 76, 1 (1987)
Y. Xu, Ferroelectric Materials and Their Applications, North Holland, Amsterdam, (1991)
K. Uchino, (Piezoelectric actuators and ultrasonic motors (Kluwer, Boston, 1997)
M.B. Lines, A.M. Glass, (Principles and applications of ferroelectrics and related materials (Clarendon, Oxford, 1997)
G.M. Haerling, J. Am, Ceram. Soc. 82, 797–8181 (1999)
C.P. Shaw, S. Gupta, S.B. Stringfellow, A. Nawarro, J.R. Alcock, R.W. Whatmore, J. Eur. Cer. Soc 22, 2123 (2002)
R.W. Whatmore, O. Molter, C.P. Shaw, J. Eur. Ceram. Soc 23, 721 (2003)
S. B. Lang, Phys. Today 31, (2005)
W. Cao, L.E. Cross, Phys. Rev. B 47, 4825 (1993)
G.A. Rossetti Jr., W. Zhang, A.G. Khachaturyan, Appl. Phys. Lett. 88, 072912 (2006)
C.A. Guarany, L.H.Z. Pelaio, K. Yukimitu, J.C.S. Morales, J.A. Eiras, J. Phys.: Condens. Matter 15, 4851 (2003)
B. Noheda, J.A. Gonzalo, L.E. Cross, R. Guo, S.E. Park, D.E. Cox, G. Shirane Phys. Rev. B 61, 8687 (2000)
B. Noheda, D.E. Cox, G. Shirane, R. Guo, B. Jones, L.E. Cross, Phys. Rev. B 63, 014103 (2000)
R. Guo, L.E. Cross, S.E. Park, B. Noheda, D.E. Cox, G. Shirane, Phys. Rev. Lett. 84, 5423 (2000)
X. Zhu, Z. Meng, J Mater Sci 31, 2171 (1996)
T. Takenaka, A.S. Bahalla, L.E. Cross, K. Sakata, J. Am. Ceram. Soc. 72, 1016 (1989)
V. Shilnikov, A.V. Sopit, A.I. Burhanov, A.G. Luchaninov, J. Eur. Ceram. Soc 19, 1295 (1999)
V. Kowal, C. Alemany, J. Brancin, H. Brunckowa, J. Electroceram. 10, 19 (2003)
Z.G. Zhu, B.S. Li, G.R. Li, W.Z. Zhang, Q.R. Yin Mat, Sci. Eng. B 117, 216 (2005)
H. Du, Qu , J. Che, Z. Pei and W. Zhou, J. Electroceram. 21, 589 (2008)
A.P. Osak, M. Pawełczyk, W.S. Ptak, Ferroelectrics 186, 123 (1996)
I. Jankowska-Sumara, Ferroelectrics 345, 115 (2006)
I. Jankowska-Sumara, A. Osak, Phase Transitions 81, 331 (2008)
G. Helke, Hermsdorfer Techn. Mitt. 2, 1010 (1971)
G. Helke, W. Kirsch, Hermsdorfer Techn. Mitt. 44, 1456 (1977)
G. Helke, G. Röder, Hermsdorfer Techn. Mitt. 54, 1729 (1979)
I. Jankowska-Sumara, A. Osak, Physica B 404, 3698 (2009)
A.M. Gonzalez, C. Alemany, J. Phys, D. Appl. Phys. 29, 247 (1996)
D.A. Berlicourt, D.R. Curran, H. Jaffe, Physical Acoustic-Principles and Methods 1, 169 (1964)
IEEE Standard on Piezoelectricity, ANSI/IEEE Std. 176 (1987)
B. Noheda, J. A .Gonzalo, A. Caballero, C. Moure, D. E. Cox, G. Shirane, arXiv,cond-mat/9907286v1 (1999)
J. Petzelt, Y.G. Gonharov, G.V. Kozlov, A.A. Volkov, B. Wyncke, F. Brehat, Czech J. Phys B 34, 887 (1984)
K. Wieczorek, A. Ziębińska, Z. Ujma, K. Szot, M. Górny, I. Franke, J. Koperski, A. Soszyński, K. Roleder, Electrostrictive and Piezoelectric Effect in BaTiO3 and PbZrO3. Ferroelectrics 336, 61 (2006)
Acknowledgments
This work was partially supported by the State Committee of Scientific research (KBN). The author is grateful to dr A. Osak from the Institute of Physics, Cracow University of Technology for supplying the ceramics.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jankowska-Sumara, I. Phase transitions in Pb[(Ni1/3Sb2/3)xTiyZrz]O3 solid solution ceramics studied by piezoelectric measurements. J Electroceram 25, 168–173 (2010). https://doi.org/10.1007/s10832-010-9611-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10832-010-9611-x