Skip to main content
Log in

Phase transitions in Pb[(Ni1/3Sb2/3)xTiyZrz]O3 solid solution ceramics studied by piezoelectric measurements

  • Published:
Journal of Electroceramics Aims and scope Submit manuscript

Abstract

The piezoelectric properties of Pb[(Ni1/3Sb2/3)xTiyZrz]O3 solid solution, where x+y+z = 1, x = 0.08 and y = 0.44–0.49 have been investigated in a wide temperature region using a resonance technique. The physical properties of PZT near the morphotropic phase boundary modified with the relaxor Pb(Ni1/3Sb2/3)O3 have been studied. The coefficients s 11, k 31 and d 31 have been calculated basing on the damped harmonic oscillator model of piezoelectricly vibrating sample. Several anomalies in the temperature dependence of piezoelectric coefficients within the temperature range from 300 to 600 K have been found. For y > 0.46 the coexistence of rhombohedral and tetragonal phases occurs. The observed low piezoelectric activity confirms the existence of polar regions above T m in Pb[(Ni1/3Sb2/3)xTiyZrz]O3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. H. Jaffe, D.A. Berlincourt, Piezoelectric Transduces materials. Proc. IEEE 53, 1372–86 (1965)

    Article  Google Scholar 

  2. B. Jaffe, R.W. Cook, H. Jaffe, Piezoelectric Ceramics (Academic, London, 1971)

    Google Scholar 

  3. J.M. Herbert, (Ferrolectric transducers and sensors (Gordon and Breach, New York, 1982)

    Google Scholar 

  4. R.W. Whatmore, P.C. Osbond, N.M. Shorrocks, Ferroelectrics 76, 1 (1987)

    Google Scholar 

  5. Y. Xu, Ferroelectric Materials and Their Applications, North Holland, Amsterdam, (1991)

  6. K. Uchino, (Piezoelectric actuators and ultrasonic motors (Kluwer, Boston, 1997)

    Google Scholar 

  7. M.B. Lines, A.M. Glass, (Principles and applications of ferroelectrics and related materials (Clarendon, Oxford, 1997)

    Google Scholar 

  8. G.M. Haerling, J. Am, Ceram. Soc. 82, 797–8181 (1999)

    Article  Google Scholar 

  9. C.P. Shaw, S. Gupta, S.B. Stringfellow, A. Nawarro, J.R. Alcock, R.W. Whatmore, J. Eur. Cer. Soc 22, 2123 (2002)

    Article  CAS  Google Scholar 

  10. R.W. Whatmore, O. Molter, C.P. Shaw, J. Eur. Ceram. Soc 23, 721 (2003)

    Article  CAS  Google Scholar 

  11. S. B. Lang, Phys. Today 31, (2005)

  12. W. Cao, L.E. Cross, Phys. Rev. B 47, 4825 (1993)

    Article  CAS  ADS  Google Scholar 

  13. G.A. Rossetti Jr., W. Zhang, A.G. Khachaturyan, Appl. Phys. Lett. 88, 072912 (2006)

    Article  ADS  Google Scholar 

  14. C.A. Guarany, L.H.Z. Pelaio, K. Yukimitu, J.C.S. Morales, J.A. Eiras, J. Phys.: Condens. Matter 15, 4851 (2003)

    Article  CAS  ADS  Google Scholar 

  15. B. Noheda, J.A. Gonzalo, L.E. Cross, R. Guo, S.E. Park, D.E. Cox, G. Shirane Phys. Rev. B 61, 8687 (2000)

    Article  CAS  ADS  Google Scholar 

  16. B. Noheda, D.E. Cox, G. Shirane, R. Guo, B. Jones, L.E. Cross, Phys. Rev. B 63, 014103 (2000)

    Article  ADS  Google Scholar 

  17. R. Guo, L.E. Cross, S.E. Park, B. Noheda, D.E. Cox, G. Shirane, Phys. Rev. Lett. 84, 5423 (2000)

    Article  CAS  ADS  PubMed  Google Scholar 

  18. X. Zhu, Z. Meng, J Mater Sci 31, 2171 (1996)

    Article  CAS  ADS  Google Scholar 

  19. T. Takenaka, A.S. Bahalla, L.E. Cross, K. Sakata, J. Am. Ceram. Soc. 72, 1016 (1989)

    Article  CAS  Google Scholar 

  20. V. Shilnikov, A.V. Sopit, A.I. Burhanov, A.G. Luchaninov, J. Eur. Ceram. Soc 19, 1295 (1999)

    Article  CAS  Google Scholar 

  21. V. Kowal, C. Alemany, J. Brancin, H. Brunckowa, J. Electroceram. 10, 19 (2003)

    Article  Google Scholar 

  22. Z.G. Zhu, B.S. Li, G.R. Li, W.Z. Zhang, Q.R. Yin Mat, Sci. Eng. B 117, 216 (2005)

    Google Scholar 

  23. H. Du, Qu , J. Che, Z. Pei and W. Zhou, J. Electroceram. 21, 589 (2008)

  24. A.P. Osak, M. Pawełczyk, W.S. Ptak, Ferroelectrics 186, 123 (1996)

    Article  CAS  Google Scholar 

  25. I. Jankowska-Sumara, Ferroelectrics 345, 115 (2006)

    Article  CAS  Google Scholar 

  26. I. Jankowska-Sumara, A. Osak, Phase Transitions 81, 331 (2008)

    Article  CAS  Google Scholar 

  27. G. Helke, Hermsdorfer Techn. Mitt. 2, 1010 (1971)

    Google Scholar 

  28. G. Helke, W. Kirsch, Hermsdorfer Techn. Mitt. 44, 1456 (1977)

    Google Scholar 

  29. G. Helke, G. Röder, Hermsdorfer Techn. Mitt. 54, 1729 (1979)

    Google Scholar 

  30. I. Jankowska-Sumara, A. Osak, Physica B 404, 3698 (2009)

    Article  CAS  ADS  Google Scholar 

  31. A.M. Gonzalez, C. Alemany, J. Phys, D. Appl. Phys. 29, 247 (1996)

    Google Scholar 

  32. D.A. Berlicourt, D.R. Curran, H. Jaffe, Physical Acoustic-Principles and Methods 1, 169 (1964)

    Google Scholar 

  33. IEEE Standard on Piezoelectricity, ANSI/IEEE Std. 176 (1987)

  34. B. Noheda, J. A .Gonzalo, A. Caballero, C. Moure, D. E. Cox, G. Shirane, arXiv,cond-mat/9907286v1 (1999)

  35. J. Petzelt, Y.G. Gonharov, G.V. Kozlov, A.A. Volkov, B. Wyncke, F. Brehat, Czech J. Phys B 34, 887 (1984)

    Article  ADS  Google Scholar 

  36. K. Wieczorek, A. Ziębińska, Z. Ujma, K. Szot, M. Górny, I. Franke, J. Koperski, A. Soszyński, K. Roleder, Electrostrictive and Piezoelectric Effect in BaTiO3 and PbZrO3. Ferroelectrics 336, 61 (2006)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was partially supported by the State Committee of Scientific research (KBN). The author is grateful to dr A. Osak from the Institute of Physics, Cracow University of Technology for supplying the ceramics.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Irena Jankowska-Sumara.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jankowska-Sumara, I. Phase transitions in Pb[(Ni1/3Sb2/3)xTiyZrz]O3 solid solution ceramics studied by piezoelectric measurements. J Electroceram 25, 168–173 (2010). https://doi.org/10.1007/s10832-010-9611-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10832-010-9611-x

Keywords

Navigation