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Electrochemical characteristics of semi conductive silicon anode for lithium polymer batteries

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Abstract

In this paper, the electrochemical characteristics of semi conductive silicon thin films (n-type and p-type silicon) anodes integrated with the solid polymer electrolyte for lithium polymer batteries were investigated. The charge/discharge cycling tests revealed that the phosphorus-doped n-type silicon electrode shows the most stable cyclic performance after the 40th cycle and still maintains a reversible specific capacity of about 2,500 mAh/g. The enhanced electrochemical performance of the doped silicon anode was attributed to the enhancement of its electrical conductivity, which was further confirmed by impedance spectroscopy and surface analysis by XPS.

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Acknowledgement

The authors thank Mr. Ji Hun Park for XPS analysis and helpful discussion. This research was supported by a grant(code #05K1501-01920) from ‘Center for Nanostructured Materials Technology’ under ‘21st Century Frontier R&D Programs’ of the Ministry of Science and Technology, Korea.

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Authors and Affiliations

  1. Advanced Energy Materials Processing Laboratory, Battery Research Center, Korea Institute of Science and Technology, P.O. BOX 131, Cheongryang, Seoul, 130-650, Korea

    Arenst Andreas Arie, Wonyoung Chang & Joong Kee Lee

  2. Energy Conversion Technology Division, University of Science and Technology, Daejeon, Korea

    Arenst Andreas Arie

Authors
  1. Arenst Andreas Arie
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  2. Wonyoung Chang
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  3. Joong Kee Lee
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Correspondence to Joong Kee Lee.

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Andreas Arie, A., Chang, W. & Kee Lee, J. Electrochemical characteristics of semi conductive silicon anode for lithium polymer batteries. J Electroceram 24, 308–312 (2010). https://doi.org/10.1007/s10832-009-9573-z

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  • DOI: https://doi.org/10.1007/s10832-009-9573-z

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