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Preparation and electrochemical properties of La1.0Sr1.0FeO4+δ as cathode material for intermediate temperature solid oxide fuel cells

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Abstract

Cathodic material La1.0Sr1.0FeO4+δ for an intermediate temperature solid oxide fuel cell (IT-SOFC) was prepared via the glycine-nitrate process and characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM). XRD results showed that no reaction occurred between the La1.0Sr1.0FeO4+δ electrode and Sm0.2Ce0.8O1.9 (SDC) electrolyte at 1000 °C. SEM results showed that the electrode formed good contact with the SDC electrolyte after sintering at 1000 °C for 2 h. The electrochemical properties of La1.0Sr1.0FeO4+δ were measured using electrochemical impedance spectroscopy (EIS) and steady state polarization measurement. At 700 °C, the polarization resistance was about 3.90 Ωcm2, and the lowest polarization overpotential was 57 mV at a current density of 55 mA cm−2.

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References

  1. S.B. Adler, Chem. Rev. 4791, 104 (2004)

    Google Scholar 

  2. F. Mauvy, J.M. Bassat, E. Boehm, J.P. Manaud, P. Dordor, J.C. Grenier, Solid State Ion. 17, 158 (2003)

    Google Scholar 

  3. E. Ivers-Tiffee, A. Weber, D. Herbstritt, J. Eur. Ceram. Soc. 1805, 21 (2001)

    Google Scholar 

  4. J. Fleig, J. Maier, J. Eur. Ceram. Soc. 1343, 24 (2004)

    Google Scholar 

  5. S.J. Skinner, J.A. Kilner, Solid State Ion. 709, 135 (2000)

    Google Scholar 

  6. M.A. Daroukh, V.V. Vashook, H. Ullmann, F. Tietzb, I. Arual. Raj., Solid State Ion. 141, 158 (2003)

    Google Scholar 

  7. Y.S. Wang, H.W. Nie, S.R. Wang, T.L. Wen, U. Guth, V. Valshook, Mater. Lett. 1174, 60 (2006)

    Google Scholar 

  8. C. Jin, J. Liu, Y.H. Zhang, J. Sui, W.M. Guo, J. Power Sources 482, 182 (2008)

    Google Scholar 

  9. E. Boehm, J.M. Bassat, M.C. Steil, P. Dordor, F. Mauvy, J.C. Grenier, Solid State Sci. 973, 5 (2003)

    Google Scholar 

  10. E. Boehm, J.M. Bassat, P. Dordor, F. Mauvy, J.C. Grenier, P. Stevens, Solid State Ion. 2717, 176 (2005)

    Google Scholar 

  11. N. Solak, M. Zinkevich, F. Aldinger, Solid State Ion. 2139, 177 (2006)

    Google Scholar 

  12. M.L. Fontaine, C. Laberty-Robert, F. Ansart, P. Tailhades, J. Power Sources 33, 156 (2006)

    Google Scholar 

  13. V. Vashook, J. Zosel, T.L. Wen, U. Guth, Solid State Ion. 1827, 177 (2006)

    Google Scholar 

  14. F. Mauvy, J.M. Bassat, E. Boehm, J.P. Manaud, P. Dordor, J.C. Grenier, Solid State Ion. 17, 158 (2003)

    Google Scholar 

  15. C. Lalanne, F. Mauvy, E. Siebert, M.L. Fontaine, J.M. Bassat, F. Ansart et al., J. Eur. Ceram. Soc. 4195, 27 (2007)

    Google Scholar 

  16. Q. Li, Y. Fan, H. Zhao, L.P. Sun, L.H. Huo, J. Power Sources 64, 167 (2007)

    Google Scholar 

  17. A.J. Jennings, S.J. Skinner, Solid State Ion. 663, 152–153 (2002)

    Google Scholar 

  18. T. Omata, K. Ueda, N. Ueda, M. Katada, S. Fujitsu, T. Hashimoto et al., Solid State Commun. 807, 88 (1993)

    Google Scholar 

  19. L.A. Chick, L.R. Pederson, G.D. Maupin, J.L. Bates, L.E. Thomas, G.J. Exarhos, Mater. Lett. 6, 10 (1990)

    Google Scholar 

  20. D.H.A. Blank, H. Kruidhof, J. Flokstra, J. Phys, D. Appl. Phys. (Berl.) 226, 21 (1988)

    Google Scholar 

  21. C. Jin, J. Liu, W.M. Guo, Y.H. Zhang, J. Power Sources 506, 183 (2008)

    Google Scholar 

  22. J. Liu, S.A. Barnett, Solid State Ion. 11, 158 (2003)

    Google Scholar 

  23. J. Liu, Z. Lü, S.A. Barnett, Y. Ji, W.H. Su, the 9th International Symposium on Solid oxide Fuel Cells Electrochemical Society Proceedings. 1976, 07 (2005)

  24. D.C. Zhu, X.Y. Xu, S.J. Feng, W. Liu, C.S. Chen, Catal. Today 151, 82 (2003)

    Google Scholar 

  25. C. Li, T.H. Hu, H. Zhang, Y. Chen, J. Jin, N.R. Yang, J. Membr. Sci. 1, 226 (2003)

    Google Scholar 

  26. J.W.J. Potts, Chemical Infrared Spectroscopy, vol. 135 (Wiley, NewYork, 1963), p. 1

    Google Scholar 

  27. V.V. Vashook, S.P. Tolochko, I.I. Yushkevich, L.V. Makhnach, I.F. Kononyuk, H. Altenburg et al., Solid State Ion. 245, 110 (1998)

    Google Scholar 

  28. K. Ishikawa, S. Kondo, H. Okanc, S. Suzuki, Y. Suzuki, Bull. Chem. Soc. Jpn. 1295, 60 (1987)

    Google Scholar 

  29. L.A. Chick, L.R. Pederson, G.D. Maupin, J.L. Bates, L.E. Thomas, G.J. Exarhos, Mater. Lett. 6, 10 (1990)

    Google Scholar 

  30. S.B. Adler, Solid State Ion. 125, 111 (1998)

    Google Scholar 

  31. Q. Li, Y. Fan, H. Zhao, L.H. Huo, Chin J. Inorg. Chem 2025, 22 (2006)

    Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Hualan Road, Xinxiang, 453003, People’s Republic of China

    Jianhua Huang, Xiaoying Jiang, Xiaobo Li & Aiqin Liu

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  1. Jianhua Huang
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  2. Xiaoying Jiang
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  3. Xiaobo Li
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Correspondence to Jianhua Huang.

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Huang, J., Jiang, X., Li, X. et al. Preparation and electrochemical properties of La1.0Sr1.0FeO4+δ as cathode material for intermediate temperature solid oxide fuel cells. J Electroceram 23, 67–71 (2009). https://doi.org/10.1007/s10832-008-9536-9

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  • DOI: https://doi.org/10.1007/s10832-008-9536-9

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