Abstract
A significant decrease in the dielectric loss and leakage current by introducing Ce in small amounts into BST thin films is demonstrated. The other effects of Ce doping are a lowering of the dielectric constant and a lower temperature coefficient of dielectric constant. In films containing a periodic fluctuation of Ce concentration through the thickness, prepared using a multilayer approach, the dielectric loss is further reduced. The periodicity of the composition is shown to have a significant effect on the properties. The properties of the multilayer films are seen to be significantly different from the single layer films of corresponding average composition.
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Y. Ohya, T. Ito, Y. Takahashi, Jpn. J. Appl. Phys. 33, 5272–5276 (1994)
R. Poyato, M.L. Calzada, L. Pardo, J. Appl. Phys. 97, 034108 (2005)
A. Safari, R.K. Panda, V.F. Janas, in Advanced Ceramic Materials: Key Engineering Materials, vols. 122–124, ed. by M. Mostaghasi (Trans Tech Publications, 1996), pp. 35–71
C. Wang, Q.F. Fang, Z.G. Zhu, A.Q. Jiang, S.Y. Wang, B.L. Chen, Z.H. Chen, Appl. Phys. Lett. 82(17), 2880–2882 (2003)
F. Yan, Y. Wang, H.L.W. Chen, C.L. Choy, Appl. Phys. Lett. 82 (24), 4325–4327 (2003)
D. Bao, N. Wakiya, K. Shinozaki, N. Mizutani, Ferroelectrics 220, 27–32 (2002)
K. Li, K. Zou, Y. Wang, H. Jiang, X. Chen, Mater. Res. Soc. Symp. Proc. 784, C 8.9.1–C 8.9.6 (2004)
C. Wang, B.L. Cheng, S.Y. Wang, H.B. Lu, Y.L. Zhuo, Z.H. Chen, G.Z. Wang, Appl. Phys. Lett. 84(5), 765–767 (2004)
K.H. Yoon, J.C. Lee, J. Park, D.H. Kang, C.M. Song, Y.G. Seo, Jpn. J. Appl. Phys. 40, 5497–5500 (2001)
S.B. Majumder, D.C. Agrawal, Y.N. Mohapatra, R.S. Katiyar, Math. Sci. Eng. B98, 25–32 (2003)
M. Cernea, O. Monnereau, P. Llewellyn, L. Tortet, C. Galassi, J. Eur. Ceram. Soc. 26, 3241–3246 (2006)
D.-Y. Lu, X.-Y. Sun, M. Toda, J. Phys. Chem. Solids 68, 650–664 (2007)
Z. Yu, C. Ang, Z. Jing, P.M. Vilarinho, J.L. Baptista, J. Phys. Condens. Matter 9, 3081 (1997)
S.Y. Wang, B.L. Cheng, C. Wang, S.Y. Dai, K.J. Jin, Y.L. Zhou, H.B. Lu, Z.H. Chen, G.Z. Yang, J. Appl. Phys. 99, 013504 (2006)
S.Y. Wang, B.L. Cheng, C. Wang, S.A.T. Redfern, S.Y. Dai, K.J. Jin, H.B. Lu, Y.L. Zhou, Z.H. Chen, G.Z. Yang, J. Phys. D. Apple. Phys. 38, 2253–2257 (2005)
F.D. Morrison, D.C. Sinclair, A.R. West, J. Appl. Phys. 86, 6355–6366 (1999)
D.F.K. Hennings, B. Schreinemacher, H. Schreinemacher, J. Eur. Ceram. Soc. 13, 81–88 (1994)
D. Makovec, D. Kolar, J. Am. Ceram. Soc. 80, 45–52 (1997)
J. Zhi, Y. Zhi, A. Chen, J. Mater. Res. 17, 2787–2793 (2002)
A.S. Shaikh, R.W. Vest, J. Am. Ceram. Soc. 69, 689–694 (1986)
T.R.N. Kutty, P. Murugaraj, J. Mater. Sci. 22, 3652–3664 (1987)
Y. Park, H.G. Kim, Jpn. J. Appl. Phys. Part 1 36, 3558–3563 (1997)
Y. Park, H.G. Kim, Ferroelectrics 198, 67–76 (1997)
D.-Y. Lu, T. Koda, H. Suzuki, M. Toda, J. Ceram. Soc. Jpn. 113, 721–727 (2005)
M.A.A. Issa, N.M. Molokhia, S.A. Nasser, J. Phys. D 17, 571–578 (1984)
Y. Park, K. Cho, H.G. Kim, J. Am. Ceram. Soc. 81, 1893–1899 (1998)
G. Burns, F.H. Dacol, Phys. Rev. B28, 2527 (1983)
Z. Kutnjak, C. Filipic, R. Pirc, A. Levstik, Phys. Rev. B 59, 294 (1999)
B. Jeffe, W.R. Cook, H. Jaffe, Piezoelectric Ceramics (Academic Press, London, 1971)
F. John, G. Shirane, Ferroelctric Crystals (Pergamon, New York, 1962)
J.G. Cheng, X. Meng, B.J. Tang, S. Guo, Z. Wang, Appl. Phy. Lett. 75, 2132 (1999)
F.M. Pontes, J. Appl. Phys. 91, 5972 (2002)
Anju Dixit, Santosh K. Gupta, D. C. Agrawal, Y. N. Mohapatra, S. B. Majumder, and R. S. Katiyar. (Communicated).
Y.B. Lin, J.Y. Lee, J. Appl. Phys. 87, 1841 (2000)
H. Schroeder, S. Schmitz, P. Meuffels, Appl. Phys. Lett. 82, 781 (2003)
S.B. Majumder, Y.N. Mohapatra, D.C. Agrawal, Appl. Phys. Lett. 70, 138 (1997)
A. Garg, D.C. Agrawal, J. Mater. Sci. Mater. Electron. 10, 649–652 (1999)
M. Izuha, K. Abe, N. Fukushima, Jpn. J. Appl. Phys. 36, 5866 (1997)
Acknowledgements
Support, in part, by the Government of India through grant Nos. ERIP/ER/0300199/M01 and DST/INT/US (NSF-RP052)/2000 and by NSF through NSF-DMR-305588 is greatly acknowledged.
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Basu, S., Verma, A., Agrawal, D.C. et al. Effect of uniform and periodic doping by Ce on the properties of barium strontium titanate thin films. J Electroceram 19, 229–236 (2007). https://doi.org/10.1007/s10832-007-9336-7
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DOI: https://doi.org/10.1007/s10832-007-9336-7